Article
Chemistry, Physical
Chenglong Zhang, Jin Wu, Ruixue Wang, En Ma, Liang Wu, Jianfeng Bai, Jingwei Wang
Summary: Ionic liquids are promising solvents for the absorption of volatile organic compounds. By studying the effects of different structural features on solubility, potential solvents can be identified and the relationship between various interaction energy parameters and solubility can be determined. The study provides a fundamental basis and practical data for the control and treatment of VOCs.
GREEN ENERGY & ENVIRONMENT
(2021)
Article
Engineering, Chemical
Di Zhao, Chen Liu, Yonggang Wang, Haiyong Zhang
Summary: In this study, ionic liquids were utilized to separate anthracene and carbazole, resulting in highly efficient solvents with improved purity of the refined compounds. The separation mechanism of anthracene and carbazole was also discussed in detail, showcasing the potential of ILs in chemical industry applications.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)
Article
Chemistry, Physical
Sulafa Abdalmageed Saadaldeen Mohammed, Wan Zaireen Nisa Yahya, Mohamad Azmi Bustam, Md Golam Kibria, Asiah Nusaibah Masri, Nurul Diyana Mohd Kamonwel
Summary: Ionic liquids (ILs) as electrolytes have unique properties and have attracted attention. This study experimentally evaluated the reduction potentials of five ILs and investigated the parameters that affect their reduction stability. It was found that considering the molecular interaction is crucial for predicting the reduction stability, rather than solely relying on the individual energy levels of the cations or anions.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Chemistry, Physical
Amir Sada Khan, Taleb Ibrahim, Noor Akbar, Mustafa Khamis, Ruqaiyyah Siddiqui, Paul Nancarrow, Farouq Sabri Mjalli, Naveed Ahmed Khan, Nabil Abdel Jabbar
Summary: In this study, the efficiency of three ionic liquids with a common cation trioctylammonium and different anions for removing phenol from aqueous solution was investigated. The [TOA][4-phenylbutanoate] ionic liquid showed the best performance and was further optimized for process parameters. The interaction modes between these ionic liquids and phenol were modeled, and their cytotoxicity towards human cells was found to be lower than commonly used alternatives.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Engineering, Chemical
Xiao Xu, Gilles Van Eygen, Cristhian Molina-Fernandez, Daria Nikolaeva, Ysaline Depasse, Sara Chergaoui, Yusak Hartanto, Bart Van der Bruggen, Joao A. P. Coutinho, Anita Buekenhoudt, Patricia Luis
Summary: This study investigates the use of task-specific ionic liquids (TSILs) in the form of supported ionic liquid membranes (SILMs) for the separation and purification of dimethyl carbonate (DMC) through pervaporation. The results show that SILMs exhibit higher selectivity at low temperatures and an increase in temperature negatively affects the permeance of DMC and methanol.
JOURNAL OF MEMBRANE SCIENCE
(2023)
Article
Chemistry, Physical
Congwen Qin, Hongshuai Gao, Xue Liu, Xinxin Li, Yanyan Xie, Yan Bai, Yi Nie
Summary: This study used COSMO-RS to predict the dissolution ability of 143 kinds of ILs for human hair, and screened out five-imidazole based ILs with strong dissolution ability. The effects of dissolution temperature, mass ratio, water content, and the recycle performance of ILs on the dissolution process were systematically studied. The structure of regenerated keratin was characterized and found to be similar to human hair.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Engineering, Chemical
Zhixing Wu, Sensen Shi, Guoxiong Zhan, Fei Chang, Yinge Bai, Xiangping Zhang, Jeffery C. S. Wu, Shaojuan Zeng
Summary: Through multi-scale investigation and optimization using the COSMO-RS model, 1-ethyl-1-methylpiperidinium acetate was identified as the optimal IL for DCM absorption with excellent performance and the lowest operational cost among the studied cases.
SEPARATION AND PURIFICATION TECHNOLOGY
(2021)
Article
Engineering, Chemical
Zhengxing Dai, Yifeng Chen, Chang Liu, Xiaohua Lu, Yanrong Liu, Xiaoyan Ji
Summary: The study utilized literature survey and prediction model to obtain heat capacity data for 117 ionic liquids at different temperatures, demonstrating the reliability of COSMO-RS for predicting the heat capacity of ionic liquids.
