Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 139, Issue 2, Pages 623-626Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.6b12161
Keywords
-
Categories
Funding
- NSFC [21372268]
- Fundamental Research Funds for the Central Universities [106112016CDJZR228806]
- Graduate Scientific Research and Innovation Foundation of Chongqing [CYB16033]
Ask authors/readers for more resources
A chemoselective ring-opening protocol of the formal [2+2] cycloadducts of 3-triflyloxyarynes was developed to generate 2,3-aryne intermediate via Grob fragmentation. A variety of 1,3-di- and 1,2,3-trisubstituted arenes could be readily accessed through this [2+2] cycloaddition-2,3-aryne formation sequence. The regioselectivity in these transformations originates from the steric repulsion of the aliphatic chain.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available