Journal
DALTON TRANSACTIONS
Volume 44, Issue 19, Pages 9038-9043Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt00447k
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Funding
- Danish National Research Foundation (Center for Materials Crystallography) [DNRF93]
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The crystal structure of the linear metal chain compound Co-3(dpa)(4)Br-2 center dot CH2Cl2 (1) has been investigated up to a pressure of 13.6(2) GPa in a diamond anvil cell (DAC) using single crystal X-ray diffraction. The structure remains orthorhombic as the unit cell volume is reduced by 30% at 12.8 GPa. At 13.6(2) GPa the diffraction pattern is of very poor quality and not even reliable unit cell parameters can be determined. Peak broadening resulting from non-hydrostatic conditions was avoided by annealing the loaded DAC prior to data collection, allowing reliable structural models to be refined up to a pressure of 11.8(2) GPa. On increasing pressure, the disordered CH2Cl2 crystal solvent molecule gradually becomes redistributed from one site to another. Hirshfeld surface analysis suggests that the redistribution is a result of repulsive H center dot center dot center dot H interactions. Pressure also affects the molecular geometry, in particular the Co-Co and Co-Br bond lengths which decrease by 4% and 12%, respectively, at 11.8(2) GPa.
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