Unusual non-bifunctional mechanism for Co-PNP complex catalyzed transfer hydrogenation governed by the electronic configuration of metal center

Hydrogenation of Esters to Alcohols with a Well-Defined Iron Complex

(2014) Svenja Werkmeister et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rational development of iron catalysts for asymmetric transfer hydrogenation

(2014) Peter E. Sues et al.   DALTON TRANSACTIONS

Catalytic Mechanisms of Direct Pyrrole Synthesis via Dehydrogenative Coupling Mediated by PNP-Ir or PNN-Ru Pincer Complexes: Crucial Role of Proton-Transfer Shuttles in the PNP-Ir System

(2014) Shuanglin Qu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Based Catalysts for the Hydrogenation of Esters to Alcohols

(2014) Sumit Chakraborty et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron Catalysts Containing Amine(imine)diphosphine P-NH-N-P Ligands Catalyze both the Asymmetric Hydrogenation and Asymmetric Transfer Hydrogenation of Ketones

(2014) Weiwei Zuo et al.   ORGANOMETALLICS

Computational Mechanistic Study of Fe-Catalyzed Hydrogenation of Esters to Alcohols: Improving Catalysis by Accelerating Precatalyst Activation with a Lewis Base

(2014) Shuanglin Qu et al.   ACS Catalysis

Well-Defined Iron Catalysts for the Acceptorless Reversible Dehydrogenation-Hydrogenation of Alcohols and Ketones

(2014) Sumit Chakraborty et al.   ACS Catalysis

Cobalt-catalyzed transfer hydrogenation of CO and CN bonds

(2013) Guoqi Zhang et al.   CHEMICAL COMMUNICATIONS

Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO2 Fixation

(2013) Aaron M. Appel et al.   CHEMICAL REVIEWS

Mechanism of the Methyltrioxorhenium-Catalyzed Deoxydehydration of Polyols: A New Pathway Revealed

(2013) Shuanglin Qu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Density Functional Theory Mechanistic Study of the Reduction of CO2 to CH4 Catalyzed by an Ammonium Hydridoborate Ion Pair: CO2 Activation via Formation of a Formic Acid Entity

(2013) Mingwei Wen et al.   INORGANIC CHEMISTRY

The effect of substituents on the hydrogenation of an aldehyde catalyzed by Knölker's catalyst

(2013) Xi Lu et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Understanding the Mechanisms of Cobalt-Catalyzed Hydrogenation and Dehydrogenation Reactions

(2013) Guoqi Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The mechanism for the hydrogenation of ketones catalyzed by Knölker's iron-catalyst

(2013) Xi Lu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Cobalt-Catalyzed Acceptorless Alcohol Dehydrogenation: Synthesis of Imines from Alcohols and Amines

(2013) Guoqi Zhang et al.   ORGANIC LETTERS

Amine(imine)diphosphine Iron Catalysts for Asymmetric Transfer Hydrogenation of Ketones and Imines

(2013) W. Zuo et al.   SCIENCE

Mild and Homogeneous Cobalt-Catalyzed Hydrogenation of CC, CO, and CN Bonds

(2012) Guoqi Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Interconversion of CO2 and formic acid by bio-inspired Ir complexes with pendent bases

(2012) Etsuko Fujita et al.   BIOCHIMICA ET BIOPHYSICA ACTA-BIOENERGETICS

Computational Insight into the Mechanism of Selective Imine Formation from Alcohol and Amine Catalyzed by the Ruthenium(II)-PNP Pincer Complex

(2012) Haixia Li et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Computational Mechanistic Study of the Hydrogenation of Carbonate to Methanol Catalyzed by the RuIIPNN Complex

(2012) Haixia Li et al.   INORGANIC CHEMISTRY

The Mechanism of Efficient Asymmetric Transfer Hydrogenation of Acetophenone Using an Iron(II) Complex Containing an (S,S)-Ph2PCH2CH═NCHPhCHPhN═CHCH2PPh2 Ligand: Partial Ligand Reduction Is the Key

(2012) Alexandre A. Mikhailine et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Transfer Hydrogenation of Ketimines Using Well-Defined Iron(II)-Based Precatalysts Containing a PNNP Ligand

(2012) Alexandre A. Mikhailine et al.   ORGANIC LETTERS

Spectroscopic and DFT Study of Ferraaziridine Complexes Formed in the Transfer Hydrogenation of Acetophenone Catalyzed Using trans-[Fe(CO)(NCMe)(PPh2C6H4CH═NCH2−)2-κ4P,N,N,P](BF4)2

