Article
Materials Science, Multidisciplinary
Pedro Leo, Gisela Orcajo, Jose A. Garcia, Ana M. Ortuno, Juan M. Cuerva, David Briones, Guillermo Calleja, Antonio Rodriguez-Dieguez, Raul Sanz, Javier Cepeda, Fernando Martinez
Summary: This work reports the synthesis and characterization of enantiomeric pair of 3D coordination polymers based on heavy alkaline-earth metal ions and cyclic aliphatic chiral linkers. These materials exhibit dense framework and intriguing photophysical properties, including intense fluorescence and long-lasting phosphorescence, as well as circularly polarized luminescence in accordance with their chiral nature.
JOURNAL OF MATERIALS CHEMISTRY C
(2021)
Article
Chemistry, Inorganic & Nuclear
Pavel A. Demakov, Alexey A. Ryadun, Vladimir P. Fedin
Summary: Six new three-dimensional metal-organic frameworks based on early lanthanide(III) cations and trans-1,4-cyclohexanedicarboxylic acid were synthesized and their structures, thermal stability, and luminescent properties were investigated.
Article
Materials Science, Multidisciplinary
Amr Ghazy, Mika Lastusaari, Maarit Karppinen
Summary: Precisely composition-tuned lanthanide-organic thin films with white light emission are fabricated using ALD/MLD technique. The emission characteristics are comparable to or even better than those of commercial incandescent bulbs, fluorescent tubes, and LED lamps. The films consist of up to four lanthanide species and terephthalate as the organic linker, which not only provides mechanical flexibility and defines the distance between lanthanide ions but also exhibits UV/blue broad-band emission upon UV excitation. The emission energy is efficiently transferred to Er3+ ions, resulting in longer wavelength emission, while Tb and Eu contribute to green and red emissions, producing warm white light emission in the films. By controlling the distribution of Ln dopants using a three-layer composition, the emission intensity is increased fourfold.
JOURNAL OF MATERIALS CHEMISTRY C
(2023)
Article
Chemistry, Inorganic & Nuclear
Tomasz Charytanowicz, Barbara Sieklucka, Szymon Chorazy
Summary: An effective strategy for tunable room-temperature multicolor to white-light emission was achieved by mixing different lanthanide ions (Sm3+, Tb3+, and Ce3+) in three-dimensional coordination frameworks based on hexacyanidoruthenate(II) metalloligands. By forming blue RuII emission, red SmIII emission, and green TbIII emission in the Ln-NC-Ru linkages, the emission characteristics for different lanthanide ions were successfully adjusted.
INORGANIC CHEMISTRY
(2023)
Article
Chemistry, Inorganic & Nuclear
S. Zaenker, G. Scholz, T. Krahl, C. Prinz, F. Emmerling, E. Kemnitz
Summary: By doping lanthanides with different binding motifs into coordination polymers, the influence of different fluorine positions in the structure on the decay time of the excited states can be investigated. The CP with a metal-fluorine bond exhibits the highest lifetime of the excited states of lanthanides, enabling the simultaneous excitation of different lanthanides.
SOLID STATE SCIENCES
(2021)
Article
Chemistry, Inorganic & Nuclear
Shiying Liu, Wei Liu, Yiliang Sun, Weisheng Liu
Summary: The in situ doping method was used to construct Ln-MOFs with excellent luminescent properties. A novel Bi-MOF was constructed and doped with different lanthanide metal ions to achieve high luminescence quantum yields. The doped MOFs showed potential for temperature sensing and color change applications.
INORGANIC CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
Yu-Guang Li, Jun-Jie Hu, Jia-Li Zhang, Sui-Jun Liu, Yan Peng, He-Rui Wen
Summary: A family of novel lanthanide-based metal-organic frameworks with bifunctional fluorescence sensing properties was synthesized and characterized. These frameworks exhibit strong fluorescence emissions due to the presence of a pyrene ring. They also serve as good bifunctional fluorescence sensors for acetylacetone and aspartic acid.
