Article
Chemistry, Physical
Anuja A. Yadav, Yuvaraj M. Hunge, Seok-Won Kang
Summary: In this study, a CeO2/MoS2 composite photocatalyst was successfully synthesized, exhibiting superior hydrogen production performance compared to individual CeO2 and MoS2. The composite showed higher photostability and faster charge transfer rate.
Article
Chemistry, Physical
Kejie Zhang, Zhen Mou, Shihai Cao, Tingting Meng, Jiacheng Li, Guangjie Ling, Xiang Zhang, Zhiping Zhou, Wei Meng
Summary: A novel nano-heterojunction photocatalyst of CdS/MoS2 was successfully obtained by a facile two-step hydrothermal synthesis method. The combination of MoS2 ultrathin layer and CdS nanosheets facilitated charge transfer and separation, leading to significantly enhanced photocatalytic performance.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Biotechnology & Applied Microbiology
Bi-yu Tan, Xiao-jie Song, Shi Xian-yang
Summary: The CdS/MoS2/rGO nanocomposites exhibited the highest H-2 evolution rate at 0.35 wt% CdS, with excellent stability in recycling experiments. The introduction of MoS2/rGO significantly improved the photocatalytic activity for H-2 evolution.
JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY
(2021)
Article
Chemistry, Physical
Zhen Mou, Jiali Xu, Tingting Meng, Xinping Wang, Runxin Gao, Junjie Guo, Siwen Gu, Zhiping Zhou, Wei Meng, Kejie Zhang
Summary: The ternary nanocomposites of CNTs/CdS/MoS2 were synthesized by a simple two-step hydrothermal method. The resulting composite material exhibited improved photocatalytic performance and stability, making it an economically feasible approach for the degradation of tetracycline.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Physical
Xiaolei Liu, Qingzhe Zhang, Yong Wang, Chen Wang, Guolong Song, Dongling Ma
Summary: In this study, a photocatalyst with multi-interfacial charge transfer was developed, achieving both broadband H2 production and high activity through optimizing the photoinduced interfacial charge transfer at the CdS/CuS interface and the synergistic effect of NiS cocatalyst for H2 production.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2023)
Article
Chemistry, Inorganic & Nuclear
Chrysanthi Patriarchea, Ioannis Vamvasakis, Eirini D. Koutsouroubi, Gerasimos S. Armatas
Summary: Modulating heterojunction interfaces at the nanoscale is crucial for developing efficient photocatalysts. The mesoporous heterojunction architectures made of MoS2 nanolayers and CdS nanocrystals showed high efficiency in solar energy to chemical fuel conversion, with a remarkable enhancement in photocatalytic hydrogen production activity. The optimized MoS2/CdS catalyst achieved a H2 production rate of up to 0.4 mmol h(-1) with 51.2% apparent quantum yield, demonstrating a 6.7x enhancement in H2 generation efficiency compared to unmodified CdS.
INORGANIC CHEMISTRY FRONTIERS
(2022)
Article
Chemistry, Physical
Caili Yang, Yanjia Cui, Yingshi Su, Yonghui Cheng, Defu Yao, Yuting Liao, Suyao Liu, Yiwen Fang, Yuqi Wu, Xiaoming Wang, Yibing Song, Gongxuan Lu, Zhen Li
Summary: In this study, Rh2O3 nanoparticles were implanted on the surface of reduced graphene oxide (RGO) by a hydrothermal reaction. Sensitized by Eosin Y, Rh2O3 was converted into metal Rh, forming a strong interaction interface between Rh NPs and RGO. The fabricated Rh/RGO catalyst showed high performance for photocatalytic H-2 evolution under visible light irradiation, with a H-2 evolution rate of 98.1 mmol center dot g(-1)center dot h(-1) and a maximum apparent quantum efficiency of 79.3% at 520 nm. The enhanced performance was attributed to the excellent electron conduction ability of RGO and the strong interaction between Rh NPs and RGO, which accelerated electron transfer and prolonged charge lifetime. The strong interaction also ensured the strong anchoring and excellent stability of the Rh/RGO catalyst.
ACS APPLIED ENERGY MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Haifeng Lin, Xiaowei Ma, Hui Wang, Bo Wang, Shao-Xiang Li, Xiujie Yi, Yan-Yan Li, Lei Wang
Summary: This research has successfully developed nanoassemblies constructed by Zn, Ni-doped CdS nanocrystals and oxygen-incorporated MoS2 nanosheets, which exhibit superior performance in visible-light photocatalytic hydrogen evolution reaction.
