4.7 Article Proceedings Paper

Role of oxygen and DOM in sunlight induced photodegradation of organophosphorous flame retardants in river water

Journal

JOURNAL OF HAZARDOUS MATERIALS
Volume 323, Issue -, Pages 242-249

Publisher

ELSEVIER
DOI: 10.1016/j.jhazmat.2016.05.019

Keywords

Photosensitizers; Singlet oxygen; ROS; Photolysis; Organophosphate esters

Ask authors/readers for more resources

The wide use of organophosphorous flame retardants (OPFR) and plasticizers causes a continuous release of large quantities into natural waters. One of the main contributors to micropollutants depletion in surface water is sunlight induced phototransformations. This study aims to elucidate whether alkyl, chloroalkyl and aryl organophosphorus flame retardants undergo phototransformations in river water. To perform the experiments, nine OPFR were subjected to natural sunlight, Xe lamp (simulated sunlight) and UV-C irradiations in ultra-pure Milli-Q water, Milli-Q water with humic acid and river water. Experiments demonstrated that OPFR achieve an important degree of photodegradation noticeable at long irradiation time, although direct photolysis did not account as the main photodegration mechanism. Results indicated that sunlight absorbing OPFR exhibited photosensitizing activity. The presence of azide in ultra-pure water inhibited some OPFR photodegration by singlet oxygen (O-1(2)) scavenging, and the absence of dissolved oxygen significantly depleted most of OPFR removal. In the conditions studied, humic acid inhibited OPFR phototransformations, while river water enhanced their removal. Results from this study point out the need to further investigate the role of some OPFR as photosensitizers, which are important for fate and ecological risk assessment of flame retardants and other micropollutants in water. (C) 2016 Elsevier B.V. All rights reserved.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Environmental Sciences

Toxicity assessment of polyethylene microplastics in combination with a mix of emerging pollutants on Physalaemus cuuieri tadpoles

Amanda Pereira da Costa Araujo, Thiarlen Marinho da Luz, Mohamed Ahmed Ibrahim Ahmed, Mir Mohammad Ali, Md Mostafizur Rahman, Bojan Nataraj, Daniela de Melo e Silva, Damia Barcelo, Guilherme Malafaia

Summary: Recent studies have indicated that microplastic pollution can exert additional stress on amphibian populations. However, our understanding of the effects of microplastics on amphibians, especially in combination with other emerging pollutants, is limited. This study aimed to assess the potential toxicity of polyethylene microplastics (PE-MPs), alone or in combination with a mixture of pollutants, on the health of Physalaemus cuvieri tadpoles. The results showed that exposure to the combination of PE-MPs and pollutants induced enhanced stress responses in tadpoles, although the uptake and accumulation of PE-MPs in the animals was reduced. This study provides new insights into the risks posed by microplastics coexisting with other pollutants in aquatic environments.

JOURNAL OF ENVIRONMENTAL SCIENCES (2023)

Article Chemistry, Analytical

Effects of sulfamethoxazole exposure on mussels (Mytilus galloprovincialis) metabolome using retrospective non-target high-resolution mass spectrometry and chemometric tools

Carlos Perez-Lopez, Sara Rodriguez-Mozaz, Albert Serra-Compte, Diana Alvarez-Munoz, Antoni Ginebreda, Damia Barcelo, Roma Tauler

Summary: In this study, the ROIMCR method is proposed for the analysis of non-target metabolomics data. The effects of SMX exposure and seasonal conditions on marine mussels were studied using HPLC-HRMS. The results showed that seasonal conditions had a greater impact on metabolite concentrations compared to SMX exposure and the interaction of these factors.

TALANTA (2023)

Article Environmental Sciences

Legacy and emerging contaminants in flamingos' chicks' blood from the Ebro Delta Natural Park

Maria Dulsat-Masvidal, Albert Bertolero, Rafael Mateo, Silvia Lacorte

Summary: The aim of this study is to evaluate the exposure of 91 emerging and legacy micropollutants in flamingo chicks, an emblematic species of the area. The results indicate a multi-exposure of flamingo's chicks from a very young age. This is the first study to describe flamingos chicks' exposure to multiple contaminants, highlighting the importance of biomonitoring for wildlife conservation and biodiversity preservation.