Article
Chemistry, Applied
Sibo Wang, Bo Sun, Jing Sun, Xiangrong Hao, Xiao Li, Chen Zhou, Zhongmin Su
Summary: In this study, two stable lanthanide metal-organic frameworks were successfully constructed and exhibited luminescence emission in multiple spectral regions. These materials not only demonstrated solid-state white light emission performance, but also showed remarkable characteristics in temperature and ion sensing.
Article
Chemistry, Inorganic & Nuclear
Md Jahidul Islam, Yuichi Kitagawa, Makoto Tsurui, Yasuchika Hasegawa
Summary: This paper presents chiral mixed Eu(iii)-Ln(iii) coordination polymers (Ln = Gd and Sm) with a high dissymmetry factor of circularly polarized luminescence, achieving enhanced emission quantum yield (phi(tot) >= 50%) through control of 4f electronic structures.
DALTON TRANSACTIONS
(2021)
Article
Polymer Science
Dimitry Grebenyuk, Mirijam Zobel, Dmitry Tsymbarenko
Summary: A new family of isostructural lanthanide pivalate complexes with ethylenediamine ligands were synthesized and their crystal structures were determined. The peculiarities of the lanthanide coordination environment and the stability of the chains were explored. The luminescent properties of the complexes were investigated, revealing temperature-dependent luminescence and potential for optical applications.
Article
Chemistry, Inorganic & Nuclear
De-Gang Ke, Sheng-Li Huang, Guo-Yu Yang
Summary: In this study, three polyoxometalate-based metal-organic frameworks were synthesized through the thermal reaction of pyridyl-Anderson polyoxometalate linker and lanthanide ions. These frameworks exhibited excellent photocatalytic sulfide oxidation performance with sulfoxide selectivity in the presence of [Ru(bpy)3]2+ photosensitizer.
INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Physical
Yasuchika Hasegawa, Yuichi Kitagawa
Summary: This review focuses on the recent progress of one-, two-, and three-dimensional polymer-typed lanthanide complexes, luminescent lanthanide coordination polymers, for physical and chemical sensing applications. Their changeable luminescence, which depends on the energy transfer between lanthanide(III) ions and aromatic organic ligands, makes them useful for sensing physical (temperature, pressure, pH, and mechanical force) and chemical (adsorption of metal ions and molecules) conditions.
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS
(2022)
Article
Chemistry, Analytical
Nan Gao, Zhipeng Zhang, Yi Xiao, Pengcheng Huang, Fang-Ying Wu
Summary: In this study, rhodamine B (RhB) and glucose oxidase (GOx) are successfully encapsulated in a heterobinuclear lanthanide coordination polymer (RhB & GOx@AMP-Tb/Ce) synthesized by self-assembly of Ce3+, Tb3+, and adenosine monophosphate (AMP). The material shows good storage stability and minimal leakage. The RhB & GOx@AMP-Tb/Ce exhibits superior luminescence and can quantitatively detect glucose.
Article
Chemistry, Multidisciplinary
Jinzeng Wang, Yan Suffren, Carole Daiguebonne, Kevin Bernot, Guillaume Calvez, Stephane Freslon, Olivier Guillou
Summary: The study discovered that reactions in water between lanthanide chlorides and the disodium salt of 2-hydroxyterephthalic acid can lead to six families of lanthanide-based coordination polymers. These polymers vary in composition depending on the lanthanide ion and the crystal growth method. Additionally, the optical properties of these compounds have been studied in detail.
Article
Polymer Science
Pilar Narea, Benjamin Hernandez, Jonathan Cisterna, Alejandro Cardenas, Pilar Amo-Ochoa, Felix Zamora, Gerzon E. Delgado, Jaime Llanos, Ivan Brito
Summary: Two Zn(II) coordination polymers (CPs) were synthesized using n-methylpyridyltriazole carboxylate semi-rigid organic ligands (L1 and L2). The structures of the CPs were found to be influenced by the isomeric positional effect and the presence of a methylene spacer group. The luminescent properties of the CPs were significantly different, with CP 2 showing strong emission at 367 nm while CP 1 had substantially quenched emission.
