4.2 Article

Spinel cobalt manganese oxide nano-composites grown hydrothermally on nanosheets for enhanced photocatalytic mineralization of Acid Black 1 textile dye: XRD, FTIR, FESEM, EDS and TOC studies

Journal

JOURNAL OF THE IRANIAN CHEMICAL SOCIETY
Volume 14, Issue 8, Pages 1643-1649

Publisher

SPRINGER
DOI: 10.1007/s13738-017-1104-2

Keywords

CoMn2O4; Nano-composite; Nanosheets; Acid Black 1

Funding

  1. University of Isfahan

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Spinel cobalt manganese oxide nano-composites were grown on nanosheets using acetate precursors in mono-ethylene glycol. Crystal structures and morphologies of nano-composites were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy and energy dispersive X-ray spectroscopy to characterize the element composition. Fourier transform infrared spectroscopy was used for structural characterization and UV-Vis diffuse reflectance spectra (UV-Vis DRS) for optical properties. XRD results showed tetragonal spinel cobalt manganese oxide (Co,Mn)(Co,Mn)(2)O-4 and cubic spinel cobalt manganese oxide MnCo2O4.5 structural phases. The crystallite size calculated by the Scherrer's equation was 17 nm. The morphological studies displayed the existence of 40-63 nm nano-powders grown on nanosheets with a good degree of crystallization. Optical properties of cobalt manganese oxide nano-composites exhibit absorbance edge, and the band gap calculated from UV-Vis DRS results was 1.78 eV. FTIR spectra indicated that hydroxyl and oxide groups were major active sites. The absorption bands observed at 656 and 568 cm(-1) are related to stretching vibrations of Mn-O and Co-O, respectively. The photocatalytic activities of nano-composites for photocatalytic mineralization of Acid Black 1 textile dye showed an outstanding performance. Photocatalytic process yielded 91% total organic carbon removals within 2.5 h of irradiation. The enhanced photocatalytic activity was attributed to better charge separation of the photo-generated electron-hole pairs in nano-composite.

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