4.8 Article

High efficiency of CO2-activated graphite felt as electrode for vanadium redox flow battery

Journal

JOURNAL OF POWER SOURCES
Volume 364, Issue -, Pages 1-8

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2017.07.103

Keywords

Vanadium redox flow battery; Electrode; CO2-activation

Funding

  1. Institute of Nuclear Energy Research, Atomic Energy Council

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A simple method for preparing CO2-activated graphite felt as an electrode in a vanadium redox flow battery (VRFB) was employed by the direct treatment in a CO2 atmosphere at a high temperature for a short period. The CO2-activated graphite felt demonstrates excellent electrochemical activity and reversibility. The VRFB using the CO2-activated graphite felts in the electrodes has coulombic, voltage, and energy efficiencies of 94.52%, 88.97%, and 84.15%, respectively, which is much higher than VRFBs using the electrodes of untreated graphite felt and N-2-activated graphite felt. The efficiency enhancement was attributed to the higher number of oxygen-containing functional groups on the graphite felt that are formed during the CO2-activation, leading to improving the electrochemical behaviour of the resultant VRFB. (C) 2017 Elsevier B.V. All rights reserved.

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