CRYSTAL GROWTH & DESIGN
(2021)
Article
Chemistry, Physical
Shuying Dong, Yinlan Zhao, Jingyi Yang, Xiaodan Liu, Wen Li, Luyuan Zhang, Yuhan Wu, Jianhui Sun, Jinglan Feng, Yongfa Zhu
Summary: The study achieved a visible-light responsive PDI/rGO composite film with excellent photocatalytic performance and efficient interfacial steam generation, and exhibited good removal capabilities of ciprofloxacin hydrochloride in real water samples.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2021)
Article
Materials Science, Ceramics
Gang Su, Lihua Liu, Xing Liu, Lixing Zhang, Jianrong Xue, Anping Tang
Summary: A novel magnetic Fe3O4@SiO2@BiFeO3/rGO composite was successfully synthesized via a hydrothermal method, showing excellent performance in photocatalytic degradation of organic pollutants under visible light, as well as remarkable recyclability and stability.
CERAMICS INTERNATIONAL
(2021)
Article
Engineering, Chemical
Haitao Fu, Hongming Zhao, Xiaohong Yang, Shixian Xiong, Xizhong An
Summary: This study demonstrates high-performance visible-light-driven H-2-evolution photocatalysts based on novel CdS nanodiamonds decorated with MoS(2) nanosheets. The composites exhibited enhanced photocatalytic performances due to improved optical absorption range, low recombination rate of the photo-generated electrons and holes, extra generated charges, excellent charge transfer ability, and increased donor density.
Article
Environmental Sciences
Muhammad Munir Sajid, Sadaf Bashir Khan, Yasir Javed, Nasir Amin, Zhengjun Zhang, Naveed Akhtar Shad, Haifa Zhai
Summary: A BiVO4/Ti3C2 nanocomposite was synthesized via a low-cost hydrothermal method, showing enhanced photocatalytic degradation activity with the addition of MXene. The heterojunction composite demonstrated high degradation efficiency for various dyes due to its large specific surface area, reduced band gap, and low recombination rate of charge carriers. The chemical mechanism proposed Ti3C2 playing a role in electron capture, paving the way for excellent photocatalytic action and potential development of cost-effective co-catalysts in solar utilization.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2021)
Article
Chemistry, Physical
Xing-Liang Yin, Lei-Lei Li, Yao Lu, Jian-Min Dou, Da-Cheng Li
Summary: In this study, a novel 2D MoS2/CdS nanoheterostructure was developed by employing strategies of morphology, band gap, and active site engineering to overcome the drawback of charge recombination in photocatalytic H-2 generation. The results showed that the intimate contact interface formation between MoS2 and CdS, as well as the efficient charge separation, contribute to the high performance of MoS2/CdS with an optimized H2 evolution rate of 28.2 mmol g-1 h-1, which is over 9 times higher than that of pristine CdS. This research has important implications for the construction of high-quality heterostructure catalysts.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Materials Science, Paper & Wood
Lei Jiang, Mengying Xu, Shan Jiang, Pier-Luc Tremblay, Tian Zhang
Summary: The ternary photocatalyst of CdS/BC-MoS2, synthesized through a low-toxicity process, showed increased surface area and improved photoinduced charge separation. The composite photocatalyst exhibited strong interactions between CdS, MoS2, and BC, resulting in enhanced absorption of visible light and significantly faster PHE rate. Moreover, the CdS/10%BC-MoS2 photocatalyst demonstrated excellent quantum efficiency and high stability under visible light, making it a promising material for sustainable improvement of CdS-based heterostructure photocatalysts.
Article
Chemistry, Physical
Chunyu Yuan, Huijun Lv, Yujin Zhang, Qian Fei, Dongdong Xiao, Hongfei Yin, Zhen Lu, Yongzheng Zhang
Summary: Properly engineered heterojunction photocatalysts can effectively separate photoexcited electron-hole pairs and improve the photocatalytic hydrogen evolution performance. In this study, 3D bicontinuous nanoporous reduced graphene oxide (np-rGO) was used as a supporting matrix for CdS nanoparticles to achieve a highly efficient photocatalysis system for hydrogen production. The bicontinuous internal ligament and open nanopores in the 3D nanoporous heterojunction contribute to improved light absorption and utilization capacity. The construction of a p-n heterojunction with staggered band alignment in CdS/np-rGO accelerates the transport of photo-excited carriers, leading to a significant increase in hydrogen generation rate.
