Article
Environmental Sciences
Nishanthi Ellepola, Talysa Viera, Praveen L. Patidar, Gayan Rubasinghege
Summary: This study investigates the impact of minerals on the degradation of diclofenac and its photo-degradation products, as well as their potential health effects. The results show that kaolinite enhances the degradation of diclofenac, while anatase diminishes its degradation. Some photo-degraded compounds are more cytotoxic than diclofenac itself.
ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY
(2022)
Article
Nanoscience & Nanotechnology
Arkaprabha Giri, Subha Biswas, Md Waseem Hussain, Tapas Kumar Dutta, Abhijit Patra
Summary: This research successfully controlled the morphology of nanostructured hypercrosslinked porous organic polymers using different polymerization methods, resulting in irregular aggregates, rigid spheres, and two-dimensional nanosheets. The study also found that reaction temperature, catalysts, and solvents have significant effects on the morphology. Additionally, sulfonated 2D sheet-like polymers exhibited rapid adsorption kinetics and excellent recyclability for various toxic organic micropollutants in water.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Engineering, Chemical
Marta Bauza, Gemma Turnes Palomino, Carlos Palomino Cabello
Summary: In this study, a magnetic hybrid carbon@MOF material was prepared by combining hypercrosslinked polymer-derived carbon and MIL-100(Fe) MOF. The developed material showed good adsorption performance for the removal of the emerging pollutant diclofenac (DCF) and demonstrated high adsorption capacity and excellent reusability.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)
Article
Engineering, Environmental
Muhamad Sharafee Shamsudin, Azam Taufik Mohd Din, Lotfi Sellaoui, Michael Badawi, Adrian Bonilla-Petriciolet, Suzylawati Ismail
Summary: Trace pharmaceutical concentrations in wastewater pose a major threat to the environment and human health. Conventional treatment methods are ineffective in removing these organic pollutants. This study evaluates the use of kaolin modified with cetylpyridinium chloride for diclofenac removal, achieving a high removal rate of 93.53% and adsorption capacity of 392.3 μg/g.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Environmental Sciences
S. Bielfeldt, D. Urquhart, M. Brandt, N. Hennighausen, R. Bazzanella
Summary: Diclofenac, a widely used topical treatment for pain and inflammation, may not be completely removed from hands after washing. This study quantifies the amount of diclofenac present in rinse water after applying a diclofenac gel and washing hands. The results show that wiping hands before washing can significantly reduce diclofenac release into the wastewater system. This study highlights the importance of wiping hands to minimize the residual diclofenac after product application.
Article
Environmental Sciences
T. Di Lorenzo, M. Cifoni, M. Baratti, G. Pieraccini, W. D. Di Marzio, D. M. P. Galassi
Summary: Groundwater is the largest source of liquid freshwater on Earth, with diverse ecosystems that provide important ecological services. Pharmaceutical compounds such as diclofenac pose different environmental risks in European groundwater, with varying risk expectations based on different assessment scenarios.
ENVIRONMENTAL POLLUTION
(2021)
Review
Chemistry, Analytical
Nejla Cini, Aysegul Golcu
Summary: This review highlights the most recent spectrophotometric approaches applied to analyze various classes of drugs in biological media and/or dosage forms, with a focus on direct and derivative UV/UV-Vis spectrophotometry. The versatility, ease of application, low cost, and fast response of spectrophotometric methods make them one of the most preferable methods in drug analysis, providing high accuracy and precision with a wide linear range.
CURRENT ANALYTICAL CHEMISTRY
(2021)
Article
Chemistry, Physical
Rebecca Dhawle, Dionissios Mantzavinos, Panagiotis Lianos
Summary: This study aimed to construct an integrated reactor that could generate hydrogen peroxide through photoelectrocatalysis under solar radiation and simultaneously degrade recalcitrant pollutants through the UV/H2O2 process. The chosen water-soluble model pollutant, diclofenac, was effectively degraded in the experiment. Results showed that the integrated reactor is a realistic and effective solution for sustainable environmental remediation.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2021)
Article
Environmental Sciences
Anton Puga, Marta Pazos, Emilio Rosales, M. Angeles Sanroman
Summary: This study investigated the adsorption of Diclofenac on a commercial carbonaceous aerogel monolith and found that anodic polarization enhanced the removal efficiency of DCF. Additionally, cathodic polarization proved to be a viable regeneration alternative for the spent aerogel. Sequential electro-adsorption/electro-desorption cycles confirmed the feasibility of this strategy for pollutant removal.
Article
Chemistry, Multidisciplinary
Aleksandra Jovanoski Kostic, Nikola Kanas, Vladimir Rajic, Annu Sharma, Subramshu S. S. Bhattacharya, Stevan Armakovic, Maria M. M. Savanovic, Sanja J. J. Armakovic
Summary: Water pollution is a significant issue, and photocatalysis is a promising and environment-friendly approach for water purification. The study found that SLTO and SCNPTO nano-sized powders have good photocatalytic activity in removing residual pindolol from water.
