4.0 Article

Kinetics of the Catalytic Reforming of Gasoline

Journal

KINETICS AND CATALYSIS
Volume 58, Issue 3, Pages 279-289

Publisher

PLEIADES PUBLISHING INC
DOI: 10.1134/S0023158417030132

Keywords

catalytic reforming; kinetic model; lumping analysis; nonisothermal process; reactor block

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The main routes of catalytic gasoline reforming are considered. A kinetic model is chosen, substantiated, and modified to adequately describe the most important chemical reactions occurring in the process. The kinetic model is used to construct a mathematical model taking into account the nonisothermal character of the process. To reconcile calculated data with the corresponding industrial data, kinetic parameters (activation energies of reactions and preexponential factors of the Arrhenius equation) have been corrected for basic reactions of the process and have been redetermined for some ones. Process stages and concentration profiles of groups of reactants have been analyzed. Foundations have been laid for modeling of the entire chemical technological system of the catalytic reforming process.

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