Application of Nano FeIII-Tannic Acid Complexes in Modifying Aqueous Acrylic Latex for Controlled-Release Coated Urea

Acrylic latexes are valuable waterborne materials used in controlled-release fertilizers. Controlled-release urea coated with these latexes releases a large amount of nutrients, making it difficult to meet the requirement of plants. Herein, Fe-III-tannic acid (TA) complexes were blended with acrylic latex and subsequently reassembled on a surface of polyacrylate particles. These complexes remarkably retarded the release of urea (the preliminary solubility was decreased from 22.3 to 0.8%) via decreasing the coating tackiness (T-g was increased from 4.17 to 6.42 degrees C), increasing the coating strength (tensile stress was improved from 3.88 to 4.45 MPa), and promoting the formation of denser structures (surface tension was decreased from 37.37 to 35.94 mN/m). Overall, our findings showed that a simple blending of Fe-III-TA complexes with acrylic latex produces excellent coatings that delay the release of urea, which demonstrates great potential for use in controlled-release fertilizers coated with waterborne polymers.