Journal
JOURNAL OF RARE EARTHS
Volume 35, Issue 2, Pages 164-171Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/S1002-0721(17)60895-0
Keywords
high-level radioactive waste; waste form; zircon; chemical durability; rare earths
Categories
Funding
- National Natural Science Foundation of China [21507105, 41302029]
- Thousand Youth Talents Plan [Y42H831301]
- Key Project of Sichuan Education Department [15ZB0116]
- Foundation of Laboratory of National Defense Key Discipline for Nuclear Waste and Environmental Safety
- Southwest University of Science and Technology [15yyhk10]
- Doctor Foundation in Southwest University of Science and Technology [10zx7126]
- Sichuan's Training Program of Innovation and Entrepreneurship for Undergraduate [201610619039]
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Zircon was employed to immobilize simulated tetravalentactinide nuclide (Ce4+). Zr1-x,CexSiO4(0 <= x <= 0.10) ceramics were synthesized and their chemical durabilities were investigated systematically. The effects of pH and temperature on the chemical durability of the as-prepared compounds were investigated using the MCC-1 static leaching test, and their coupling effects were also explored. It was found that the normalized release rates of Ce in deionized water and alkaline solutions (pH=10) were smaller than those in acid solutions (p11=4). At a certain pH value, the normalized release rate of Ce (LRCe) increased with the temperature in the initial period. However, the leaching progress almost reached a balance after 14 days, and both of the pH and the temperature had slight impact on the leaching of Ce element. Moreover, the LR(Ce)were below 10(-5) g/m(2)/d after 42 days, which was lower than those of other nuclear waste forms in all discussed leachates.
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