Article
Engineering, Environmental
Chujia Ye, Parisa A. Ariya, Fenglian Fu, Guangda Yu, Bing Tang
Summary: This study investigated the dynamic interactions among ferrihydrite, Al(III) and Sb(V), as well as the influence of coprecipitated Al(III) and Sb(V) on the transformation of ferrihydrite. Results showed that Al(III) enhanced the immobilization of Sb(V) and the presence of Sb(V) induced more production of extractable Al(III). XRD patterns revealed that the transformation rate of coprecipitated Al(III) and Sb(V) ferrihydrite was higher than Al-coprecipitated ferrihydrite.
JOURNAL OF HAZARDOUS MATERIALS
(2021)
Article
Environmental Sciences
Sunday J. Olusegun, Taiane. G. F. Souza, Nelcy. D. S. Mohallem, Virginia. S. T. Ciminelli
Summary: Pure ferrihydrite and ferrihydrite-biosilica composite were synthesized and studied for the removal of As(III) and As(V). The synthesized materials showed high adsorption capacity for As(III) and As(V), with pH significantly affecting As(V) adsorption. Thermal treatment promoted ferric arsenate formation and oxidized As(III) to As(V), resulting in changes in As mobility in the adsorption residues. This work presents a process for environmentally safe disposal of As residues after As removal and thermal treatment of arsenic-loaded ferrihydrites.
JOURNAL OF ENVIRONMENTAL MANAGEMENT
(2023)
Article
Environmental Sciences
Lei Chen, Yu Han, Wei Li, Xiaohui Zhan, He Wang, Chengchao Shi, Yanping Sun, Huixiang Shi
Summary: This study prepared siliceous ferrihydrite (SiFh) through coprecipitation and found that it could resolve the instability issue of traditional ferrihydrite (Fh) due to its amorphous structure. The results showed that the growth of Fh particles was inhibited by the addition of silicon, while maintaining their amorphous structure. SiFh exhibited excellent stability after multiple adsorption-desorption cycles. The presence of silicon weakened the interaction between SiFh and Sb(V), but most of the Sb(V) still entered the Fe lattice, which was favorable for Sb(V) recovery. SiFh also showed high adsorption energy for Sb(V) from simulated textile wastewater, indicating unstable inner-sphere complexation. Furthermore, the presence of certain ions contributed to Sb(V) outer-sphere adsorption, facilitating its desorption. SiFh is a promising adsorbent due to its facile preparation, stability, and regeneration properties.
Article
Environmental Sciences
Tianning Wang, Yonghong Jiao, Mengchang He, Wei Ouyang, Chunye Lin, Xitao Liu, Haijiao Xie
Summary: This study prepared a porous Fe-Cu-chitosan composite through one-step coprecipitation and found the optimal Fe/Cu proportion for antimony adsorption. Spectral characterization, batch experiments, and density functional theory simulations were conducted to determine the adsorption mechanism involving Fe-Cu coupling and surface hydroxyls.
ENVIRONMENTAL POLLUTION
(2022)
Article
Engineering, Chemical
Lingfan Zhang, Sichao Lou, Xiangrui Hao, Hongyan Zhang, Wenqing Zhang, Xin Liu, Jiaofang Huang
Summary: A highly porous composite of zirconium-chitosan with excellent adsorption capacity for Sb(III) and Sb(V) has been successfully developed. The composite possesses an open large-pore structure, providing more adsorption sites for Sb(III) and Sb(V) removal. The experimental results demonstrated the exceptional abilities of the composite in removing both Sb(III) and Sb(V). The removal of Sb(III) involved a dehydration reaction, while the removal of Sb(V) was attributed to electrostatic attraction. This study highlights the potential applications of the composite in water purification.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)
Article
Geochemistry & Geophysics
Chengjun Zhang, Mengchang He, Chunye Lin, Wei Ouyang, Xitao Liu
Summary: This study comprehensively investigated the effect of dissolved Mn(II) on the oxidation and adsorption of Sb(III) in the ferrihydrite/hematite-Mn(II) system under aerobic conditions. The results showed that Sb(III) was efficiently removed in the presence of ferrihydrite/hematite and Mn(II), with formation of Mn(III/IV) oxides as the main oxidants for Sb(III) oxidation. However, the removal mechanisms differed between the ferrihydrite-Mn(II) system and the hematite-Mn(II) system.