CHEMOSPHERE (2023)

Article Environmental Sciences

Presence of novel and legacy flame retardants and other pollutants in an e-waste site in China and associated risks

Pablo Zapata-Corella, Zi-He Ren, Yin-E Liu, Anna Rigol, Silvia Lacorte, Xiao-Jun Luo

Summary: This study evaluates the distribution, partitioning and environmental and human impact of organophosphate esters, legacy polychlorinated biphenyls, polybromodiphenyl ethers and organochlorine pesticides in the e-waste recycling area of Qingyuan county, China. The study finds that a plastic debris lump accumulated in a small pond is the main source of pollution, causing high concentrations of contaminants in water, sediments, soils and hen eggs in the surrounding area.

ENVIRONMENTAL RESEARCH (2023)

Article Engineering, Environmental

GC-HRMS analysis to evaluate the effectiveness of ozone disinfection in the removal of micropollutants from wastewater

Raissa Olivia Barbacena, Joyce Cristale, Carlos Barata, Silvia Lacorte, Renato F. Dantas

Summary: The objective of this study was to assess micropollutant removal during ozone disinfection of wastewater, utilizing targeted and untargeted screening analyses. Effluents from two wastewater treatment plants were treated with ozone at various doses and analyzed using gas chromatography coupled with Orbitrap High-Resolution Mass Spectrometry. The removal of different chemical families was evaluated in relation to the level of Escherichia coli and the total removal of coliforms. The proposed methodology aims to provide a new protocol for the careful evaluation of ozonized wastewater effluents for disposal and reuse.

ENVIRONMENTAL SCIENCE-WATER RESEARCH & TECHNOLOGY (2023)

Article Environmental Sciences

Interdisciplinary approach to solve unusual mortalities in the European common frog (Rana temporaria) in two high-mountain ponds affected by climate change

Paolo Pastorino, Silvia Colussi, Katia Varello, Arianna Meletiadis, Silvia Alberti, Alessia Di Blasio, Giovanni Tedde, Mattia Begovoeva, Andrea Peano, Luca Rossi, Monia Renzi, Pier Luigi Acutis, Damia Barcelo, Marino Prearo

Summary: Unusual mortality events of frogs occurred in two high-mountain ponds in Italy. Analysis of water and frog samples revealed a correlation between the isolation of bacteria and frog mortalities, which was likely caused by high water temperatures.

ENVIRONMENTAL RESEARCH (2023)

Article Environmental Sciences

The spread of the omicron variant: Identification of knowledge gaps, virus diffusion modelling, and future research needs

Uttpal Anand, Tarun Pal, Alessandra Zanoletti, Suresh Sundaramurthy, Sunita Varjani, Anushka Upamali Rajapaksha, Damia Barcelo, Elza Bontempi

Summary: The World Health Organization (WHO) identified the variant B.1.1.529 of SARS-CoV-2 as a variant of concern, named Omicron, due to its multiple mutations that enhance its ability to spread globally and evade immunity, posing serious threats to public health.

ENVIRONMENTAL RESEARCH (2023)

Article Engineering, Environmental

Estimating the Mass of Pharmaceuticals Harbored in Municipal Solid Waste Landfills by Analyzing Refuse Samples at Various Ages and Depths

Xia Yu, Wentao Zhao, Shuguang Lyu, Zhenxiao Cai, Gang Yu, Hualin Wang, Damia Barcelo, Qian Sui

Summary: This study excavated and analyzed the refuse from the largest municipal solid waste landfill in Shanghai, revealing the presence of 42 pharmaceuticals with concentrations ranging from 0.30 to 116 μg/kg. Different concentration variations of individual pharmaceuticals were observed in refuse samples excavated at different depths and positively correlated to their sorption ability. The estimated mass of pharmaceuticals in the investigated landfill was 80-220 tons based on Monte Carlo analysis, providing the first estimate of pharmaceutical mass in an MSW landfill.