CHINESE JOURNAL OF CHEMICAL ENGINEERING
(2021)
Review
Chemistry, Physical
Amir Sada Khan, Taleb Hassan Ibrahim, Zeeshan Rashid, Mustafa Khamis, Paul Nancarrow, Nabil Abdel Jabbar
Summary: Through COSMO-RS screening, efficient ionic liquids for phenolic compound removal were identified, with findings showing that anions, cations, alkyl chain length, and functional groups on cations have significant impacts on the process. General guidelines for the proper selection of ILs for phenolic compound extraction from aqueous solution were proposed based on the screening results.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Chemistry, Physical
Yingying Cao, Zhixing Wu, Ying Zhang, Yanrong Liu, Hui Wang
Summary: This study developed a method for screening ILs with high solvation capability for artemisinin, showing that artemisinin mainly interacts with ILs through hydrogen bonds. Experimental results demonstrated that better extraction efficiency can be achieved using the optimal IL, further verifying the accuracy of the simulation results.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Chemistry, Physical
Amir Sada Khan, Taleb Hassan Ibrahim, Mustafa Khamis, Paul Nancarrow, Nabil Abdel Jabbar
Summary: This study compared the extraction behavior of ionic liquids containing the same anion [NTf2] and different alkyl chain length cations for removing phenol, finding that the performance order of ILs with the same alkyl chain length was pyrrolidinium > imidazolium > ammonium; Increasing the alkyl chain length of the imidazolium cation resulted in decreasing removal efficiency of phenol.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Environmental Sciences
Gongran Ye, Xilei Wu, Neng Gao, Yingjie Xu, Zhikai Guo, Xiaohong Han
Summary: In this study, the solubilities of R-32 and R-125 in 840 conventional ILs were analyzed, revealing the absorption mechanism of these two refrigerants in ILs. It was found that the solubility of R-125 is lower in most ILs due to the structural changes of cations and anions. Furthermore, novel functional ILs were designed for the separation process of R-32 + R-125.
ENVIRONMENTAL RESEARCH
(2023)
Article
Energy & Fuels
Nazrul Islam, Huma Warsi Khan, Abdullatif A. Gari, Mohammad Yusuf, Kashif Irshad
Summary: With the growth of the world's population, urbanization, and industrialization, the production of greenhouse gases has also increased. It is necessary to capture these gases to reduce their levels in the atmosphere due to their harmful impact on the environment and livelihoods. Conventional solvents for capturing greenhouse gases are toxic, expensive, and generate additional waste. Ionic liquids (ILs) provide a sustainable alternative as green solvents due to their excellent properties. However, screening millions of ILs is time-consuming and inconvenient. This study used the COSMO-RS technique to pre-screen 720 ILs combinations and identified suitable cations and anions for capturing greenhouse gases.
Article
Engineering, Chemical
Placido Arenas, Inmaculada Suarez, Baudilio Coto
Summary: The study of extracting naphthenic acid by ionic liquids presents challenges in experimentation, combined with molecular dynamics simulations to investigate extraction mechanisms and transport properties. Research results show that a longer alkyl chain of ionic liquids behaves better in extraction, with the anion of the ILs playing a more significant role in the extraction process of naphthenic acid than the cation.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)
Article
Biochemistry & Molecular Biology
Xiaokang Wang, Yuanyuan Cui, Yingying Song, Yifan Liu, Junping Zhang, Songsong Chen, Li Dong, Xiangping Zhang
Summary: In this study, ionic liquids (ILs) containing hydroxylamine as the cation were found to have better extraction performance for the separation of methanol from DMC. The extraction mechanism of these functionalized ILs was analyzed to be mainly governed by hydrogen bonding energy and Van der Waals force. Experimental results validated the reliability of the COSMO-RS model, and ethanolamine acetate ([MEA][Ac]) was determined to have the best extraction performance.