Article
Engineering, Environmental
Cesar Vinicius Toniciolli Rigueto, Marieli Rosseto, Mateus Torres Nazari, Bruna Elisangela Pessini Ostwald, Ingridy Alessandretti, Christian Manera, Jeferson Steffanello Piccin, Aline Dettmer
Summary: This study aimed to produce composite beads for diclofenac removal using gelatin recovered from chromium tanned leather waste and carbon nanotubes, showing similar adsorption capacities and kinetic behaviors as commercial gelatin and carbon nanotubes, with potential applications in water treatment.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2021)
Article
Engineering, Environmental
Marketa Spacilova, Simona Krejcikova, Ywetta Maleterova, Frantisek Kastanek, Olga Solcova
Summary: This study investigates the scalability and durability of TiO2/UV photocatalyst for wastewater treatment. The results show that the prepared TiO2 layers are capable of effectively reducing the concentration of pollutants in wastewater, and the efficiency of the photocatalytic process remains stable during long-term tests.
WATER SCIENCE AND TECHNOLOGY
(2022)
Article
Chemistry, Analytical
Alejandro Martin, Elia Santigosa, Maria Ramos-Payan
Summary: Microfluidic devices have made significant advancements in recent years and have become an important tool in pharmaceutical analysis. This study proposes a green microfluidic method for the simultaneous extraction of basic polar and non-polar compounds, offering a more sustainable and environmentally friendly alternative.
MICROCHEMICAL JOURNAL
(2023)
Article
Engineering, Environmental
J. Meijide, G. Lama, M. Pazos, M. A. Sanroman, P. S. M. Dunlop
Summary: Contaminants of emerging concern, including pharmaceuticals, are detected at low concentrations in surface waters, posing potential risks to aquatic life and the food chain. This review focuses on the removal of active pharmaceutical ingredients using ultraviolet processes, such as photo-Fenton, photocatalysis, and photoelectrocatalysis. However, there is limited research on scaling up the systems and testing their effectiveness in real water matrices.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Article
Chemistry, Applied
Weipeng Sun, Junwei Wang, Yongqiang Shi, Ziang Wu, Yumin Tang, Kui Feng, Han Young Woo, Xugang Guo, Fei-Bao Zhang
Summary: A series of random terpolymer acceptors with A(1)-A(2)-A(3) backbone were synthesized using random copolymerization strategy, among which PBTP showed good performance and achieved high power conversion efficiency in all-polymer solar cells. This suggests that A(1)-A(2)-A(3) type terpolymer acceptors have potential for developing high-performance all-polymer solar cells.
Review
Polymer Science
Ahmad Adlie Shamsuri, Khalina Abdan, Siti Nurul Ain Md. Jamil
Summary: The enhanced awareness of environmental conservation has led researchers to search for alternatives to volatile organic compounds in polymer processing. Ionic liquids have emerged as non-volatile, recyclable, and non-flammable solvents for biodegradable polymers, as well as for the preparation of electrospun fibers. This concise review provides examples of natural and synthetic biodegradable polymers commonly used in electrospinning, and showcases the utilization of ionic liquids in the process. It also demonstrates the preparation of electrospinning solutions using ionic liquids, and presents a concise review of the properties of electrospun biodegradable polymer fibers assisted by different ionic liquids.
Article
Polymer Science
Nurul Nazihah Amerhaider Nuar, Siti Nurul Ain Md Jamil, Fan Li, Intan Diana Mat Azmi, Pen-Chi Chiang, Thomas Shean Yaw Choong
Summary: Coating nanoscale calcium peroxide with dextran improved the degradation efficiency and long-term efficacy of doxycycline in wastewater treatment.
Article
Engineering, Chemical
Fan Li, Thomas Shean Yaw Choong, Soroush Soltani, Luqman Chuah Abdullah, Siti Nurul Ain Md Jamil, Nurul Nazihah Amerhaider Nuar
Summary: This study investigated the performance of glyphosate removal from aqueous solutions using a Fenton-like system with calcium peroxide as an oxidant. Under optimal conditions, the maximum removal rates of total phosphorus and chemical oxygen demand were 94.50% and 68.60%, respectively. Experimental data were analyzed using various kinetics models, showing that calcium peroxide is an effective oxidant for glyphosate wastewater treatment.
Article
Engineering, Chemical
Zulina Abd Maurad, Luqman Chuah Abdullah, Mohd Shamsul Anuar, Nor Nadiah Abdul Karim Shah, Zainab Idris
Summary: The preparation and behavior of powder stearin-based methyl ester sulfonates (MES) with the addition of builder as a glidant agent was studied. The properties of powder MES were evaluated in terms of morphology, particle size, cohesion, caking, and compaction. The addition of zeolite or soda ash as a glidant improved the caking behavior of powdered MES.
Article
Polymer Science
Fan Li, Thomas Shean Yaw Choong, Luqman Chuah Abdullah, Siti Nurul Ain Md Jamil, Nurul Nazihah Amerhaider Nuar
Summary: Glyphosate and its metabolites are problematic contaminants in water, and an effective technology for their removal is urgently needed. In this study, calcium peroxide nanoparticles were used as an oxidant to remove glyphosate from water, achieving high removal rates.
