4.5 Article

Absolute frequency determination of molecular transition in the Doppler regime at kHz level of accuracy

Journal

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jqsrt.2017.07.010

Keywords

Transition frequency; Absolute frequency measurement; Optical atomic clock; Oxygen B band; Cavity ring-down spectroscopy

Funding

  1. National Laboratory FAMO in Torun, Poland
  2. National Science Center, Poland [2014/15/D/ST2/05281, DEC-2012/05/D/ST2/01914, DEC-2013/11/D/ST2/02663, 2015/17/B/ST2/02115]
  3. COST Action [CM1405 MOLIM]
  4. EMPIR programme
  5. European Union's Horizon research and innovation programme [EMPIR 1551803 OC18]

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We measured absolute frequency of the unperturbed P7 P7 O-2 B-band transition v(0) =434783.5084857(82)GHz and the collisional self-shift coefficient delta =-9.381(62) x 10(-21) GHz/(molecule/cm(3)). With Doppler-limited spectroscopy we achieved the relative standard uncertainty of 2 x 10(-11) on line position, typical for Doppler-free techniques. Shapes of the spectral line were measured with a Pound-Drever-Hall-locked frequency-stabilized cavity ring-down spectrometer referenced to an Sr-88 optical atomic clock via an optical frequency comb. (C) 2017 Elsevier Ltd. All rights reserved.

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