(2012) Demyan E. Prokopchuk et al.   ORGANOMETALLICS

Inner-Sphere Activation, Outer-Sphere Catalysis: Theoretical Study on the Mechanism of Transfer Hydrogenation of Ketones Using Iron(II) PNNP Eneamido Complexes

(2012) Demyan E. Prokopchuk et al.   ORGANOMETALLICS

Cyclometalated Complexes of Ruthenium, Rhodium and Iridium as Catalysts for Transfer Hydrogenation of Ketones and Imines

(2011) Nicolas Pannetier et al.   ADVANCED SYNTHESIS & CATALYSIS

Insights into Dehydrogenative Coupling of Alcohols and Amines Catalyzed by a (PNN)–Ru(II) Hydride Complex: Unusual Metal–Ligand Cooperation

(2011) Guixiang Zeng et al.   INORGANIC CHEMISTRY

Low-Valent Ene–Amido Iron Complexes for the Asymmetric Transfer Hydrogenation of Acetophenone without Base

(2011) Paraskevi O. Lagaditis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Merging the old with the new

(2011) Marcetta Y. Darensbourg et al.   Nature Chemistry

Computational Mechanistic Study on Cp*Ir Complex-Mediated Acceptorless Alcohol Dehydrogenation: Bifunctional Hydrogen Transfer vs β-H Elimination

(2011) Haixia Li et al.   ORGANOMETALLICS

On the “Reverse Gear”Mechanism of the Reversible Dehydrogenation/Hydrogenation of a Nitrogen Heterocycle Catalyzed by a Cp*Ir Complex: A Computational Study

(2011) Haixia Li et al.   ORGANOMETALLICS

Computational Study on the Catalytic Role of Pincer Ruthenium(II)-PNN Complex in Directly Synthesizing Amide from Alcohol and Amine: The Origin of Selectivity of Amide over Ester and Imine

(2011) Haixia Li et al.   ORGANOMETALLICS

Artificial hydrogenases

(2010) Bryan E Barton et al.   CURRENT OPINION IN BIOTECHNOLOGY

Iron Complexes for the Catalytic Transfer Hydrogenation of Acetophenone: Steric and Electronic Effects Imposed by Alkyl Substituents at Phosphorus

(2010) Paraskevi O. Lagaditis et al.   INORGANIC CHEMISTRY

Highly Enantioselective Hydrogenation of α-Arylmethylene Cycloalkanones Catalyzed by Iridium Complexes of Chiral Spiro Aminophosphine Ligands

(2010) Jian-Bo Xie et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Multifunctional ligands in transition metal catalysis

(2010) Robert H. Crabtree   NEW JOURNAL OF CHEMISTRY

Asymmetric hydrosilylation, transfer hydrogenation and hydrogenation of ketones catalyzed by iridium complexes

(2009) Raluca Malacea et al.   COORDINATION CHEMISTRY REVIEWS

Performance of SM6, SM8, and SMD on the SAMPL1 Test Set for the Prediction of Small-Molecule Solvation Free Energies

(2009) Aleksandr V. Marenich et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Efficient Asymmetric Transfer Hydrogenation of Ketones Catalyzed by an Iron Complex Containing a P−N−N−P Tetradentate Ligand Formed by Template Synthesis

(2009) Alexandre Mikhailine et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cyclopentadienone Iron Alcohol Complexes: Synthesis, Reactivity, and Implications for the Mechanism of Iron-Catalyzed Hydrogenation of Aldehydes

(2009) Charles P. Casey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Monoiron Hydrogenase Catalysis: Hydrogen Activation with the Formation of a Dihydrogen, Fe−Hδ−···Hδ+−O, Bond and Methenyl-H4MPT+Triggered Hydride Transfer

(2009) Xinzheng Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Small molecule mimics of hydrogenases: hydrides and redox

(2008) Frédéric Gloaguen et al.   CHEMICAL SOCIETY REVIEWS

Role of the NH2 Functionality and Solvent in Terdentate CNN Alkoxide Ruthenium Complexes for the Fast Transfer Hydrogenation of Ketones in 2-Propanol

(2008) Walter Baratta et al.   CHEMISTRY-A EUROPEAN JOURNAL

Computational Study of the Factors Controlling Enantioselectivity in Ruthenium(II) Hydrogenation Catalysts

(2008) Devis Di Tommaso et al.   INORGANIC CHEMISTRY

Origin of Enantioselective Hydrogenation of Ketones by RuH2(diphosphine)(diamine) Catalysts: A Theoretical Study

(2008) Tom Leyssens et al.   ORGANOMETALLICS