Article
Environmental Sciences
Heng Li, Kaisheng Gong, Xiaoying Jin, Gary Owens, Zuliang Chen
Summary: In this study, phytosynthesized iron nanoparticles were used to effectively remove Sb(III) and Sb(V) from mining wastewater. The nanoparticles oxidized Sb(III) to Sb(V) on their surface, and both Sb species were adsorbed onto the nanoparticles. The adsorption behavior of Sb(III) and Sb(V) followed the Langmuir adsorption model and pseudo-second-order kinetics. The nanoparticles showed great potential for removing Sb from contaminated mining wastewaters.
Article
Engineering, Environmental
Tianning Wang, Yonghong Jiao, Mengchang He, Wei Ouyang, Chunye Lin, Xitao Liu, Haijiao Xie
Summary: This study prepared a novel Fe-Ti-chitosan composite (FTC-2/1) via a facile coprecipitation method for efficient elimination of Sb(III) and Sb(V) in water. The FTC-2/1 exhibited abundant surface hydroxyl groups and a unique three-dimensional porous structure, promoting the diffusion kinetics of Sb(III) and Sb(V). Density functional theory calculations revealed that the highest adsorption efficiency of FTC-2/1 was attributed to the preferential adsorption of the Fe-Ti bidentate complex towards Sb(III) and Sb(V) and the electronic structure reconstruction of the adsorbed antimony molecules and Fe-Ti atoms.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Chemistry, Physical
Wei Zhang, Ping Xiong, Qiao Li, Jiansheng Li, Jinyou Shen, Pengyu Zhu, Xiuyun Sun, Jingyu Lu, Ya Hu
Summary: This study investigated the competitive adsorption behavior and selective removal mechanisms of coexisting EDTA-complexed heavy metals (EDTA-CHMs) on an adsorbent. The results showed that Ferrihydrite (Fh) had a higher adsorption capacity for EDTA-Cu(II) compared to EDTA-Cr(III). The adsorption performance of Fh for EDTA-Cu(II) was consistently stronger, regardless of the ratio and addition order of the coexisting EDTA-CHMs.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2023)
Review
Engineering, Environmental
Melvin S. Samuel, E. Selvarajan, Ankur Sarswat, Harshiny Muthukumar, Jaya Mary Jacob, Malavika Mukesh, Arivalagan Pugazhendhi
Summary: The demand for freshwater is expected to rise in the next few decades due to global population growth and industrial development. Arsenic contamination in groundwater is a major worldwide issue, with various methods such as adsorption and filtration being used to address it. Nanomaterials and biopolymers are widely used for arsenic removal, with studies focusing on their sorption mechanisms and performance.
JOURNAL OF HAZARDOUS MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Marco Sanna Angotzi, Valentina Mameli, Alessandra Fantasia, Claudio Cara, Fausto Secci, Stefano Enzo, Marianna Gerina, Carla Cannas
Summary: This study investigates the removal of As-V and As-III from water using iron oxides/oxyhydroxides, with akaganeite found to be the most effective sorbent in the pH range 2-8. The surface chemistry of the sorbents plays a crucial role in the arsenic uptake, and the ability to modify the starting pH is a key factor in determining the removal performance. The study provides insights into the uptake mechanism and offers a direct comparison among the sorbents.
Article
Engineering, Environmental
Xiaofeng Yi, Shenhua Huang, Lu Chang, Zhaoshou Wang, Yuanpeng Wang
Summary: The study investigated As(V) immobilization and redistribution processes during ferrihydrite reduction mediated by Geobacter sulfurreducens. The results showed that As(V) was redistributed on different minerals and EPS induced by G. sulfurreducens, with the addition of TiO2 nanoparticles delaying rather than promoting the entire process. Changes in aqueous arsenic and iron concentrations were found to be closely related to the formation time of secondary minerals.
