Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 121, Issue 29, Pages 15931-15936Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpcc.7b04793
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Funding
- National Research Foundation of Korea (NRF) Grant - Korea government (MSIP) [NRF-2015R1A2A1A10055620]
- MOTIE (Ministry of Trade, Industry and Energy) [10051463]
- KDRC (Korea Display Research Corporation) support program for the development of future devices technology for display industry
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A new donor donor copolymer consisting of phenanthro[1,10,9,8-cdefg]carbazole and thiophene unit (PP-Th) was synthesized for narrow band green-selective organic photodiode application. Thanks to well-defined intramolecular conjugation and inhibited intermolecular interaction of PP-Th compared to its donor- acceptor type analogues, PP-Th revealed narrow band green-selective absorption peak at 510 nm with low full width at half-maximum value of 98 nm. In addition, deep ionization energy of PP-Th, as confirmed by photophysical analyses, made it less susceptible to oxidational degradation. Green-selective organic photodiodes (OPDs) were fabricated utilizing PP-Th as a green absorbing donor material and ZnO as a nonabsorbing acceptor material. The optimized OPD rendered a very low dark current of 2 nA cm(-2) and a high detectivity of 1.42 x 10(12) Jones with narrow band green-selectivity. Moreover, PP-Th enabled OPD with a high 3-dB bandwidth of 3.1 kHz and a high linear dynamic range of 84.9 dB. Furthermore, the responsivity of the OPD could be maintained for more than 30 days under atmospheric condition, revealing excellent stability of PP-Th.
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