Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 140, Issue 1, Pages 114-117Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b11245
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Funding
- JSPS [26220802]
- Grants-in-Aid for Scientific Research [17H06451] Funding Source: KAKEN
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The C-H addition of sulfides to alkenes is an atom-efficient route for the functionalization and modification of sulfide compounds through C-C bond formation, but this transformation is highly challenging. We report here the regioselective alpha-C(sp(3))-H addition of a wide range of methyl sulfides to a variety of olefins and dienes by a half-sandwich scandium catalyst. This protocol provides a unique route for the synthesis of diverse sulfide derivatives through C-C bond formation at a sulfur-adjacent carbon atom in a 100% atom efficient fashion.
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