Journal
DALTON TRANSACTIONS
Volume 44, Issue 34, Pages 15126-15129Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt00793c
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Funding
- MEXT, Japan [26620049]
- MEXT [30467279]
- Center of Advanced Instrumental Analysis, Kyushu University
- Kyushu University Interdisciplinary Program in Education and Projects in Research Development
- Grants-in-Aid for Scientific Research [26620049, 15K13661] Funding Source: KAKEN
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A composite containing a liposome and a lipophilic ruthenium complex was synthesized to regulate an O-2 evolution reaction using cerium(IV) ammonium nitrate as an oxidizing reagent. We found that the surrounding environment of the reaction centre is an important factor for controlling the O-2 evolution catalytic reaction. We successfully regulated the reaction activity using the linker length of the lipophilic ligand and using the head groups of the phospholipid component.
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