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Stress/strain effects on thermodynamic properties of magnesium hydride: A brief review

Journal

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 42, Issue 26, Pages 16603-16610

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2017.05.174

Keywords

Magnesium hydride; Hydrogen storage; Stress/strain effects; Thermodynamics

Funding

  1. National Natural Science Foundation of China [51401036]
  2. Hunan Provincial Natural Science Foundation of China [17JJ2263]
  3. Science Research Project of Hunan Province Office of Education [16K001]

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Magnesium hydride MgH2 is an attractive hydrogen storage candidate due to its high reversible hydrogen mass capacity of 7.6 wt%, abundant resources of Mg and low cost. Unfortunately, its stubborn thermodynamic stability results in a high temperature of 573 K for hydrogen desorption, which is still far from the target for practical applications. In this article, we highlight the recent advances in stress/strain effects on the de/rehydrogenation thermodynamics of MgH2, which sheds a new light on tuning the thermodynamic properties of magnesium and other metal hydrides for hydrogen storage. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

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