Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 139, Issue 12, Pages 4338-4341Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b01266
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Funding
- Italian MIUR (PRIN Project HYFSRT)
- Fondazione Ente Cassa di Risparmio di Firenze
- European COST [CA15128 MOLSPIN]
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Here we report the investigation of the magnetization dynamics of a vanadyl complex with diethyldithiocarbamate (Et(2)dtc(-)) ligands, namely [VO-(Et(2)dtc)(2)] (1), in both solid-state and frozen solution. This showed an anomalous and unprecedentedly observed field dependence of the relaxation time, which was modeled with three contributions to the relaxation mechanism. The temperature dependence of the weight of the two processes dominating at low fields was found to well correlate with the low energy vibrations as determined by THz spectroscopy. This detailed experimental comparative study represents a fundamental step to understand the spin dynamics of potential molecular quantum bits, and enriches the guidelines to design molecule-based systems with enhanced quantum coherence.
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