4.4 Article

Synthesis of MnCo2O4.5/graphene Composite as Electrode Material for Supercapacitors

Journal

INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
Volume 12, Issue 11, Pages 10763-10772

Publisher

ESG
DOI: 10.20964/2017.11.63

Keywords

Supercapacitors; MnCo2O4.5; Graphene; Hydrothermal method

Funding

  1. Scientific Research Fund of Hunan Provincial Education Department [14B022]
  2. Science and Technology Plan Fund of Changsha [k1509008-11]
  3. Aid Program for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province

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MnCo2O4.5/graphene composite is obtained by a simple hydrothermal method. The as-synthesized MnCo2O4.5/graphene composite is characterized by X-ray diffraction, and scanning electron microscopy. Electrochemical property of MnCo2O4.5/graphene composite is carried out by cyclic voltammetry, galvanostatic charge-discharge and electrochemical impedance spectroscopy. MnCo2O4.5/graphene composite exhibits good supercapacitive performance. The specific capacitances of MnCo2O4.5/graphene composite at 5 mV s(-1) and at 0.5 A g(-1) are 255.8 and 252.3 F g(-1), respectively. 88.7% of the specific capacitance is retained for a 16-time current density increase, indicating its superior rate capability. At the 1000th cycle, MnCo2O4.5/graphene composite shows a specific capacitance of 225.6 F g(-1) at 1.0 A g(-1), which is 92.6% of initial specific capacitance, demonstrating its excellent cycling stability. These characteristics illustrate that MnCo2O4.5/graphene composite is a promising electrode material in supercapacitors.

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