Journal
JOURNAL OF MAGNETIC RESONANCE
Volume 285, Issue -, Pages 1-7Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jmr.2017.10.003
Keywords
Long-lived states; q-space; Diffusion; Diffusive-diffraction; Magnetic resonance
Funding
- EPSRC [EP/N033558/1]
- EPSRC [EP/N033558/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/N033558/1] Funding Source: researchfish
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The latest developments in the field of long-lived spin states are merged with pulsed-field gradient techniques to extend the diffusion time beyond what is currently achievable in standard q-space diffusive diffraction studies. The method uses nearly-equivalent spin-1/2 pairs that let diffusion times of the order of many minutes to be measured allowing access to the long-time limit in cavities of macroscopic size (millimeters). A pulse sequence suitable to exploit this regime has been developed and validated with the use of numerical simulations and experiments. (C) 2017 The Authors. Published by Elsevier Inc.
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