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2023)

Review Environmental Sciences

Microbial engineering strategies for synthetic microplastics clean up: A review on recent approaches

Vinay Kumar, Neha Sharma, Lucky Duhan, Ritu Pasrija, Jithin Thomas, Mridul Umesh, Sivarama Krishna Lakkaboyana, Rodrigo Andler, Alisa S. Vangnai, Meththika Vithanage, Mukesh Kumar Awasthi, Wen Yi Chia, Pau LokeShow, Damia Barcelo

Summary: This paper reviews the origin and dispersal of microplastics in aquatic systems, their biodegradation and the factors affecting it, as well as the major engineering approaches applied in microbial biotechnology. It also discusses the major challenges associated with plastic removal by evaluating recent reports.

ENVIRONMENTAL TOXICOLOGY AND PHARMACOLOGY (2023)

Review Environmental Sciences

Human biomonitoring of microplastics and health implications: A review

Giuseppina Zuri, Angeliki Karanasiou, Silvia Lacorte

Summary: This review provides an overview of the current human biomonitoring data available on microplastics (MPs), which are plastic particles ubiquitous in water, soil, and air. The review compiles 91 relevant studies and highlights that humans are exposed to MPs through ingestion and inhalation. The health risks associated with MPs exposure include inflammation, oxidative stress, and DNA damage, potentially leading to cardiovascular and respiratory diseases, as well as cancer.

ENVIRONMENTAL RESEARCH (2023)

Article Environmental Sciences

Effect of cresol isomers on reproduction and gene expression in Daphnia magna

Fulgence Jacob Macha, Hyungjoon Im, Kyungtae Kim, Kyunghwa Park, Jeong-Eun Oh, Damia Barcelo

Summary: Cresols are commonly found in freshwater systems and are used as disinfectants. However, their long-term toxicity effects on reproduction and gene expression patterns of aquatic species are not well understood. This study aimed to investigate the chronic toxic effects of cresols on reproduction and gene expression using D. magna, and also examined the bioconcentration behavior of cresol isomers. The results showed that cresols had negative effects on offspring quantity and reproduction delay, but did not significantly affect body weight and gene transcription in Daphnia. The bioconcentration experiments indicated that cresol isomers are unlikely to accumulate in aquatic species.

SCIENCE OF THE TOTAL ENVIRONMENT (2023)

Review Environmental Sciences

A review of chromium (Cr) epigenetic toxicity and health hazards

Mahalaxmi Iyer, Uttpal Anand, Saranya Thiruvenkataswamy, Harysh Winster Suresh Babu, Arul Narayanasamy, Vijay Kumar Prajapati, Chandan Kumar Tiwari, Abilash Valsala Gopalakrishnan, Elza Bontempi, Christian Sonne, Damia Barcelo, Balachandar Vellingiri

Summary: Carcinogenic metals, particularly chromium (Cr) and its derivatives, including Cr(VI)-induced, have widespread distribution and pose a concern for adverse environmental and human health effects. They cause DNA epigenetic alterations resulting in heritable changes in gene expression. This review discusses the role of Cr(VI) in epigenetic changes, highlighting the importance of considering epigenetics as a possible mechanism underlying Cr(VI) toxicity and cell-transforming ability. More clinical and preventative measures are needed to better understand the toxicity and safeguard employees against cancer.

SCIENCE OF THE TOTAL ENVIRONMENT (2023)

Article Environmental Sciences

Threats to sustainability in face of post-pandemic scenarios and the war in Ukraine

Joao Pinto da Costa, Ana Luisa Silva, Damia Barcelo, Teresa Rocha-Santos, Armando Duarte

Summary: As the world slowly emerges from the ongoing pandemic, war has broken out in Europe as Russia invades Ukraine. The military conflict in Ukraine has had far-reaching consequences on human, social, economic, and environmental levels, affecting not only the involved nations but also Europe and the world. Damaged infrastructures, disrupted economic activity, and forced migration have negatively impacted sustainability. The COVID-19 pandemic adds complexity to the situation, further disrupting economic activity and straining healthcare systems. This study examines the impact of the intersection of war and COVID-19 on the United Nations' 2030 Agenda for Sustainable Development and assesses its global implications.

