4.4 Article

Pressure dependent wall slip of wood flour filled polymer melts

Journal

JOURNAL OF NON-NEWTONIAN FLUID MECHANICS
Volume 247, Issue -, Pages 178-187

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.jnnfm.2017.07.002

Keywords

Wood polymer composite; Wall slip; In-line rheometry; Modeling; Pressure dependence

Categories

Ask authors/readers for more resources

The Theological properties of a 50 wt.% wood flour filled polypropylene have been measured at 195 degrees C using an instrumented slit die attached to a single screw extruder. Wall slip and non-Newtonian effects have been corrected through the Mooney and Rabinowitsch procedures, thus equations for viscosity and wall slip have been obtained. Interestingly, the pressure drop profiles calculated using these equations are not perfectly consistent with the experimental pressure measurements, in that the theoretical curves overestimate the experimental data. An explanation has been sought by assuming that slip velocity increases in the last portion of the slit die, i.e. close to the exit, where pressure drops down considerably. A pressure dependent slip model has been then proposed, its specific equations numerically solved and the results fitted to the experimental pressure data. The fitting is better than the one coming from the model that comprises slip depending on shear stress only, thus, for the fluid that has been studied, the assumption of pressure dependent slip appears to be justified. (C) 2017 Elsevier B.V. All rights reserved.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.4
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Polymer Science

Correlation between Mechanical Properties and Processing Conditions in Rubber-Toughened Wood Polymer Composites

Valentina Mazzanti, Lorenzo Malagutti, Andrea Santoni, Francesca Sbardella, Andrea Calzolari, Fabrizio Sarasini, Francesco Mollica

POLYMERS (2020)

Article Engineering, Manufacturing

Natural fiber-induced degradation in PLA-hemp biocomposites in the molten state

V Mazzanti, M. Salzano de Luna, R. Pariante, F. Mollica, G. Filippone

COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING (2020)

Review Polymer Science

A Review of Wood Polymer Composites Rheology and Its Implications for Processing

Valentina Mazzanti, Francesco Mollica

POLYMERS (2020)

Article Dentistry, Oral Surgery & Medicine

Comparative analysis of passive play and torque expression in self-ligating and traditional lingual brackets

Paolo Albertini, Valentina Mazzanti, Francesco Mollica, Luca Lombardo, Giuseppe Siciliani

Summary: This study aimed to determine and compare the play and torque expression of different types of self-ligating and conventionally ligated lingual brackets engaged with archwires of varying characteristics. Results showed that certain brands performed better at higher torsional loads.

JOURNAL OF OROFACIAL ORTHOPEDICS-FORTSCHRITTE DER KIEFERORTHOPADIE (2022)

Article Polymer Science

Tribological Behavior of a Rubber-Toughened Wood Polymer Composite

Valentina Mazzanti, Annalisa Fortini, Lorenzo Malagutti, Giulia Ronconi, Francesco Mollica

Summary: This study investigated the effect of a toughening agent on the tribological behavior of wood polymer composites, showing that the agent improved wear resistance but water soaking pre-treatment caused severe damage.

POLYMERS (2021)

Article Engineering, Environmental

Glycolysis of semi-interpenetrated polymer network foam based on poly (vinyl chloride) for recovery and reuse of the individual components

Matteo Calosi, Marco Renon, Giada Belletti, Valentina Mazzanti, Francesco Mollica, Alessandro Massi, Monica Bertoldo

Summary: This study focuses on the depolymerization of rigid semi-Interpenetrated Polymer Network (semi-IPN) foam based on poly(vinyl chloride) (PVC) and cross-linked polyurea/isocyanurate, aiming to separate and reuse the individual components. By optimizing the glycolysis conditions, the researchers successfully depolymerized the crosslinked portion and recovered PVC with minimal degradation.

WASTE MANAGEMENT (2022)

Proceedings Paper Polymer Science

Processing-Properties Correlation for a Rubber Toughened Wood Plastic Composite

Valentina Mazzanti, Lorenzo Malagutti, Francesca Sbardella, Francesco Mollica

Summary: Wood Polymer Composites (WPCs) are gaining attention as environmentally friendly materials. Increasing wood content reduces the environmental impact, but it also leads to drawbacks such as brittleness and reduced processability. This study focuses on reducing brittleness by adding a toughening agent and finding the optimal processing conditions and elastomer content.

