4.7 Article

1-Butyl-3-methylimidazol-2-ylidene Borane: A Readily Available, Liquid N-Heterocyclic Carbene Borane Reagent

Journal

JOURNAL OF ORGANIC CHEMISTRY
Volume 82, Issue 24, Pages 13746-13750

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.7b02730

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Funding

  1. National Science Foundation [CHE-1660927]

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1-Butyl-3-methylimidazol-2-ylidene borane has been synthesized directly from two inexpensive commercial reagents: 1-butyl-3-methylimidazolium bromide and sodium borohydride. This NHC-borane reagent is a stable, free-flowing liquid that shows promise for use in radical, ionic, and metal-catalyzed reactions.

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