Extractant (2,3-dimethylbutyl)(2,4,4′-trimethylpentyl)phosphinic acid (INET-3) impregnated onto XAD-16 and its extraction and separation performance for heavy rare earths from chloride media

(2,3-Dimethylbutyl)(2,4,4'-trimethylpentyl)phosphinic acid (INET-3) was impregnated onto dry macroporous resins XAD-16 and pretreated XAD-16 with ethyl alcohol and HCl (Pre-XAD-16) to prepare the solvent impregnated resins SIRs-INET-3/XAD-16 and SIRs-INET-3/Pre-XAD-16. The molecular weight distribution of the low molecular weight (LMW) polymers washed off by ethyl alcohol during XAD-16 pretreatment was determined by gel permeation chromatography (GPC). The macroporous resins (XAD-16 & Pre-XAD-16), the corresponding solvent impregnated resins (SIRs-INET-3/XAD-16 & SIRs-INET-3/Pre-XAD-16) and the PVA coated SIRs-INET-3/Pre-XAD-16 with boric acid as cross-linking agent were characterized by FT-IR, SEM-EDS and TGA. The effects of XAD-16 pretreatment and PVA coating technology on RE(III) adsorption equilibrium time, INET-3 losses during extraction and adsorption capacity were investigated. The adsorption kinetics, selectivity and stripping behaviors of SIRs-INET-3/XAD-16 were further studied. The washed off LMW polymers had the Mn of 36,656, Mw of 40,310 and polydispersity coefficient of 1.10. The SIRs-INET-3/XAD-16 had shorter equilibrium time, less INET-3 loss and more Tm(III) adsorption capacity than the SIRs-INET-3/Pre-XAD-16. The PVA coated SIRs-INET-3/Pre-XAD-16 had less INET-3 loss and more Tm(III) adsorption capacity but longer equilibrium time than the uncoated SIRs-INET-3/Pre-XAD-16. The adsorption of RE(III) on the SIRs-INET-3/XAD-16 followed the pseudo-second-order kinetic model. The Tm(III) accumulative adsorption amounts onto SIRs-INET-3/XAD-16 after eight extraction stages was 23.6 mg/g. The separation factors of adjacent heavy RE(III) beta(Er/Ho), beta(Tm/Er), beta(Yb/Tm) and beta(Lu/Yb) values were 1.76, 2.59, 2.56 and 1.19, respectively. The adsorbed Lu(III) onto the SIRs-INET-3/XAD-16 can be stripped completely by 1.0 mol/L H2SO4. (c) 2017 Published by Elsevier B.V. on behalf of Chinese Society of Rare Earths.