Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 82, Issue 18, Pages 9525-9536Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.7b01547
Keywords
-
Categories
Funding
- IISc, SERB, New Delhi [SB/S1/OC-56/2013]
- RL Fine Chem
- CSIR
- IISc
Ask authors/readers for more resources
A successful synthesis of alpha-fluoro-beta-ketosulfides using an electrophilic fluorination method has been reported for the first time. The reaction proceeds via an electrophilic fluorination of alpha-sulfenyl-beta-diketones followed by an unexpected tandem deacylation. The resulting products, alpha-fluoro-beta-ketosulfides, are easily oxidized to the corresponding alpha-fluoro-beta-ketosulfones, which can be used for further useful olefination reactions.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available