Journal
JOURNAL OF COORDINATION CHEMISTRY
Volume 70, Issue 14, Pages 2425-2435Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/00958972.2017.1343945
Keywords
Zn(II) complexes; hydrazones; crystal structure; antimicrobial activity; pseudohalides
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Funding
- Ministry of Education, Science and Technological development of the Republic of Serbia [OI 172055]
- Slovenian Research Agency [P1-0175]
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Two Zn(II) complexes with the condensation product of 2-quinolinecarboxaldehyde and trimethylammonium acetohydrazide chloride (Girard's T reagent) (HLCl) and monodentate pseudohalides (azide and cyanate) have been synthesized and characterized by elemental analysis, IR and NMR spectroscopy, and single-crystal X-ray diffraction. In both complexes, the coordination surroundings of the Zn(II) ions consist of a deprotonated hydrazone ligand coordinated through an NNO set of donor atoms and two monodentate pseudohalides (N-3(-) or NCO-) at the remaining coordination sites. The Zn(II) complexes showed low to moderate activity against laboratory control strains of pathogenic bacteria and fungi. [GRAPHICS] .
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