4.3 Article

Synthesis, characterization, and application of ZnO/TiO2 nanocomposite for photocatalysis of a herbicide (Bentazon)

Journal

DESALINATION AND WATER TREATMENT
Volume 57, Issue 29, Pages 13632-13644

Publisher

DESALINATION PUBL
DOI: 10.1080/19443994.2015.1060541

Keywords

Photocatalysis; Bentazon; Nanocomposite; Zinc oxide; titanium oxide

Funding

  1. Iran University of Medical Sciences, Iran
  2. [93-02-193-24775]

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The purpose of this investigation was to study the applicability of ZnO-TiO2 composite as a photocatalyst for degradation of Bentazon. Effects of various parameters such as catalyst dosage, pH, initial Bentazon concentration, oxygen purging gas, hydrogen peroxide concentration and type of organic compounds on the removal efficiency of Bentazon were studied. The results of SEM and FT-IR analysis demonstrated favorable immobilization of zinc oxide nanoparticles onto TiO2. The greatest removal of Bentazon was observed at neutral pH due to photo-corrosion of ZnO on composite in acidic and basic conditions. The pseudo-first-order rate constant (k(obs)) and electrical energy per order (E-Eo) were greatly dependent on the Bentazon concentration. Removal efficiency of Bentazon was increased with O-2 purging and addition of H2O2, while it was decreased in the presence of organic compounds. Removal efficiency of Bentazon by UV/ZnO/TiO2 process was greater than that by UV/TiO2 process, UV/ZnO, and UV alone. Photocatalytic activity was maintained even after five successive cycles.

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