Article
Chemistry, Multidisciplinary
Yiwei Liu, Shumei Liu, Xuying Lai, Jun Miao, Danfeng He, Ning Li, Fang Luo, Zhan Shi, Shuxia Liu
ADVANCED FUNCTIONAL MATERIALS
(2015)
Article
Chemistry, Inorganic & Nuclear
Qun Tang, Shuxia Liu, Yiwei Liu, Danfeng He, Jun Miao, Xingquan Wang, Yujuan Ji, Zhiping Zheng
INORGANIC CHEMISTRY
(2014)
Article
Chemistry, Multidisciplinary
Weiguang Kong, Wang Li, Chanwen Liu, Hui Liu, Jun Miao, Weijun Wang, Shi Chen, Manman Hu, Dedi Li, Abbas Amini, Shaopeng Yang, Jianbo Wang, Baomin Xu, Chun Cheng
Article
Chemistry, Physical
Puttaswamy Madhusudan, Yu Wang, Bananakere Nanjegowda Chandrashekar, Weijun Wang, Jingwei Wang, Jun Miao, Run Shi, Yuxing Liang, Guojun Mi, Chun Cheng
APPLIED CATALYSIS B-ENVIRONMENTAL
(2019)
Article
Multidisciplinary Sciences
Junjie Hao, Haochen Liu, Jun Miao, Rui Lu, Ziming Zhou, Bingxin Zhao, Bin Xie, Jiaji Cheng, Kai Wang, Marie-Helene Delville
SCIENTIFIC REPORTS
(2019)
Article
Chemistry, Multidisciplinary
Junjie Hao, Yiwen Li, Jun Miao, Rulin Liu, Jiagen Li, Haochen Liu, Qiushi Wang, Huan Liu, Marie-Helene Delville, Tingchao He, Kai Wang, Xi Zhu, Jiaji Cheng
Article
Chemistry, Physical
Shuzhang Niu, Si-Wei Zhang, Run Shi, Jingwei Wang, Weijun Wang, Xiaomei Chen, Zhuoqiong Zhang, Jun Miao, Abbas Amini, Yusheng Zhao, Chun Cheng
ENERGY STORAGE MATERIALS
(2020)
Review
Chemistry, Multidisciplinary
Jun Miao, Zhongling Lang, Tianyu Xue, Yan Li, Yiwen Li, Jiaji Cheng, Han Zhang, Zikang Tang
Article
Nanoscience & Nanotechnology
Zhongling Lang, Jun Miao, Yangchun Lan, Jiaji Cheng, Xiaoqian Xu, Chun Cheng
Article
Chemistry, Multidisciplinary
Xiaofeng Fan, Wei Pang, Hao Feng, Ruiyi Zhang, Wentao Zhu, Qiushi Wang, Jun Miao, Yiwen Li, Yanjun Liu, Xiaoqian Xu
Summary: This article provides a brief introduction to the application of metal-oxide clusters in cancer treatment, with a focus on their biocompatibility and diagnostic and photochemotherapy performance. It summarizes the development of next-generation multifunctional cancer targeting agents and discusses future research directions.