SCIENCE OF THE TOTAL ENVIRONMENT (2023)

Article Engineering, Environmental

A critical scientific and policy opinion on reuse and reclamation of contaminated wastewater for agriculture and other purposes

Evgenios Agathokleous, Damia Barcelo, Edward J. Calabrese

Summary: Contaminants of emerging concern and other chemicals are widely present in the environment, and they can induce various effects at concentrations/doses smaller than the toxicological threshold. These low-dose effects pose challenges for wastewater reuse and reclamation, and stakeholders have made efforts to address this issue. To effectively tackle the low-dose issue, the improvement of treatment/remediation sites, better control/prevention of chemical release, and involvement of citizen-science approach should be considered.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2023)

Article Engineering, Environmental

Current knowledge on the presence, biodegradation, and toxicity of discarded face masks in the environment

Ana M. Oliveira, Ana L. Patricio Silva, Amadeu M. V. M. Soares, Damia Barcelo, Armando C. Duarte, Teresa Rocha-Santos

Summary: During the COVID-19 pandemic, the increased use of disposable face masks has led to a significant environmental burden. This critical review discusses the degradation and toxicity of face mask contaminants and emphasizes the need for more research in this area. The lack of studies on biodegradation and ecotoxicity, as well as the uncertainties in experimental procedures, hinder the comparison with conventional plastic debris. Further studies on the abundance and composition of face mask-released contaminants and the development of methodological strategies are crucial to understand their environmental impact.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2023)

Article Engineering, Environmental

Temperature-modulated sensing characteristics of ultrafine Au nanoparticle-loaded porous ZnO nanobelts for identification and determination of BTEX

Shun-Shun Chen, Xu-Xiu Chen, Tian-Yu Yang, Li Chen, Zheng Guo, Xing-Jiu Huang

Summary: A temperature-modulated sensing strategy was proposed to identify and determine BTEX compounds. Highly effective identification of BTEX was achieved using linear discrimination and convolutional neural network analyses. Additionally, quantitative analysis of concentration was accomplished by establishing the relationship between concentration and response.

JOURNAL OF HAZARDOUS MATERIALS (2024)

Article Engineering, Environmental

Particulate matter-induced metabolic recoding of epigenetics in macrophages drives pathogenesis of chronic obstructive pulmonary disease

Myungkyung Noh, Jeong Yeon Sim, Jisung Kim, Jee Hwan Ahn, Hye-Young Min, Jong-Uk Lee, Jong-Sook Park, Ji Yun Jeong, Jae Young Lee, Shin Yup Lee, Hyo-Jong Lee, Choon-Sik Park, Ho-Young Lee

Summary: This study reveals that chronic exposure to PM induces chronic inflammation and development of COPD by dysregulating NAD+ metabolism and subsequent SIRT1 deficiency in pulmonary macrophages. Activation of SIRT1 by resveratrol effectively mitigates PM-induced inflammation and COPD development. Targeting metabolic and epigenetic reprogramming in macrophages induced by PM is a promising strategy for COPD treatment.

JOURNAL OF HAZARDOUS MATERIALS (2024)

Article Engineering, Environmental

Electrocatalytic degradation of nitrogenous heterocycles on confined particle electrodes derived from ZIF-67

Yu Liu, Linlin Qin, Yiming Qin, Tong Yang, Haoran Lu, Yulong Liu, Qiqi Zhang, Wenyan Liang

Summary: Co/NC/PAC electrode was prepared by compounding ZIF-67 with powder-activated carbon for the electrocatalytic treatment of nitrogen-containing heterocyclic compounds. The degradation efficiency of the four compounds reached 90.2-93.7% under optimal conditions, and the degradation order was pyridazine < pyrimidine < pyrazine < pyridine.