Article
Chemistry, Physical
Chayma Abed, Amira Ben Gouider Trabelsi, Fatemah H. Alkallas, Susana Fernandez, Habib Elhouichet
Summary: Magnesium-doped zinc oxide nanocrystals were fabricated through a sol gel method. The impact of magnesium concentration on the structure, electrical, and dielectric characteristics of the nanocrystals was investigated. The results showed that the magnesium content affected the conductivity, impedance spectra, dielectric constant, and Debye-like relaxation behavior. The nanocrystals with 3% magnesium doping exhibited a large dielectric constant. These findings highlight the importance of magnesium-doped zinc oxide nanocrystals for device applications and energy storage.
Article
Chemistry, Physical
Tariq Altalhi, Amine Mezni, Mohamed M. Ibrahim, Moamen S. Refat, Adil A. Gobouri, Ayham M. Safklou, Adel M. Mousli, Mohamed S. Attia, Purna K. Boruah, Manash R. Das, Jacek Ryl, Rabah Boukherroub, Mohammed A. Amin
Summary: In this study, FA-TiO2 nanocomposites were prepared using fly ash waste and titanium oxide. The nanocomposites exhibited considerable electrocatalytic activity for the hydrogen evolution reaction (HER), and their performance was significantly enhanced through cathodic activation. The activated FA-TiO2 showed comparable performance to commercial Pt/C catalysts for HER.
Article
Crystallography
Amira Ben Gouider Trabelsi, Fatemah. H. Alkallas, Aicha Ziouche, Abdelwaheb Boukhachem, Mostefa Ghamnia, Habib Elhouichet
Summary: NiO thin films were successfully prepared and characterized. The structural investigation revealed a cubic structure with (111) preferential orientation. The NiO layers showed uniform grain size and randomly distributed aggregates. The optical properties exhibited normal dispersion and good transparency. Unexpected ferromagnetic behavior was observed due to high oxygen content, along with high thermal dependency of conductivity and semiconductor behavior.
Article
Biochemistry & Molecular Biology
Guillaume P. Grolez, Giorgia Chinigo, Alexandre Barras, Mehdi Hammadi, Lucile Noyer, Kateryna Kondratska, Etmar Bulk, Thibauld Oullier, Severine Marionneau-Lambot, Marilyne Le Mee, Stephanie Retif, Stephanie Lerondel, Antonino Bongiovanni, Tullio Genova, Sebastien Roger, Rabah Boukherroub, Albrecht Schwab, Alessandra Fiorio Pla, Dimitra Gkika
Summary: TRPM8 plays a protective role in the progression of prostate cancer and may be a potential therapeutic target. The study demonstrated that TRPM8 overexpression can significantly inhibit tumor growth and metastasis in prostate cancer using a mouse model and in vitro experiments.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2022)
Article
Energy & Fuels
Ramzi Nasser, Xiao-Lu Wang, Jian Tiantian, Habib Elhouichet, Ji-Ming Song
Summary: In this study, a novel CoMoO4@CoWO4 nanorod core-shell heterostructure was designed to enhance the practicality of CoMoO4 as an electrode material. The core-shell structure exhibited high specific capacitance and excellent stability due to the synergistic effect. Furthermore, the supercapacitor device demonstrated high specific energy and power, and was able to illuminate LEDs.
JOURNAL OF ENERGY STORAGE
(2022)
Article
Energy & Fuels
Ramzi Nasser, Xiao-Lu Wang, Amira Ben Gouider Trabelsi, Fatemah Homoud Alkallas, Habib Elhouichet, Ji-Ming Song
Summary: Hydrothermal and ultrasonic methods were used to successfully prepare Fe-doped NiCo2O4@rGO hybrid heterostructure material, which showed excellent electrochemical properties and is suitable for supercapacitor electrode materials.
JOURNAL OF ENERGY STORAGE
(2022)
Article
Infectious Diseases
Noura Hazime, Yanath Belguesmia, Alexandre Barras, Mohamed Amiche, Rabah Boukherroub, Djamel Drider
Summary: Dermaseptin B2 (DRS-B2) is an antimicrobial peptide secreted by the Amazonian tree frog, Phyllomedusa bicolor. This study demonstrates that adsorption of DRS-B2 onto alginate nanoparticles enhances its antibacterial activity, particularly against colistin-resistant strains of Escherichia coli. The addition of lactic acid or menthol further enhances the antibacterial activity of this new formulation. Safety and stability tests conducted on human erythrocytes and eukaryotic cell lines indicate the potential of these formulations as alternatives to antibiotics for treating Gram-negative bacterial infections such as E. coli.
Review
Chemistry, Analytical
Sabine Szunerits, Hiba Saada, Quentin Pagneux, Rabah Boukherroub
Summary: The ongoing pandemic of COVID-19 highlights the importance of diagnostic testing in outbreak control. Current diagnosis methods largely rely on RT-PCR, but there have been proposals to use SPR-based sensing platforms to detect the presence of SARS-CoV-2 viral particles. This review provides an overview of the state-of-the-art SPR-based sensing devices and discusses the applicability of plasmonic sensors as point-of-care testing for virus particles and viral protein sensing.