Article
Education & Educational Research
Mohammed Alshehri, Aaron J. Kruse-Diehr, Justin T. McDaniel, Julie Partridge, Dawn B. Null
Summary: Lack of familiarity and social support may contribute to unhealthy dietary behaviors among international students in the US. Students from East Asia, Europe, and North America, as well as those with families that discourage healthy eating habits, are more likely to engage in unhealthy dietary behaviors. Living with immediate family members decreases the likelihood of receiving friend encouragement for healthy eating habits. Longer duration of stay in the US increases the likelihood of receiving friend discouragement for healthy eating habits.
JOURNAL OF AMERICAN COLLEGE HEALTH
(2023)
Article
Chemistry, Applied
Idris Juma Al-Busaidi, Rashid Ilmi, Danyang Zhang, Jose D. L. Dutra, Willyan F. Oliveira, Nawal K. Al Rasbi, Liang Zhou, Wai-Yeung Wong, Paul R. Raithby, Muhammad S. Khan
Summary: Three new europium(III) complexes have been synthesized and characterized, with the phenyl-ethynyl-bipyridine ligand showing impressive performance in red organic light emitting diodes. The contribution of each ligand to the sensitized Eu(III) photoluminescence has been analyzed. An energy transfer mechanism for the sensitized Eu(III) emission has been proposed and discussed using experimental and theoretical data.
Article
Biochemistry & Molecular Biology
Raoudha Soury, Mahjoub Jabli, Salman Latif, Khalaf M. Alenezi, Mabrouka El Oudi, Fahad Abdulaziz, Safa Teka, Hani El Moll, Ashanul Haque
Summary: The study successfully prepared and characterized a new composite gel bead by chemically modifying a biopolymer. It was found that the composite beads exhibited excellent adsorption capacity for removing cationic dye from water.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2022)
Article
Electrochemistry
Hani El Moll, Khalaf M. Alenezi, Ashanul Haque, Jamal Humaidi, Abdullah O. Alshammari, Eid M. S. Azzam, Raoudha Soury, Fahad Abdulaziz, Salman Latif, Milan Vranes
Summary: This study reports the electrocatalytic activity of a cobalt(II) compound based on thiacalix[4]arene that is equipped with sulfur and oxygen coordinating donor atoms, which has been underestimated as a pre-catalyst for the Hydrogen Evolution Reaction (HER). The compound was characterized by cyclic voltammetry, showing two reduction peaks corresponding to the Co2+/Co+ and Co+/Co redox couples.
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
(2022)
Article
Chemistry, Inorganic & Nuclear
Raoudha Soury, Marwa Chaabene, Ashanul Haque, Mahjoub Jabli, Khalaf M. Alenezi, Salman Latif, Fahad Abdulaziz, Amor Bchetnia, Christian Philouze
Summary: In this study, two new zinc-porphyrinic complexes with pyrazine as an axial ligand were successfully synthesized and extensively characterized. The crystal structure revealed a penta-coordinated environment around the zinc atom in the complexes. Weak C-H (...) Cg pi interactions were found to stabilize the complexes. Optical absorption studies confirmed their semiconducting nature. The fluorescence quantum yields and lifetime were not significantly affected by the axial ligand. Additionally, the ability of a dye to remove the free bases and metal complexes from solution was demonstrated. Density functional theory calculations showed charge transfer within the molecules.
JOURNAL OF SOLID STATE CHEMISTRY
(2022)
Article
Biochemistry & Molecular Biology
Essam N. Ads, Syed Hassan, Saravanan Rajendrasozhan, Mona H. Hetta, Shaza H. Aly, Mohamed A. Ali
Summary: This study isolates and identifies two new compounds from the stem bark of Ziziphus spina-christi, demonstrating their potential antimicrobial properties in pharmaceutical and clinical applications.
Article
Polymer Science
Ahmed A. Al Otaibi, Abdulmohsen Khalaf Dhahi Alsukaibi, Md. Ataur Rahman, Md. Mushtaque, Ashanul Haque
Summary: Recycling plastic waste into valuable materials is a significant challenge. Only a portion of PET bottles is currently being recycled each year. In this study, PET-based waste materials were successfully converted into a precursor and a Schiff-base compound was synthesized.
