Adsorption thermodynamics and kinetics of yohimbine onto strong acid cation exchange fiber

The strong acidic cationic exchange fiber (SACEF) was used to adsorb yohimbine from alcoholic solution. Batch experiments were performed to examine the effects of adsorbent dosage, solution pH and temperature in the adsorption process. The thermodynamics and kinetics of adsorption were also analyzed. The optimum yohimbine adsorption onto the SACEF was found at pH = 5 of solution and equilibrium could be attained within 20 min. The equilibrium adsorption data were preferably modeled with the Freundlich isotherm model and the thermodynamic parameters were calculated to be: 11.99 kJ/mol < Delta H < 13.72 kJ/mol, -21.17 kJ/mol < Delta G < 17.87 kJ/mol and 63.18 J/mol K < Delta S < 65.60 J/mol K. The results demonstrated that the adsorption was an endothermic, spontaneous and feasible process of physisorption. Meanwhile, yohimbine adsorption on SACEF fitted well to the pseudo-second-order kinetic model and the adsorption rate was limited by film diffusion. The activation energy Ea was calculated to be 14.39 kJ/mol. Furthermore, the surface morphologies of the SACEF before and after yohimbine adsorption were analyzed by SEM and the adsorption mechanism was discussed by FTIR analysis. SACEF could effectively adsorb yohimbine from alcoholic solution and could be used repeatedly for more than five cycles. (C) 2016 Taiwan Institute of Chemical Engineers. Published by Elsevier B.V. All rights reserved.