JOURNAL OF HAZARDOUS MATERIALS (2024)

Article Engineering, Environmental

Yttrium speciation variability in bauxite residues of various origins, ages and storage conditions

Julien Couturier, Pierre Tamba Oulare, Blanche Collin, Claire Lallemand, Isabelle Kieffer, Julien Longerey, Perrine Chaurand, Jerome Rose, Daniel Borschneck, Bernard Angeletti, Steven Criquet, Renaud Podor, Hamed Pourkhorsandi, Guilhem Arrachart, Clement Levard

Summary: This study analyzes the properties of bauxite residue samples and explores the influence of bauxite ore origin, storage conditions, and storage time. The results show that the speciation of yttrium is related to the origin of bauxite ore, while no significant variation was observed with storage conditions or aging of the residues.

JOURNAL OF HAZARDOUS MATERIALS (2024)

Article Engineering, Environmental

Trophic transfer and their impact of microplastics on estuarine food chain model

Sakthinarenderan Saikumar, Ravi Mani, Mirunalini Ganesan, Inbakandan Dhinakarasamy, Thavamani Palanisami, Dharani Gopal

Summary: Microplastic contamination in marine ecosystems poses a growing concern due to its trophic transfer and negative effects on marine organisms. This study investigates the transfer and impacts of polystyrene microplastics in an estuarine food chain. The results show that microplastics can be transferred through the food chain, although the transfer rates are low. The exposed organisms exhibit stress responses, suggesting the potential risk of microplastics reaching humans through the food chain.

JOURNAL OF HAZARDOUS MATERIALS (2024)

Review Engineering, Environmental

Antibiotic resistance genes and heavy metals in landfill: A review

Yan-Jiao Li, Ying Yuan, Wen-Bing Tan, Bei-Dou Xi, Hui Wang, Kun-Long Hui, Jia-Bao Chen, Yi-Fan Zhang, Lian-Feng Wang, Ren-Fei Li

Summary: This review investigated and analyzed the distribution, composition, and abundance of heavy metals and antibiotic resistance genes (ARGs) in landfill. The results showed that heavy metals have lasting effects on ARGs, and complexes of heavy metals and organic matter are common in landfill. This study provides a new basis to better understand the horizontal gene transfer (HGT) of ARGs in landfill.

JOURNAL OF HAZARDOUS MATERIALS (2024)

Article Engineering, Environmental

The effect of synthesis conditions on the in situ grown MIL-100(Fe)-chitosan beads: Interplay between structural properties and arsenic adsorption

Jessy Joseph, Ari Vaisanen, Ajay B. Patil, Manu Lahtinen

Summary: Efficient and environmentally friendly porous hybrid adsorbent beads have been developed for the removal of arsenic from drinking water. The structural tuning of the adsorbents has been shown to have a significant impact on their adsorption performance, with high crystallinity leading to increased adsorption capacity and selectivity towards As5+.

JOURNAL OF HAZARDOUS MATERIALS (2024)

Article Engineering, Environmental

Phthalate metabolites in breast milk from mothers in Southern China: Occurrence, temporal trends, daily intake, and risk assessment

Yangyang Liu, Minhua Xiao, Kaiqin Huang, Juntao Cui, Hongli Liu, Yingxin Yu, Shengtao Ma, Xihong Liu, Meiqing Lin

Summary: This study measured the levels of phthalate metabolites in breast milk collected from mothers in southern China. The results showed that phthalates are still prevalent in the region, and breastfeeding contributes to phthalate intake in infants. However, the levels detected do not pose significant health risks to infants based on dietary exposure. The increasing exposure to certain phthalates calls for further research into their sources and potential risks.

JOURNAL OF HAZARDOUS MATERIALS (2024)

Article Engineering, Environmental

Depth significantly affects plastisphere microbial evenness, assembly and co-occurrence pattern but not richness and composition

Zhiqiang Wu, Jianxing Sun, Liting Xu, Hongbo Zhou, Haina Cheng, Zhu Chen, Yuguang Wang, Jichao Yang

Summary: Ocean depth affects microbial diversity, composition, and co-occurrence patterns of microplastic microbial communities. Deterministic processes dominate the assembly of mesopelagic plastisphere microbial communities, while stochastic processes shape the assembly of bathypelagic microbial communities. The relationships between microorganisms in the mesopelagic layer are more complex and stable, with Proteobacteria and Actinobacteriota playing important roles.