Article
Chemistry, Physical
Imen Mechrgui, Amira Ben Gouider Trabelsi, Fatemah. H. Alkallas, Saber Nasri, Habib Elhouichet
Summary: The melt-quenching technique was used to synthesize tellurite glasses doped with vanadium. The addition of V2O5 changed the glass structure, as evidenced by Raman and FTIR measurements. The AC conductivity showed coherence and the dielectric constant exhibited high values in the lower and medium frequency range. The electric modulus and dielectric loss parameters were mainly related to the vanadate phases.
Article
Biology
Nicolas Bondon, Denis Durand, Kamel Hadj-Kaddour, Lamiaa M. A. Ali, Rabah Boukherroub, Nadir Bettache, Magali Gary-Bobo, Laurence Raehm, Jean-Olivier Durand, Christophe Nguyen, Clarence Charnay
Summary: In this study, multifunctional nanodiamond-organosilica core-shell nanoparticles were successfully prepared and demonstrated high biocompatibility and efficiency in two-photon-excited photodynamic therapy (TPE-PDT) in vitro in a breast cancer cell model. These nanoparticles hold great potential for TPE-PDT applications.
Review
Biochemistry & Molecular Biology
Tomasz Swebocki, Alexandre Barras, Amar Abderrahmani, Kamel Haddadi, Rabah Boukherroub
Summary: In recent years, there has been a significant increase in the number of studies focusing on the synthesis and characterization of deep eutectic solvents (DESs). DESs, known for their stability, ease of synthesis, and ability to tailor properties, are considered one of the greenest solvent families used in various fields such as organic synthesis, catalysis, electrochemistry, and medicine. However, there is a lack of research on specific groups of DESs, particularly those comprising organic acids (OA-DESs), despite their potential in biomedical applications. This review aims to highlight the importance and applications of OA-DESs as antimicrobial agents and drug delivery enhancers, providing valuable insights for future developments in this field.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2023)
Review
Pharmacology & Pharmacy
Shakila Behzadifar, Alexandre Barras, Valerie Plaisance, Valerie Pawlowski, Sabine Szunerits, Amar Abderrahmani, Rabah Boukherroub
Summary: Diabetes poses major economic, social, and public health challenges worldwide and is a leading cause of foot ulcers and amputations. Lack of clinical imaging tools, insulin monitoring, and patients' adherence to treatment contribute to the diabetes epidemic. Advances in polymeric materials show potential for beta-cell imaging and non-invasive drug delivery in managing blood glucose and foot ulcers.
Article
Materials Science, Ceramics
Moufida Saad, Marwa Ennouri, M. I. Sayyed, Amira Ben Gouider Trabelsi, Fatemah Homoud Alkallas, Habib Elhouichet
Summary: This work investigates the properties of Ag-containing lead-boro-phosphate glasses in terms of structure, optics, refractive index dispersion, and shielding. It is found that Ag NPs precipitation occurs, as evidenced by XRD patterns and TEM images. The formation of Ag NPs leads to a depolymerization process and an increase in glass density, as well as a reduction in optical band gap energy. The optical performance of the glass is improved due to the formation of Ag NPs, making it suitable for various multi-functional optical devices.
CERAMICS INTERNATIONAL
(2023)
Article
Energy & Fuels
Ramzi Nasser, Hao Zhou, Amira Ben Gouider Trabelsi, Fatemah Homoud AlKallas, Habib Elhouichet, Ji-Ming Song
Summary: Designing hybrid composites electrodes with hierarchical nano-structural features and superb electrochemical performances is important for advanced supercapacitors. A novel nanocomposite was successfully prepared by anchoring CoWO4 nanodots on olive derived activated carbon doped with N and S (OACNS). The composite showed excellent capacitance value and cycle life, indicating its potential as a cathode for next generation energy storage devices.
JOURNAL OF ENERGY STORAGE
(2023)
Article
Materials Science, Multidisciplinary
Monaam Ben Ali, Amira Ben Gouider Trabelsi, Fatemah H. Alkallas, Habib Elhouichet
Summary: Designing fast, eco-friendly, and effective adsorbents to remove heavy metal ions from complex environments is crucial. In this study, MoS4 doped poly-N-phenylglycine (MoS4-PPG) composites were synthesized through radical polymerization. The composites showed high homogeneity and exhibited significant adsorption of Pb2+ ions in aqueous solution.
MATERIALS TODAY COMMUNICATIONS
(2023)