CHINESE CHEMICAL LETTERS
(2022)
Article
Chemistry, Inorganic & Nuclear
Zhongling Lang, Jun Miao, Huaqiao Tan, Zhongmin Su, Yangguang Li, Zhiping Zheng
INORGANIC CHEMISTRY FRONTIERS
(2020)
Article
Chemistry, Multidisciplinary
Xiongbin Wang, Junjie Hao, Jiaji Cheng, Junzi Li, Jun Miao, Ruxue Li, Yiwen Li, Jiagen Li, Yuhui Liu, Xi Zhu, Yanjun Liu, Xiao Wei Sun, Zikang Tang, Marie-Helene Delville, Tingchao He, Rui Chen
Article
Nanoscience & Nanotechnology
Jun Miao, Yulong Chen, Yiwen Li, Jiaji Cheng, Qingyin Wu, Kar Wei Ng, Xin Cheng, Rui Chen, Chun Cheng, Zikang Tang
ACS APPLIED NANO MATERIALS
(2018)
Article
Engineering, Environmental
Shumei Liu, Yiwei Liu, Shaoping Jiang, Shuxia Liu, Danfeng He, Ning Li, Jun Miao, Jinhua Ye
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2016)
Article
Chemistry, Applied
Leping Chen, Yanfen Wang, Tingyu Shi, Tiantian Ma, Yang Li, Huayu Qiu, Shouchun Yin, Meier Gu
Summary: This study successfully overcame the limitations of the heavy atom effect by introducing iodine atoms and innovatively enhancing the structure while weakening stacking behavior, achieving high efficiency and precision in photodynamic therapy and photothermal therapy.
Article
Chemistry, Applied
Bingpeng Guo, Honghan Sa, Peng Zhang, Guiwen Hao, Mengyu Li, Qingqing Jiang, Baoying Li, Wei Shu, Changxiang Shao
Summary: The design of ratiometric fluorescence probes with large Stokes shift is of great significance in detecting and imaging target substances in complex organisms. In this study, a novel fluorophore with a large Stokes shift was easily obtained, and a fluorescence probe based on it demonstrated rapid response, high selectivity, and sensitivity towards peroxynitrite. The probe also showed excellent biocompatibility and remarkable mitochondrial targeting ability, making it suitable for proportional imaging of peroxynitrite in living cells and zebrafish.
Review
Chemistry, Applied
Haidong Huang, Xiaohui Wang, Xinyang Li, Yichen Li, Guojin Liu, Lan Zhou, Jianzhong Shao
Summary: This article introduces the application of responsive photonic crystals in anti-counterfeiting technology, with a focus on the preparation principle, classification, and preparation methods.
Article
Chemistry, Applied
Yunpeng Wang, Tao Zhao, Xiaoye Bi, Chencheng Lv
Summary: In this study, three novel carbene dyes were designed to achieve environmentally friendly dyeing processes. The dyes formed covalent bonds with fibers and exhibited good dyeing performance and high color fastness. These findings highlight the potential of the novel carbene dyes in promoting green production in the textile industry.
Review
Chemistry, Applied
Yizhe Yan, Xiaopei Zhu, Jia-Xin Cao, Yuan He, Shaoqing Li, Jian-Yong Wang
Summary: In this paper, 1,3,5-triazine dyes were successfully synthesized and their photophysical properties were studied. Two probes were selected for further investigation, showing promising applications in various fields.
Article
Chemistry, Applied
Xin Hu, Tongsheng Huang, Lihua Chen, Weifeng Zhu, Fengjie Deng, Xiancai Li, Jianwen Tian, Meiying Liu, Xiaoyong Zhang, Yen Wei
Summary: This study presents the synthesis of fluorescent cyclomatrix polyphosphazene spheres with aggregation-induced emission (AIE) feature and biodegradable potential for controlled drug delivery. The resulting micelles exhibit high water dispersibility, desirable fluorescence performance, and high drug loading capacity. They can effectively release the encapsulated drug in physiological solution and show excellent biological imaging ability and cytotoxicity against cancer cells.
Article
Chemistry, Applied
Yanzhu Liu, Yanghui Lei, Dongyan Li, Guangkui Li, Dongping Li, Yongxiu Li
Summary: In this study, luminescent lanthanide nanoparticles were synthesized as a dual emission turn-off probe for detecting 2,6-pyridinedicarboxylic acid (DPA) in water. The nanoparticles showed good dispersion and water stability, and achieved low detection limits for DPA. They also exhibited high recoveries in various samples.