MACROMOLECULAR SYMPOSIA (2022)

Proceedings Paper Polymer Science

A MATLAB-Based Software for Estimating Measurement Uncertainties in Capillary Viscometry

Lorenzo Malagutti, Valentina Mazzanti, Francesco Mollica

Summary: The Mooney wall slip correction procedure is necessary for rheological characterization of complex fluids that tend to slip at solid walls during capillary viscometry. The imprecise knowledge of the capillary radius in the Mooney procedure can amplify measurement errors, even if the uncertainty is small. This study proposes a MATLAB-based software to determine the maximum allowable inaccuracy of the capillary diameter for feasible data in fluid characterization, with prior knowledge of the unknown fluid's constitutive characteristics being ideal for the best results.

MACROMOLECULAR SYMPOSIA (2022)

Article Engineering, Chemical

A Post-Processing Method for Improving the Mechanical Properties of Fused-Filament-Fabricated 3D-Printed Parts

Lorenzo Malagutti, Giulia Ronconi, Marco Zanelli, Francesco Mollica, Valentina Mazzanti

Summary: Fused-filament fabrication is a popular 3D printing technique, but its mechanical properties limit its use in structural applications. Post-processing methods, such as remelting and compaction, can improve mechanical properties and make the material more isotropic.

PROCESSES (2022)

Article Materials Science, Multidisciplinary

Infill Density Effects on the Mechanical and Thermal Properties of Copper-Plated 3D Printed Parts

Tommaso Ludergnani, Giulia Fredi, Lorenzo Malagutti, Andrea Balbo, Andrea Dorigato, Francesco Mollica, Valentina Mazzanti

Summary: FFF is a low-cost 3D-printing technique that allows for the production of complex geometries with high customization. A two-step metallization method using a non-toxic and cost-effective plating solution is performed to enhance the mechanical and thermal properties of FFF-printed parts. The study finds that an infill density of 50-60% provides the best compromise between mechanical performance and thermal conductivity.

MACROMOLECULAR MATERIALS AND ENGINEERING (2023)

Article Materials Science, Multidisciplinary

Morphology and Mechanical Properties of Poly(vinyl alcohol)/Poly(lactic acid) Blend Films Prepared from Aqueous Dispersions

Giada Belletti, Giulia Ronconi, Valentina Mazzanti, Elena Buratti, Lorenzo Marchi, Giovanna Sotgiu, Matteo Calosi, Francesco Mollica, Monica Bertoldo

Summary: This study reports the preparation and characterization of poly(vinyl alcohol) (PVA)/poly(lactic acid) (PLA) blends of different compositions. Films of PLA and its blends with PVA were obtained by drying water dispersions. The morphology of the films showed a PVA-rich continuous phase, except for the 25/75 composition where an inverted phase composition was observed. Trapped air bubbles caused voids in the films and affected their thermal degradation and mechanical properties. Films with a neutral stabilizer showed improved toughness compared to commercial PLA, with properties depending on the composition and arrangement of blend phases.

MACROMOLECULAR MATERIALS AND ENGINEERING (2023)

Article Dentistry, Oral Surgery & Medicine

Assessment of stiffness and load deflection of orthodontic miniscrews used for palatal anchorage: An in vitro biomechanical study

Anna Colonna, Margherita Drudi, Giorgio Alfredo Spedicato, Francesco Mollica, Valentina Mazzanti, Emanuele Paoletto, Giuliano Maino, Giuseppe Siciliani, Luca Lombardo

INTERNATIONAL ORTHODONTICS (2020)

Article Mechanics

The similarity theory of free turbulent shear flows of viscoelastic fluids

Mateus C. Guimaraes, Fernando T. Pinho, Carlos B. da Silva

Summary: A new theory is proposed to describe the conformation state of polymer chains in free turbulent shear flows of viscoelastic fluids. The theory shows the existence of minimum and maximum solvent dissipation reduction asymptotes and four different polymer deformation regimes, based on self-similarity arguments and new scaling relations for the turbulent flux of conformation tensor. In addition, analytical solutions for the self-similar transverse profiles of the conformation tensor components are obtained. The theory is validated through excellent agreement with direct numerical simulations employing the FENE-P rheological model.

JOURNAL OF NON-NEWTONIAN FLUID MECHANICS (2024)