Article
Biochemistry & Molecular Biology
Ashanul Haque, Khalaf M. Alenezi, Hani El Moll, Muhammad S. Khan, Wai-Yeung Wong
Summary: This study reports the synthesis and characterization of some mixed arylalkyl tertiary phosphines via the Grignard approach, extensively characterizes a new asymmetric phosphine by multiple spectroscopic techniques, and compares and discusses the IR and UV-Vis spectra of some selected compounds.
Article
Chemistry, Physical
Rayya A. Al-Balushi, Idris Juma Al-Busaidi, Houda Al-Sharji, Ashanul Haque, Md. Serajul Haque Faizi, Necmi Dege, Muhammad S. Khan, Tarek A. Mohamed
Summary: In this study, the structures, photo-physical properties, and DFT computations of curcumin type diarylheptanoids were described. These compounds exhibited blue-shifted optical spectroscopic features and aggregation enhanced emission properties. The incorporation of halogen atoms improved the thermal stability of the compounds.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Review
Chemistry, Multidisciplinary
Ashanul Haque, Khalaf M. Alenezi, Muhammad S. Khan, Wai-Yeung Wong, Paul R. Raithby
Summary: The design and development of functional materials with practical applications require high standards. Understanding and controlling inter- and intra-molecular interactions offer opportunities for designing new materials. Manipulating the molecular structure can significantly alter these interactions and enhance the properties and functions of the material. Non-covalent interactions (NCIs) have been found to have beneficial effects, indicating that manipulating NCIs can generate functional materials with various physical properties for applications in catalysis, drug delivery, crystal engineering, etc. This review aims to explore the implications of NCIs on molecular packing, optical properties, and applications of functional pi-conjugated materials. Additionally, it attempts to delineate the effects of weak interactions on opto-electronic (O-E) applications.
CHEMICAL SOCIETY REVIEWS
(2023)
Article
Chemistry, Multidisciplinary
Hani El Moll, Khalaf M. Alenezi, Ashanul Haque, Jamal Humaidi, Raoudha Soury, Eid M. S. Azzam, Fahad Abdulaziz, Salman Latif, Milan Vranes
Summary: This study evaluates the electrocatalytic performance of a nickel(II) coordination complex based on thiacalix[4]arene. The experiment shows that the peak current of proton reduction increases with the increase of acetic acid equivalents.
JOURNAL OF CHEMICAL RESEARCH
(2022)
Article
Chemistry, Multidisciplinary
Salma A. Al-Zahrani, Violeta Jevtovic, Khalaf M. Alenezi, Hani El Moll, Ashanul Haque, Dragoslav Vidovic
Summary: The study demonstrates the impressive HER catalytic activity of Cu(II) complexes based on pyridoxal semicarbazone and thiosemicarbazone. The catalytic activity of these complexes is not only determined by the central metal, but also influenced by the coordinating ligand.
JOURNAL OF THE SERBIAN CHEMICAL SOCIETY
(2022)
Article
Chemistry, Multidisciplinary
Violeta Jevtovic, Khalaf M. Alenezi, Hani El Moll, Ashanul Haque, Salma A. Al-Zahrani, Jamal Humaidi, Dragoslav Vidovic
Summary: This study investigated the electrocatalytic hydrogen evolution reaction (HER) performances of two stabilized metal complexes, showing that complex 2 was more active than complex 1. The research suggests that the electrocatalytic HER is a crucial and challenging method for obtaining H-2.
JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN
(2021)
Article
Chemistry, Inorganic & Nuclear
Idris Juma Al-Busaidi, Ashanul Haque, John Husband, Nawal K. Al Rasbi, Osama K. Abou-Zied, Rayya Al Balushi, Muhammad S. Khan, Paul R. Raithby
Summary: A series of mono-, di-, and poly(platina-ynes) incorporating stilbene spacer units were synthesized and characterized to explore the effects of ligand topology on photoisomerization and photophysical properties. The experimental findings showed that the topology-dependent reversible trans-to-cis photoisomerization occurred in certain organometallic species in CH2Cl2 solution. Computational modeling supported the experimental results.
