Journal
JOURNAL OF MOLECULAR STRUCTURE
Volume 1134, Issue -, Pages 591-598Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.molstruc.2017.01.005
Keywords
Bio-polymer; Biaryls; Schiff base; Microwave; Reusability
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Funding
- Aksaray University Scientific Research Projects [2016-021]
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In this paper we described the fabrication, characterization and application of a new biopolymer (chitosan)-based pincer-type Pd(II) catalyst in Suzuki cross coupling reactions using a non-toxic, cheap, ecofriendly and practical method. The catalytic activity tests showed remarkable product yields as well as TON (19800) and TOF (330000) values with a small catalyst loading. In addition, the catalyst indicated good recyclability in the Suzuki C-C reaction. This biopolymer supported catalyst can be used with various catalyst systems due to its unique properties, such as being inert, green in nature, low cost and chemically durable. (C) 2017 Elsevier B.V. All rights reserved.
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