Journal
JOURNAL OF COORDINATION CHEMISTRY
Volume 70, Issue 5, Pages 757-779Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/00958972.2017.1278572
Keywords
N; N; N-tris(3; 5-dimethylpyrazol-1-ylmethyl)amine; N; N-bis(3; 5-dimethylpyrazol-1-ylmethyl)amine; In situ synthesis; complexes; crystal structure
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This paper reviews the coordination chemistry of polypyrazolylmethylamines as tripodal tetradentate (L-S=N,N,N-tris(3,5-dimethylpyrazol-1-ylmethyl)amine) and dipodal tridentate (L-D=N,N,-bis(3,5-dimethylpyrazol-1-ylmethyl)amine) ligands. References to the methods for the synthesis of both the ligands alone and their transition metal complexes are given with emphasis placed on the structural features of the latter. Special attention was paid to the one-pot synthesis, which is a new method for isolation of various metal complexes with N,N-bis- and N,N,N-trispyrazolylmethylamines and co-ligands, such as urotropine and 3,5-dimethylpyrazole. The complexes in question were created in situ from 1-hydroxymethyl-3,5-dimethylpyrazole (L-0) and zerovalent metals. [GRAPHICS]
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