Article
Engineering, Chemical
Saidah Altway, Snehal C. Pujar, Andre B. de Haan
Summary: The effect of fructose on the extraction performance of HMF was studied. It was found that fructose had minimal effect on the extraction performance in the LLE system using [EMIM][BF4], but the separation factors decreased by around 1.1 times. However, in the LLE system using ChCl-urea, fructose decreased the separation factors by around 1.3 times and distribution coefficients of HMF by around 1.1 times.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2022)
Article
Thermodynamics
Hongyue Guo, Tianyi Cao, Yicong Zhao, Haigang Liu, Jun Li, Qingsong Li
Summary: In this study, cyclohexanone and water were successfully separated in a solvent system using liquid-liquid extraction. The distribution coefficient and selectivity factor of the extractant were determined based on experimental data and models, with the NRTL and UNIQUAC models showing good agreement with the data. Furthermore, a graphical user interface was utilized to verify the consistency of the regression parameters.
JOURNAL OF CHEMICAL THERMODYNAMICS
(2022)
Article
Thermodynamics
Hongyue Guo, Hui Li, Wei Wang, Bing Li, Qingsong Li
Summary: The liquid-liquid equilibrium data of the ternary mixture of water, cyclohexanone, and mesityl oxide at different temperatures and pressures were presented. The distribution coefficient and separation factor were used to assess the efficiency of extracting cyclohexanone from water. The NRTL and UNIQUAC models successfully correlated the experimental data with good reliability.
JOURNAL OF CHEMICAL THERMODYNAMICS
(2021)
Article
Chemistry, Physical
Qingsong Li, Hongyue Guo, Song Lin, Yicong Zhao, Hui Li
Summary: The study evaluated the ability to extract DEM from water using liquid-liquid equilibrium data, distribution coefficient, and separation coefficient, demonstrating the accuracy and relevance of the models used.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Thermodynamics
Wenyang Fan, Qing Li, Dongmei Xu, Jun Gao, Huiwen Huang, Yinglong Wang
Summary: In this study, the separation of formaldehyde from its aqueous solution was investigated. The separation effect was evaluated using the separation factor and partition coefficient. It was found that cyclohexanone is a suitable extractant compared to methyl isobutyl ketone. The experimental data was fitted using the quasi-chemical theory and nonrandom two-liquid theory models, with good agreement. The binary interaction parameters were validated using a topology of Gibbs energy analysis.
JOURNAL OF CHEMICAL AND ENGINEERING DATA
(2022)
Article
Thermodynamics
Mai Han, Song Lin, Mingyi Xu, Yueyang Jiang, Qingqing Yin, Yufan Pang, Yujian Song, Qingsong Li
Summary: This study obtained the liquid-liquid equilibrium data of tetrahydrofurfuryl alcohol (THFA) in aqueous solution using two solvents. The results showed that both solvents are excellent for extracting THFA.
JOURNAL OF CHEMICAL THERMODYNAMICS
(2022)
Article
Thermodynamics
Guangyuan Chen, Yunhai Shi, Rongchun Shen, Wei Li, Jinghong Zhou
Summary: The study utilized 5-methyl-2-hexanone as the extraction agent for separating the azeotrope of ethylene glycol and 1,2-butanediol, and calculated the relevant coefficients from experimental data. The results indicated that using 5-methyl-2-hexanone was more effective, with the experimental data closely matching the calculated values.
JOURNAL OF CHEMICAL THERMODYNAMICS
(2022)
Article
Chemistry, Physical
Francesca Liguori, Claudio Oldani, Laura Capozzoli, Nicola Calisi, Pierluigi Barbaro
Summary: The solvent-free hydrogenation of acetone was investigated using bifunctional heterogeneous catalysts, and the main reaction parameters were systematically analyzed to determine their effect on the reaction outputs. A reproducible trend was observed, and the best compromise results were obtained with the 0.26Pd@X-link-08-PW79 catalyst at 19.7% acetone conversion, showing a selectivity of 92% and a productivity of 37.0 mmol(MIBK) g(cat)(-1)h(-1).
APPLIED CATALYSIS A-GENERAL
(2021)
Article
Engineering, Chemical
Vanessa A. A. Mascietti, Larissa Silva Farias, Frederico W. W. Tavares, Papa M. M. Ndiaye
Summary: New liquid-liquid equilibrium data of ternary systems of mono ethylene glycol + n-pentane + methanol, mono-ethylene glycol (MEG) + n-pentane + ethanol, and mono ethylene glycol + n-pentane + n-butanol were determined. The solubility of alcohols in the mixtures was found to increase with temperature and decrease with increasing alcohol chain length. The obtained experimental data were successfully correlated using the CPA and the PC-SAFT equation with appropriate binary interaction parameters.
CANADIAN JOURNAL OF CHEMICAL ENGINEERING
(2023)
Article
Thermodynamics
Yaqi Ding, Neng Gao, Nian Li, Guangming Chen, Yongmei Xuan
Summary: The vapor liquid equilibrium data of four ternary solutions with ionic liquids as additives were measured and show lower vapor pressure compared to binary solutions without ILs. Different ILs have varying effects on reducing the vapor pressure of HCOOK + H2O under specific conditions.
JOURNAL OF CHEMICAL THERMODYNAMICS
(2021)
Article
Energy & Fuels
Mingmei Wang, Lin Li, Erqiang Wang
Summary: In this study, a new separation process based on a dividing wall column, HA-DWC-U, was developed to address the difficulty of extracting high-purity MIBK from complex azeotropes. Through thermodynamic research and steady-state simulation optimization, the results demonstrate that HA-DWC-U has significant advantages over traditional separation processes, with a 18.47% savings in total utility cost and 17.86% savings in total annual cost.
CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION
(2022)
Article
Chemistry, Physical
Zhiguo Lv, Yan Zhang, Yiming Gong, Zhenmei Guo, Chao Zhang
Summary: A Pd/Al2O3-CeO2 nanosheets catalyst was successfully prepared for the conversion of acetone to methyl isobutyl ketone (MIBK). The catalyst exhibited high catalytic activity and selectivity, and DFT calculations showed that Pd/Al2O3-CeO2 could increase the electron activity of acetone and facilitate its hydrogenation process.
Article
Thermodynamics
Yixin Ma, Dongmei Xu, Tao Zhang, Feng Wei, Lin Yang, Jun Gao, Lianzheng Zhang, Yinglong Wang
Summary: In this study, three organic solvents were selected as extractants to recover 2,2,2-trifluoroethanol (TFE) from its azeotropic mixture with water. The results showed that isobutyl acetate has better extraction ability.
JOURNAL OF CHEMICAL AND ENGINEERING DATA
(2023)
Article
Thermodynamics
Houchun Yan, Yuanyuan Han, Shiwei Sun, Mai Han, Wenyang Fan, Qingsong Li
Summary: Liquid-liquid equilibrium (LLE) data of water + tetrahydrofurfuryl alcohol (THFA) + isopentanol/1-hexanol were measured at different temperatures. The distribution coefficient and separation coefficient of THFA were used for evaluation. The NRTL and UNIQUAC models were employed to connect the measured data and calculate the binary interaction parameters. The consistency between the calculated parameters and experimental data was confirmed using GUI-MATLAB.
JOURNAL OF CHEMICAL THERMODYNAMICS
(2022)
Article
Engineering, Chemical
Christian F. Breitkreuz, Jakob Burger, Hans Hasse
Summary: Solid precipitation from aqueous formaldehyde solutions is a major technical problem that is difficult to predict and mitigate. This study developed a new method to measure the solid-liquid equilibria and kinetics of solid formation in formaldehyde-containing systems, obtaining reliable data and proposing a physico-chemical model to explain the phenomena.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2022)
Article
Thermodynamics
Qingsong Li, Midong Shi, Liping Wang, Gaoyin He, Fan Gan
JOURNAL OF CHEMICAL AND ENGINEERING DATA
(2018)
Article
Thermodynamics
Midong Shi, Gaoyin He, Fan Gan, Xuemin Yu, Qingsong Li
JOURNAL OF CHEMICAL AND ENGINEERING DATA
(2017)
Article
Thermodynamics
Chong Yang, Hai Liu, Chuanfu Zhu, Midong Shi, Gaoyin He, Qingsong Li
JOURNAL OF CHEMICAL AND ENGINEERING DATA
(2018)
Article
Thermodynamics
Chuanfu Zhu, Yingmin Yu, Hui Jiang, Qingsong Li
JOURNAL OF CHEMICAL AND ENGINEERING DATA
(2018)
Article
Thermodynamics
Peng Cui, Hai Liu, Kun Xin, Houchun Yan, Qing Xia, Yunjing Huang, Qingsong Li
JOURNAL OF CHEMICAL THERMODYNAMICS
(2018)
Article
Thermodynamics
Qingsong Li, Bing Jia, Liping Wang, Mengmeng Yan, Hai Liu, Yingmin Yu
JOURNAL OF CHEMICAL THERMODYNAMICS
(2018)
Article
Chemistry, Physical
Chong Yang, Xuemin Yu, Liping Wang, Midong Shi, Gaoyin He, Qingsong Li
JOURNAL OF MOLECULAR LIQUIDS
(2018)
Article
Thermodynamics
Liping Wang, Saisai Zhou, Midong Shi, Bing Jia, Hai Liu, Qingsong Li
JOURNAL OF CHEMICAL AND ENGINEERING DATA
(2018)
Article
Thermodynamics
Liping Wang, Saisai Zhou, Pan Li, Pengzhou Li, Qingsong Li, Yingmin Yu
JOURNAL OF CHEMICAL AND ENGINEERING DATA
(2018)
Article
Thermodynamics
Bing Jia, Liping Wang, Mengmeng Yan, Hai Liu, Yingmin Yu, Qingsong Li
JOURNAL OF CHEMICAL AND ENGINEERING DATA
(2018)
Article
Thermodynamics
Lili Zhang, Zhaohui Liao, Chuanfu Zhu, Yingmin Yu, Qingsong Li
JOURNAL OF CHEMICAL AND ENGINEERING DATA
(2019)
Article
Chemistry, Physical
Chong Yang, Qingsong Li
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
(2019)
Article
Thermodynamics
Lili Zhang, Yingmin Yu, Zhaohui Liao, Xiaosheng Xu, Xin Huang, Bing Jia, Qingsong Li
JOURNAL OF CHEMICAL AND ENGINEERING DATA
(2020)
Article
Thermodynamics
Hongyue Guo, Hui Li, Yuhe Song, Qingsong Li
Summary: The study investigated the extraction of 2-butanone and water from azeotropic system using different solvents, finding that p-xylene is more suitable for extraction. The reliability of the experimental data was verified using different equations, with UNIQUAC model showing a better correlation than NRTL model for this system.
JOURNAL OF CHEMICAL AND ENGINEERING DATA
(2021)