DALTON TRANSACTIONS
(2021)
Article
Chemistry, Physical
Rajalaxmi Sahoo, C. Reshma, D. S. Shankar Rao, C. V. Yelamaggad, S. Krishna Prasad
Summary: This study investigates the influence of the flexible spacer parity of a guest photoactive liquid crystalline dimer on the photonic bandgap features of the cholesteric and twist grain boundary smectic C phases of the host molecule. The results show that the parity of the photoactive dimer affects the width of the photonic bandgap and the blue-shift of the cholesteric phase. Additionally, the parity of the dimer also affects the layer spacing and two-dimensional periodicity of the liquid crystalline phases.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Sara Rozas, Alberto Gutierrez, Mert Atilhan, Alfredo Bol, Santiago Aparicio
Summary: This study presents a multiscale theoretical investigation on the use of bifunctional hydrophobic Deep Eutectic Solvent for carbon capture using tetrapropylammonium chloride, acetic acid, and ethanolamine. The characterization includes nanoscale analysis of CO2 absorption mechanisms and changes in liquid phase properties during gas capture.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Tabouli Eric Da-yang, Alhadji Malloum, Jean Jules Fifen, Mama Nsangou, Jeanet Conradie
Summary: In this study, the potential energy of different glycine tautomers and their interaction with Cu2+ cations was investigated. The results showed that the solvation medium and the presence of Cu2+ cations influenced the stability of glycine tautomers.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Xiaoliang Gou, Nan Ye, Qingqing Han, Junjie Cui, Long Yi Jin
Summary: In this study, amphiphilic rod-coil molecules with rigid DSA parts and flexible oligoether chains were designed and their assembly capacities were investigated. The morphology of the molecular aggregates was influenced by the pH of the solution and UV light, and the aggregates showed adsorption capacity for nitroaromatic compounds.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Shuang Liu, Liyan Shan, Cong Qi, Wenhui Zhang, Guannan Li, Bei Wang, Wei Wei
Summary: Optimizing the design of styrene-butadiene-styrene copolymer (SBS) is crucial for producing cost-effective SBS modifiers and improving road quality. This study examined the influence of SBS content and molecular structure on viscosity and compatibility. The results showed that the viscosity contribution of SBS is determined by its molecular structure and phase morphology.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Artem A. Petrov, Ekaterina A. Titova, Aydar A. Akhmadiyarov, Ilnaz T. Rakipov, Boris N. Solomonov
Summary: This work focuses on the thermochemistry of solvation of azeotropes. The enthalpies of dissolution of azeotropes in different mediums were determined, and the impact of the structure of the azeotropes on their properties in solution was discussed. A correlation between enthalpies of solvation and molar refraction was used to determine the vaporization enthalpies of azeotropes for the first time. The results were found to be consistent with literature data, obtained using direct and calculated methods. These findings contribute to the analysis of the structure-property relationships of azeotropes.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
L. V. Kamaeva, E. N. Tsiok, N. M. Chtchelkatchev
Summary: Understanding the correlations between liquids and solids allows us to predict the thermodynamic parameter range favorable for the formation of intriguing solid phases by studying liquids. In this study, we experimentally and theoretically investigated an Al-Cu-Co system within different composition ranges, and identified high-temperature solid phases. Our findings demonstrated the correlation between the boundaries of different solid phases and undercooling and viscosity in the concentration area.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
R. Aneesh Kumar, S. Jamelah Al-Otaibi, Y. Sheena Mary, Y. Shyma Mary, Nivedita Acharjee, Renjith Thomas, Renjith Raveendran Pillai, T. L. Leena
Summary: In this study, the interactions between doped and pristine coronenes and adenine nucleobases were investigated using Density Functional Theory. The optimal configurations, adsorption energies, charge transfer, and electrical properties of each complex were calculated. It was found that doped coronene had stronger adsorption strength and charge transfer compared to pristine coronene. The stability of the complexes was attributed to non-covalent interactions in the interactive region. The change in electrical conductivity of coronenes after adsorption suggested their sensitivity towards DNA bases. The predicted energy gap and prolonged recovery time for adenine-coronene configurations indicated the potential application of pristine/doped coronene in DNA detection.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Gang Zhou, Yongwei Liu, Biao Sun, Zengxin Liu, Cuicui Xu, Rulin Liu, Qi Zhang, Yongmei Wang