JOURNAL OF HAZARDOUS MATERIALS
(2022)
Article
Geochemistry & Geophysics
Colin Ferrari, Eleonore Resongles, Marina Hery, Angelique Desoeuvre, Remi Freydier, Sophie Delpoux, Odile Bruneel, Corinne Casiot
Summary: The oxidation of antimonite to antimonate plays a crucial role in controlling the mobility of antimony in aquatic systems. This study investigates the fractionation of antimony isotopes during the oxidation process under mining-relevant concentrations. The results show that the fractionation of antimony isotopes is influenced by experimental conditions and reaction pathways. While antimony isotopes have the potential to serve as process tracers in water, further research and comparison with natural systems are needed.
Article
Chemistry, Applied
Min Zhou, Ruijia Yang, Xiaoyu Tan, Boqing Tie, Ming Lei, Huihui Du
Summary: Heavy metals and metalloids commonly coexist in contaminated soils, leading to complex behaviors. This study investigated the coadsorption behaviors of Cd and Sb to different soil components. The results showed that the coadsorption phenomenon is influenced by pH and the presence of other elements, and possible ternary complexes were formed.
ADSORPTION SCIENCE & TECHNOLOGY
(2022)
Article
Chemistry, Physical
Siqi Sun, Huiping Zeng, He Xu, Weihua Zhao, Wei Qi, Ruixia Hao, Jie Zhang, Dong Li
Summary: Assessing the competition between arsenate (As(V)) and phosphate (P(V)) adsorption is important for water due to their coexistence. This paper studied the competitive adsorption of As(V) and P(V) on magnetic iron-based alginate-chitosan beads using beaker experiments and XRD and FTIR techniques for characterization. In the single system, both As(V) and P(V) adsorbed onto M-IACBs according to the Langmuir model, with maximum adsorption capacities of 14.2 +/- 0.4 mg g (-1) and 18.5 +/- 0.4 mg g (-1), respectively. In the binary system, the competitive adsorption of As(V) and P(V) was well evaluated by the extended Freundlich and pseudo-second-order models. When loaded simultaneously, As(V) adsorption was more significant than that of P(V) (2.72 mg g (-1) vs. 1.71 mg g (-1)). The desorption of P(V) was favored over As(V) during sequential loading, and the adsorption of P(V) was more influenced by pH compared to As(V). The study also investigated changes in arsenic species under anoxic aqueous solutions and oxygen-enriched air. In aqueous solutions, As(V) was reduced to the more toxic and mobile As(III) by Fe(II), and As(III) exhibited desorption-readsorption behavior. In oxygen-enriched air, As(V) underwent electron transfer with Fe(II) and O-2, resulting in the appearance of As(III), which could also be oxidized back to As(V). This study provides an objective and critical evaluation of using Fe-based adsorbents for As(V) removal, offering novel insights for designing such adsorbents.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2023)
Review
Geochemistry & Geophysics
Andreas Kubier, Richard T. Wilkin, Thomas Pichler
APPLIED GEOCHEMISTRY
(2019)
Article
Engineering, Environmental
Jianqiang Zeng, Pengfei Qi, Junjie Shi, Thomas Pichler, Fuwei Wang, Yan Wang, Kunyan Sui
CHEMICAL ENGINEERING JOURNAL
(2020)
Article
Environmental Sciences
Andreas Kubier, Kay Hamer, Thomas Pichler
INTEGRATED ENVIRONMENTAL ASSESSMENT AND MANAGEMENT
(2020)
Article
Environmental Sciences
Sarah Koopmann, Henning Froellje, Kay Hamer, Andreas Kubier, Thomas Pichler
Editorial Material
Engineering, Environmental
T. Pichler, S. Koopmann
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2020)
Article
Geography
Anant Khimasia, Alessio Rovere, Thomas Pichler
Article
Water Resources
Mahmoud M. Khalil, Kay Hamer, Thomas Pichler, Abotalib Z. Abotalib
Summary: The study on the Wadi Araba Basin reveals the influence of faults on controlling groundwater flow in the Sahara, showing that springs are distributed along structurally controlled scarps and cold springs exhibit similarities with other regional water sources. The findings emphasize the complex role of faults and folds in controlling groundwater flow dynamics.
HYDROLOGICAL PROCESSES
(2021)
Article
Geochemistry & Geophysics
A. Khimasia, C. E. Renshaw, R. E. Price, T. Pichler
Summary: The study found that the porewaters in Paleochori Bay can be separated into two distinct groups with different chemical characteristics, where high-Cl fluids are enriched in certain elements and low-Cl fluids are enriched in others. Isotope analyses indicate a seawater origin for the fluids with influences from meteoric water and arc magmatic water. High-resolution sampling and GPS coordinates helped determine the discharge patterns of different fluid types in the bay.