Article
Polymer Science
Afiqah Ahmad, Siti Nurul Ain Md. Jamil, Thomas S. Y. Choong, Abdul Halim Abdullah, Nur Hana Faujan, Abel A. Adeyi, Rusli Daik, Nurhanisah Othman
Summary: Dye pollution from textile industrial effluents is harmful to ecosystems. In this study, a composite adsorbent was developed to efficiently adsorb methylene blue and malachite green. The adsorption followed pseudo-second order kinetics and Langmuir isotherm, suggesting monolayer adsorption. The maximum adsorption capacities were 31.7 mg/g for methylene blue and 34.3 mg/g for malachite green. Thermodynamic study revealed exothermic and spontaneous adsorption.
Article
Environmental Sciences
Xiaoju Li, Luqman Chuah Abdullah, Shafreeza Sobri, Mohamad Syazarudin Md Said, Siti Aslina Hussain, Tan Poh Aun, Jinzhao Hu
Summary: This study aims to investigate the long-term variation characteristics of pollutants and meteorological parameters in Chongqing. The results show a U-shaped variation for PM, SO2, and NO2, while O-3 shows an inverted U-shaped seasonal variation. Industrial emissions account for a significant proportion of pollution emissions. PM2.5 has a strong correlation with PM10. PM is negatively correlated with O-3 but positively correlated with other gaseous pollutants. O-3 is only correlated with relative humidity and atmospheric pressure.
WATER AIR AND SOIL POLLUTION
(2023)
Article
Polymer Science
Siti Hajar Ahmad Shariff, Rusli Daik, Muhammad Salahuddin Haris, Mohamad Wafiuddin Ismail
Summary: Blending an amphiphilic polymer with hydrogel increases drug loading and entrapment efficiency. This study produced a hydrogel formulation with star-shaped PCL-b-PEG as the hydrophobic drug cargo. The synthesized polymers showed high drug loading and sustained drug release, and exhibited antibacterial activity. The hydrogel containing 4-arm PCL15k-PEG was selected as the best formulation.
Article
Polymer Science
Nurul Nazihah Amerhaider Nuar, Siti Nurul Ain Md Jamil, Thomas Shean Yaw Choong, Intan Diana Mat Azmi, Nor Athirah Abdul Romli, Luqman Chuah Abdullah, Pen-Chi Chiang, Fan Li
Summary: One of the most significant environmental problems in the world is the release of dye wastewater from the dyeing industry. This study focuses on using starch as a stabilizer for synthesizing calcium peroxide nanoparticles (Starch@CPnps) to improve the degradation efficiency of organic dyes. The results show that the potential application of starch as a stabilizer can effectively reduce the particle size and enhance the degradation efficiency of the nanoparticles.
Article
Engineering, Environmental
Xiaoju Li, Luqman Chuah Abdullah, Shafreeza Sobri, Mohamad Syazarudin Md Said, Siti Aslina Hussain, Tan Poh Aun, Jinzhao Hu
Summary: This research investigated the levels and spatio-temporal evolution of criteria pollutants in Chongqing between 2014 and 2020. The results showed significant decreases in PM10, PM2.5, CO, and SO2 concentrations, while O3 concentrations fluctuated. PM and O3 concentrations were highest in winter and summer, respectively. The distribution of air pollution exhibited significant spatial heterogeneity. These findings are important for formulating air pollution control measures and achieving carbon neutrality goals in Chongqing.
JOURNAL OF THE AIR & WASTE MANAGEMENT ASSOCIATION
(2023)
Article
Polymer Science
Norsuhaili Kamairudin, Luqman Chuah Abdullah, Seng Soi Hoong, Dayang Radiah Awang Biak, Hidayah Ariffin
Summary: This study focuses on introducing modified palm oil derivatives-based polyol into the formulation of rigid polyurethane foams (RPUFs) as a renewable material. The modified palm oil derivative, alkanolamide polyol, was successfully prepared and analyzed for its physicochemical properties. RPUFs produced with alkanolamide polyol showed improved physical, mechanical and thermal properties, making them potential candidates for insulation materials in refrigerators or freezers.
Article
Chemistry, Analytical
Wan Khartini Wan Abdul Khodir, Mohamad Wafiuddin Ismail, Shafida Abd Hamid, Rusli Daik, Deny Susanti, Muhammad Taher, Vincenzo Guarino
Summary: Star-shaped copolymers can improve the interaction with drugs, resulting in significant benefits in drug administration and controlled release. In this study, two different star-shaped copolymers were synthesized and loaded with ciprofloxacin, with no significant differences observed in terms of drug entrapment efficiency and drug release. Both star-shaped copolymers also demonstrated good antibacterial properties and biocompatibility, making them promising for oral delivery applications.
Article
Chemistry, Analytical
Lila Alatawi, Abdul Halim Abdullah, Siti Nurul Ain Md. Jamil, Robiah Yunus
Summary: In this study, a simple and eco-friendly method for synthesizing polydimethylsiloxane (PDMS) foam was developed. By changing the reactant ratios and curing temperature, foams with varying properties were obtained. The synthesized PDMS foam showed excellent mechanical properties, good selectivity for organic solvents, and high absorption capacity.