JOURNAL OF HAZARDOUS MATERIALS (2024)

Article Engineering, Environmental

Abatement of antibiotics and resistance genes during catalytic ozonation enhanced sludge dewatering process: Synchronized in volume and hazardousness reduction

Tingting Xiao, Renjie Chen, Chen Cai, Shijie Yuan, Xiaohu Dai, Bin Dong, Zuxin Xu

Summary: Based on the efficiency of catalytic ozonation techniques in enhancing sludge dewaterability, this study investigated its effectiveness in simultaneous reduction of antibiotics and antibiotic resistance genes. The results showed that catalytic ozonation conditioning changed the distribution of antibiotics and achieved high degradation rates. It also significantly reduced the abundance of ARGs, inhibited horizontal gene transfer, and decreased the signal transduction of typical ARGs host bacteria.

JOURNAL OF HAZARDOUS MATERIALS (2024)

Article Engineering, Environmental

Unlocking the potential of ferrate(VI) in water treatment: Toward one-step multifunctional solutions

Yang Deng, Xiaohong Guan

Summary: This article discusses two different development approaches for ferrate(VI) technology in water treatment, arguing that process integration is a promising method that can drive technological innovation and revolution in water treatment, achieving higher treatment efficiency, reduced costs and energy consumption, and a smaller physical footprint.

JOURNAL OF HAZARDOUS MATERIALS (2024)

Article Engineering, Environmental

Floating Catalytic Foam with prominent heat-induced convection for the effective photocatalytic removal of antibiotics

Zhe Zhang, Lu Zhang, Zhihao Huang, Yuxin Xu, Qingqing Zhao, Hongju Wang, Meiqing Shi, Xiangnan Li, Kai Jiang, Dapeng Wu

Summary: In this study, a floating catalytic foam was designed and prepared to enhance the mass transfer in immobilized photocatalysts for wastewater treatment. The floating catalytic foam could float on the water surface and establish a temperature gradient, effectively promoting the diffusion and adsorption of target molecules during the photocatalytic process.

JOURNAL OF HAZARDOUS MATERIALS (2024)

Article Engineering, Environmental

Mechanism and synergistic effect of sulfadiazine (SDZ) and cadmium toxicity in spinach (Spinacia oleracea L.) and its alleviation through zinc fortification

Muhammad Nafees, Adiba Khan Sehrish, Sarah Owdah Alomrani, Linlin Qiu, Aasim Saeed, Shoaib Ahmad, Shafaqat Ali, Hongyan Guo

Summary: The accumulation of cadmium and antibiotics in edible plants and fertile soil is a worldwide problem. This study investigated the potential of zinc oxide nanoparticles to alleviate the toxicity of both cadmium and antibiotics and promote spinach growth.

JOURNAL OF HAZARDOUS MATERIALS (2024)

Article Engineering, Environmental

Aminoalkyl organosilicon with dual chemical sites for SO2 absorption and analysis of site-specific absorption entropy and enthalpy

Lurui Wan, Kai Wang, Yuan Chen, Zhiyong Xu, Wenbo Zhao

Summary: In this study, a low viscosity and high thermal stability SO2 absorbent with dual interacting sites was successfully synthesized. The absorbent showed the highest absorption enthalpy change and entropy change values among reported SO2 absorbents, and exhibited lower viscosity and comparable thermal stability to ILs.

JOURNAL OF HAZARDOUS MATERIALS (2024)

Article Engineering, Environmental

Improvement of Fe(III)/percarbonate system by molybdenum powder and tripolyphosphate: Co-catalytic performance, low oxidant consumption, pH-dependent mechanism

Zhengwei Zhou, Guojie Ye, Yang Zong, Zhenyu Zhao, Deli Wu

Summary: This study utilized Mo powder and STPP to enhance the performance of the sodium percarbonate system in pollutant degradation. The presence of Mo and STPP resulted in a higher degradation rate of the model pollutant SMX, with low oxidant consumption. The system generated multiple active species through a series of chain reactions at different pH values, exhibiting excellent performance towards electron-rich pollutants. Furthermore, Mo demonstrated excellent stability and reusability.

JOURNAL OF HAZARDOUS MATERIALS (2024)