Article
Environmental Sciences
Janin Scheplitz, Sarah Koopmann, Henning Frollje, Thomas Pichler
Summary: Sequential extraction was adjusted by increasing reagent to sample ratios to successfully extract manganese associated with carbonate phase in high-CaCO3 samples without compromising the extraction of other sedimentary phases. Replacing Na-acetate with NH4-acetate showed increased intensities for trace metals during analysis by ICP-OES due to less suppression of the analyte signal.
ENVIRONMENTAL MONITORING AND ASSESSMENT
(2021)
Article
Environmental Sciences
Andreas Kubier, Doerte Budziak, Dieter de Vries, Joerg Elbracht, Kay Hamer, Thomas Pichler
Summary: Nine groundwater bodies in northwestern Germany had high cadmium concentrations above 0.5 mu g/l, mainly due to inputs from phosphate fertilizers and atmospheric deposition. Studies revealed a significant correlation between cadmium and nitrate plus acidification in agriculture-intensive areas, where cadmium background levels could be used to re-evaluate the chemical status of groundwater bodies.
Article
Chemistry, Multidisciplinary
Hannah Roberts, Roy Price, Christoph-Cornelius Brombach, Thomas Pichler
Summary: The study reveals the presence of mercury in the marine shallow-water hydrothermal systems of Paleochori Bay, with elevated THg concentrations observed in sea surface and bottom samples, as well as significant variations in THg concentrations in pore fluids, influenced by bottom substrate types. The research also indicates a complex relationship between gas emission rates and THg flux, with different emission rates leading to varying impacts on THg emissions.
Article
Geosciences, Multidisciplinary
Mahmoud M. Khalil, Abotalib Z. Abotalib, Mohamed H. Farag, Mostafa Rabei, Ahmed A. Abdelhady, Thomas Pichler
Summary: This study used an integrated methodology to assess the causes of waterlogging and its impact on groundwater quality in the desert fringes of the Nile Valley in Egypt. Findings suggest that flood irrigation, non-planned cultivation, and wrong management decisions significantly contributed to the development of waterlogging in the area.
Article
Engineering, Environmental
Sarah Koopmann, Henning Prommer, Thomas Pichler
Summary: This study investigates the release of molybdenum (Mo) in dolomitic aquifers during managed aquifer recharge (MAR). The findings suggest that Mo is associated with easily soluble sulfurized organic matter present in intercrystalline spaces of dolomites or directly incorporated within dolomite crystals. The injection of oxygenated water causes the oxidation of pyrite and dissolution of dolomite, leading to the release of Mo.
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2022)
Article
Engineering, Environmental
Sarah Koopmann, Henning Prommer, Adam Siade, Thomas Pichler
Summary: The mobility of molybdenum in groundwater systems has been studied using a comprehensive hydrochemical dataset collected during a multi-cycle aquifer storage and recovery test. It was found that the initial mobilization of molybdenum occurs through a series of reactions, involving pyrite oxidation, dolomite dissolution, and the release of molybdenum bound to soluble sulfurized organic matter. Once released, molybdenum mobility is primarily controlled by pH-dependent surface complexation reactions and the capture by iron sulfides.
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2023)
Article
Soil Science
Kay Hamer, Imke Gudenschwager, Thomas Pichler
Article
Engineering, Environmental
Shun-Shun Chen, Xu-Xiu Chen, Tian-Yu Yang, Li Chen, Zheng Guo, Xing-Jiu Huang
Summary: A temperature-modulated sensing strategy was proposed to identify and determine BTEX compounds. Highly effective identification of BTEX was achieved using linear discrimination and convolutional neural network analyses. Additionally, quantitative analysis of concentration was accomplished by establishing the relationship between concentration and response.
