4.4 Article

Microbial sulphate reduction during Neoproterozoic glaciation, Port Askaig Formation, UK

Journal

JOURNAL OF THE GEOLOGICAL SOCIETY
Volume 174, Issue 5, Pages 850-854

Publisher

GEOLOGICAL SOC PUBL HOUSE
DOI: 10.1144/jgs2016-147

Keywords

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Funding

  1. Natural Environment Research Council (NERC) - Isotope Community Support Facility at SUERC
  2. NERC [NE/L001764/1]
  3. NERC [icsf010001] Funding Source: UKRI
  4. Natural Environment Research Council [NE/L001764/1, icsf010001] Funding Source: researchfish

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The Neoproterozoic Port Askaig Formation contains widespread pyrite within many diamictite beds, across Scotland and Ireland. The quantity of pyrite is anomalous for coarse-grained rocks, especially in rocks deposited at a time when seawater contained low sulphate levels owing to a continental ice cover, which inhibited weathering. Sulphur isotope compositions evolve from lightest values (down to -3.1 parts per thousand) at the base of the formation to highly positive compositions in the overlying Bonahaven Dolomite (mean +44.8 parts per thousand). This trend is consistent with progressive utilization of available sulphate by closed-system microbial sulphate reduction. Together with records from other contemporary diamictite successions, there emerges a picture of global microbial activity during Neoproterozoic 'Snowball Earth' glaciation.

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