Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 139, Issue 25, Pages 8455-8457Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b05640
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Funding
- Engineering and Physical Sciences Research Council (UK)
- Royal Society
- EPSRC [EP/H021620/2] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/H021620/2] Funding Source: researchfish
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We report on the synthesis of [2]rotaxanes driven by stabilization of the axle-forming transition state. A bifunctional macrocycle, with hydrogen bond donors at one end and acceptors at the other, is used to stabilize the charges that develop during the addition of a primary amine to a cyclic sulfate.
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