Journal
DALTON TRANSACTIONS
Volume 44, Issue 20, Pages 9345-9348Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4dt03743j
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Funding
- JSPS [26107529, 26288026, 2506]
- MEXT, Japan
- Grants-in-Aid for Scientific Research [26107529, 2506, 26288026, 13F03340] Funding Source: KAKEN
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Two solvated cobalt(II) terpyridine complexes, [Co(MeO-terpy)(2)]-(BF4)(2)center dot H2O (1 center dot H2O) and [Co(MeO - terpy)(2)](BF4)(2)center dot acetone (1 center dot acetone) were prepared. Annealing each of these complexes resulted in the formation of two desolvated species, 1 and 1', respectively. 1 center dot H2O and 1 exhibited two - step and gradual SCO. The compound 1 center dot acetone has high - spin at all temperatures and 1' undergoes a reverse spin transition due to a phase change.
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