JOURNAL OF HAZARDOUS MATERIALS
(2024)
Article
Engineering, Environmental
Myungkyung Noh, Jeong Yeon Sim, Jisung Kim, Jee Hwan Ahn, Hye-Young Min, Jong-Uk Lee, Jong-Sook Park, Ji Yun Jeong, Jae Young Lee, Shin Yup Lee, Hyo-Jong Lee, Choon-Sik Park, Ho-Young Lee
Summary: This study reveals that chronic exposure to PM induces chronic inflammation and development of COPD by dysregulating NAD+ metabolism and subsequent SIRT1 deficiency in pulmonary macrophages. Activation of SIRT1 by resveratrol effectively mitigates PM-induced inflammation and COPD development. Targeting metabolic and epigenetic reprogramming in macrophages induced by PM is a promising strategy for COPD treatment.
JOURNAL OF HAZARDOUS MATERIALS
(2024)
Article
Engineering, Environmental
Yu Liu, Linlin Qin, Yiming Qin, Tong Yang, Haoran Lu, Yulong Liu, Qiqi Zhang, Wenyan Liang
Summary: Co/NC/PAC electrode was prepared by compounding ZIF-67 with powder-activated carbon for the electrocatalytic treatment of nitrogen-containing heterocyclic compounds. The degradation efficiency of the four compounds reached 90.2-93.7% under optimal conditions, and the degradation order was pyridazine < pyrimidine < pyrazine < pyridine.
JOURNAL OF HAZARDOUS MATERIALS
(2024)
Article
Engineering, Environmental
Julien Couturier, Pierre Tamba Oulare, Blanche Collin, Claire Lallemand, Isabelle Kieffer, Julien Longerey, Perrine Chaurand, Jerome Rose, Daniel Borschneck, Bernard Angeletti, Steven Criquet, Renaud Podor, Hamed Pourkhorsandi, Guilhem Arrachart, Clement Levard
Summary: This study analyzes the properties of bauxite residue samples and explores the influence of bauxite ore origin, storage conditions, and storage time. The results show that the speciation of yttrium is related to the origin of bauxite ore, while no significant variation was observed with storage conditions or aging of the residues.
JOURNAL OF HAZARDOUS MATERIALS
(2024)
Article
Engineering, Environmental
Sakthinarenderan Saikumar, Ravi Mani, Mirunalini Ganesan, Inbakandan Dhinakarasamy, Thavamani Palanisami, Dharani Gopal
Summary: Microplastic contamination in marine ecosystems poses a growing concern due to its trophic transfer and negative effects on marine organisms. This study investigates the transfer and impacts of polystyrene microplastics in an estuarine food chain. The results show that microplastics can be transferred through the food chain, although the transfer rates are low. The exposed organisms exhibit stress responses, suggesting the potential risk of microplastics reaching humans through the food chain.
JOURNAL OF HAZARDOUS MATERIALS
(2024)
Review
Engineering, Environmental
Yan-Jiao Li, Ying Yuan, Wen-Bing Tan, Bei-Dou Xi, Hui Wang, Kun-Long Hui, Jia-Bao Chen, Yi-Fan Zhang, Lian-Feng Wang, Ren-Fei Li
Summary: This review investigated and analyzed the distribution, composition, and abundance of heavy metals and antibiotic resistance genes (ARGs) in landfill. The results showed that heavy metals have lasting effects on ARGs, and complexes of heavy metals and organic matter are common in landfill. This study provides a new basis to better understand the horizontal gene transfer (HGT) of ARGs in landfill.
JOURNAL OF HAZARDOUS MATERIALS
(2024)
Article
Engineering, Environmental
Jessy Joseph, Ari Vaisanen, Ajay B. Patil, Manu Lahtinen
Summary: Efficient and environmentally friendly porous hybrid adsorbent beads have been developed for the removal of arsenic from drinking water. The structural tuning of the adsorbents has been shown to have a significant impact on their adsorption performance, with high crystallinity leading to increased adsorption capacity and selectivity towards As5+.
JOURNAL OF HAZARDOUS MATERIALS
(2024)
Article
Engineering, Environmental
Yangyang Liu, Minhua Xiao, Kaiqin Huang, Juntao Cui, Hongli Liu, Yingxin Yu, Shengtao Ma, Xihong Liu, Meiqing Lin
Summary: This study measured the levels of phthalate metabolites in breast milk collected from mothers in southern China. The results showed that phthalates are still prevalent in the region, and breastfeeding contributes to phthalate intake in infants. However, the levels detected do not pose significant health risks to infants based on dietary exposure. The increasing exposure to certain phthalates calls for further research into their sources and potential risks.