Summary: The CFD-DEM method was used to simulate the dust deposition pattern in the bronchus of anchor digging drivers, revealing the highest dust concentration in the vortex region of the working face. The study also found a positive correlation between dust particle diameter and bronchial deposition rate, and a negative correlation with alveolar deposition rate.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Yan Zhang, Yafei Luo, Lingkai Tang, Mingyan E, Jianping Hu
Summary: This study investigates the effects of different transition metal decorations on B12N12 nanocages on the adsorption properties of nitrosourea drugs using computational methods. The results reveal the presence of weak non-covalent interactions between metals and nanocages, and the interaction between drugs and nanocages plays a significant role in drug adsorption. Compared to free drugs, the adsorption of drugs on nanocages can facilitate electron transfer, reduce energy gaps and chemical hardness, indicating activity at the target site.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
C. I. Alcolado, J. Poblete, L. Garcia-Rio, E. Jimenez, F. J. Poblete
Summary: In this study, the selective oxidation of aromatic aldehydes was investigated using Ru(VI) as a catalyst and hexacyanoferrate (III) as a cooxidant in an alkaline medium. The reaction mechanism involves complex reaction orders for the oxidant and the aromatic aldehyde, while the reaction order for Ru(VI) is one. The proposed mechanism includes two catalytic cycles and the formation and decomposition of complexes. Quantitative structure-activity relationship analysis showed that deactivating groups in the para-position enhance the process.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Inez A. Barbieri, Marcos L. S. Oliveira, Franciele S. Bruckmann, Theodoro R. Salles, Leonardo Zancanaro, Luis F. O. Silva, Guilherme L. Dotto, Eder C. Lima, Mu. Naushad, Cristiano R. Bohn Rhoden
Summary: This study evaluated the adsorption of zolpidem on magnetic graphene oxide and synthesized magnetic graphene oxide adsorbents for zolpidem removal. The best magnetic nanoadsorbent was found to have a removal percentage of 87.07% at specific pH and temperature conditions. The results suggest that the removal of zolpidem is related to the surface chemistry of the adsorbent rather than the surface area of graphene oxide. The adsorbent showed excellent adsorption efficiency and magnetic behavior, making it a promising material for removing zolpidem from aqueous solutions.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Hongyan Huang, Chunquan Li, Siyuan Huang, Yuling Shang
Summary: This study examines the sensitivity of the thermal conductivity of water-based alumina nanofluids to changes in concentration, sphericity, and temperature. The results show that volume fraction and temperature have a significant impact on the thermal conductivity, while sphericity also needs to be considered. A support vector machine regression model was created to analyze the sensitivity of the thermal conductivity to different parameters. The findings indicate that temperature, sphericity, and volume fraction are the most sensitive variables.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Correction
Chemistry, Physical
V. M. Pergamenshchik, T. Bryk, A. Trokhymchuk
JOURNAL OF MOLECULAR LIQUIDS
(2024)
Article
Chemistry, Physical
Valentyn Rudenko, Anatolii Tolochko, Svitlana Bugaychuk, Dmytro Zhulai, Gertruda Klimusheva, Galina Yaremchuk, Tatyana Mirnaya, Yuriy Garbovskiy
Summary: This paper reports on the synthesis, structural characterization, spectral and nonlinear-optical properties of glass nanocomposites made of glass forming ionic liquid crystals and nanoparticles. The study reveals that by exciting the nanocomposites within their absorption band, a control over effective optical nonlinearities can be achieved, allowing the modification of the magnitude and sign of the effective nonlinear absorption coefficient. The proposed strategy using metal-alkanoates based glass-forming ionic liquid crystals and nanoparticles shows great potential for the development of nanophotonics and plasmonics technologies.
JOURNAL OF MOLECULAR LIQUIDS
(2024)