Article
Chemistry, Applied
Jung Jae Do, Jong Ryeol Kwon, Donghan Kim, Jae Woong Jung
Summary: This study presents a defect passivation approach using coumarin dye as a multi-functional passivating agent of perovskite films to boost power conversion efficiency and operating stability of PSCs. The incorporation of coumarin dye improves the film morphology, enhances carrier extraction/transport, and suppresses trap-assisted recombination in the perovskite films. The optimized device demonstrates impressive reliability and practical applicability, maintaining over 90% of its initial PCE after being exposed to continuous indoor lighting irradiation for 2000 hours.
Article
Chemistry, Applied
Gang Wang, Yu-Chang Wang, Jing Lu, Wen-Fu Yan, Juan Jin, Yuan-Peng Wang, Jia-Jia Zhang, Hui-Jie Zhang, Hao Dong, Xi-Guang Liu
Summary: A new Ni(II) compound with good solid-state fluorescence performance and stability was synthesized, and it showed outstanding detection properties for various substances in aqueous solutions. This compound has the potential to be a multifunctional sensor.
Article
Chemistry, Applied
Luyao Wei, Shenglong Shang, Yu Zheng, Jie Liu, Ping Zhu
Summary: This study developed a facile method to create high saturation and durable structural colors on cotton fabrics. The colors are regulated by adjusting the size of magnetic particles and can be conveniently printed on fabrics using photo masks on transparent films.
Article
Chemistry, Applied
Zhao Jiang, Qing Zhang, Zhaoyu Kong, Ruijie Qiao, Zichuan Liu, Linzhou Song, Senqiang Zhu, Rui Liu, Hongjun Zhu
Summary: Three heteroleptic Ir(III) complexes with different electron-donating aryl groups were synthesized and their optical properties were investigated. It was found that all three complexes exhibited aggregation-induced phosphorescence emission (AIPE) behaviors, and the relationship between the size of organic ligands and AIPE behaviors was characterized. Ir-PhCz showed the best imaging of latent fingerprints due to its green light emission and high quantum yield.
Article
Chemistry, Applied
Zhijun Ruan, Chunxia Fan, Xuanrong Wang, Dong Shao, Xiaodong Yang, Wentao He, Tao Xu, Junqi Lin, Zhengfang Tian
Summary: A novel thioketal-based probe has been designed for rapid and accurate detection of mercury (II) ions, showing different fluorescence characteristics in various states. The probe exhibits excellent selectivity and specificity, making it suitable for Hg2+ detection in water solutions.
Article
Chemistry, Applied
Jianjun Huang, Xuan Zhao, Daniel Escudero, Luc Van Meervelt, Dongbin Zheng, Yuyu Fang, Wim Dehaen
Summary: A series of BOAHY compounds were successfully synthesized and showed versatile applications as a platform for designing novel fluorescent probes, especially in selective recognition.
Article
Chemistry, Applied
Roman V. Larkovich, Victoria E. Shambalova, Savva A. Ponomarev, Alexander S. Aldoshin, Boris N. Tarasevich, Konstantin A. Lyssenko, Valentine G. Nenajdenko
Summary: An efficient synthetic protocol for the preparation of novel 1,7-difluorinated BODIPYs was elaborated. Their photophysical properties were studied and the effect of 2,6-substituents was evaluated using DFT calculations.
Article
Chemistry, Applied
Haneul Kim, Byungjin Koo
Summary: In this study, a lithium ion sensing methodology based on fluorinated naphthalene compounds using 19F NMR and UV-vis spectroscopy is reported. The binding of lithium ions to the compounds is confirmed by changes in chemical shifts and peak broadening. Additionally, the effect of different crown ether ring sizes on the binding ability is observed. This study provides a new method for lithium ion sensing using spectroscopy.