JOURNAL OF HAZARDOUS MATERIALS
(2024)
Article
Engineering, Environmental
Zhiqiang Wu, Jianxing Sun, Liting Xu, Hongbo Zhou, Haina Cheng, Zhu Chen, Yuguang Wang, Jichao Yang
Summary: Ocean depth affects microbial diversity, composition, and co-occurrence patterns of microplastic microbial communities. Deterministic processes dominate the assembly of mesopelagic plastisphere microbial communities, while stochastic processes shape the assembly of bathypelagic microbial communities. The relationships between microorganisms in the mesopelagic layer are more complex and stable, with Proteobacteria and Actinobacteriota playing important roles.
JOURNAL OF HAZARDOUS MATERIALS
(2024)
Article
Engineering, Environmental
Tingting Xiao, Renjie Chen, Chen Cai, Shijie Yuan, Xiaohu Dai, Bin Dong, Zuxin Xu
Summary: Based on the efficiency of catalytic ozonation techniques in enhancing sludge dewaterability, this study investigated its effectiveness in simultaneous reduction of antibiotics and antibiotic resistance genes. The results showed that catalytic ozonation conditioning changed the distribution of antibiotics and achieved high degradation rates. It also significantly reduced the abundance of ARGs, inhibited horizontal gene transfer, and decreased the signal transduction of typical ARGs host bacteria.
JOURNAL OF HAZARDOUS MATERIALS
(2024)
Article
Engineering, Environmental
Yang Deng, Xiaohong Guan
Summary: This article discusses two different development approaches for ferrate(VI) technology in water treatment, arguing that process integration is a promising method that can drive technological innovation and revolution in water treatment, achieving higher treatment efficiency, reduced costs and energy consumption, and a smaller physical footprint.
JOURNAL OF HAZARDOUS MATERIALS
(2024)
Article
Engineering, Environmental
Zhe Zhang, Lu Zhang, Zhihao Huang, Yuxin Xu, Qingqing Zhao, Hongju Wang, Meiqing Shi, Xiangnan Li, Kai Jiang, Dapeng Wu
Summary: In this study, a floating catalytic foam was designed and prepared to enhance the mass transfer in immobilized photocatalysts for wastewater treatment. The floating catalytic foam could float on the water surface and establish a temperature gradient, effectively promoting the diffusion and adsorption of target molecules during the photocatalytic process.
JOURNAL OF HAZARDOUS MATERIALS
(2024)
Article
Engineering, Environmental
Muhammad Nafees, Adiba Khan Sehrish, Sarah Owdah Alomrani, Linlin Qiu, Aasim Saeed, Shoaib Ahmad, Shafaqat Ali, Hongyan Guo
Summary: The accumulation of cadmium and antibiotics in edible plants and fertile soil is a worldwide problem. This study investigated the potential of zinc oxide nanoparticles to alleviate the toxicity of both cadmium and antibiotics and promote spinach growth.
JOURNAL OF HAZARDOUS MATERIALS
(2024)
Article
Engineering, Environmental
Lurui Wan, Kai Wang, Yuan Chen, Zhiyong Xu, Wenbo Zhao
Summary: In this study, a low viscosity and high thermal stability SO2 absorbent with dual interacting sites was successfully synthesized. The absorbent showed the highest absorption enthalpy change and entropy change values among reported SO2 absorbents, and exhibited lower viscosity and comparable thermal stability to ILs.
JOURNAL OF HAZARDOUS MATERIALS
(2024)
Article
Engineering, Environmental
Zhengwei Zhou, Guojie Ye, Yang Zong, Zhenyu Zhao, Deli Wu
Summary: This study utilized Mo powder and STPP to enhance the performance of the sodium percarbonate system in pollutant degradation. The presence of Mo and STPP resulted in a higher degradation rate of the model pollutant SMX, with low oxidant consumption. The system generated multiple active species through a series of chain reactions at different pH values, exhibiting excellent performance towards electron-rich pollutants. Furthermore, Mo demonstrated excellent stability and reusability.
JOURNAL OF HAZARDOUS MATERIALS
(2024)