4.5 Article

Cobalt bis(dicarbollide) anion and its derivatives

Journal

JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 849-850, Issue -, Pages 170-194

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2017.04.006

Keywords

Metallacarboranes; Sandwich complexes; Cobalt bis(dicarbollide) anion; Functionalization; Oxonium ring opening

Funding

  1. DST-SERB
  2. UGC, Govt. of India
  3. European Commission
  4. NSF

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Owing to high chemical and thermal stability, ionic character, low nucleophilicity and peculiar solubility, cobalt bis(dicarbollide) anion occupies a unique position among the metallacarboranes. Derivatives of cobalt bis(dicarbollide) find applications in different areas such as in the treatment of nuclear waste, conducting polymers and medicinal chemistry. In this paper, we have presented an overview of cobalt bis(dicarbollide) anion and its derivatives. (C) 2017 Elsevier B.V. All rights reserved.

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