Article
Chemistry, Physical
Yeon Soo Lee, Da Wan Kim, Jin Ho Song, Jinhyung Kim, Seung Hwan Jeon, Gui Won Hwang, Changhyun Pang
Summary: Bioinspired and biodegradable polymer-based adhesive films have gained attention in the medical field due to their stable adhesion performance and ability to decompose in the body. This study presents a bioinspired oil-coated adhesive film fabricated using PGS, which mimics the adhesion properties of a frog's toe pad and mucus on wet surfaces.
SURFACES AND INTERFACES
(2022)
Article
Biochemistry & Molecular Biology
Guozhi Fan, Qiao Peng, Yi Chen, Yifei Long, Juan Bai, Guangsen Song, Qunpeng Cheng
Summary: This study focuses on the preparation of a biodegradable composite film from wheat straw by transforming holocellulose into carboxymethylated holocellulose (CMHCS) through catalytic reaction. By optimizing the carboxymethylation of holocellulose, a high degree of substitution (DS) was achieved. The mechanical properties of the CMHCS-derived composite film were significantly improved compared to the unmodified holocellulose-based film, and the biodegradability of the composite film was assessed and showed good performance.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2023)
Article
Agricultural Engineering
Shafaet Ahmed, Srinivas Janaswamy
Summary: This study extracted lignocellulosic fiber from avocado peel and used it to create biodegradable films as a replacement for plastics.
INDUSTRIAL CROPS AND PRODUCTS
(2023)
Article
Nanoscience & Nanotechnology
Yongsen Zhou, Chao Zhang, Shouwei Gao, Wanbo Li, Ji-jung Kai, Zuankai Wang
Summary: A chemically functionalized PSA (f-PSA) with enhanced and phototunable underwater adhesion has been developed by incorporating an underwater adhesion enhancer (mussel-inspired catechol) and a photo-responsive functionality (anthracene) into a standard acrylic PSA matrix. This synergistic coupling secures sufficient interfacial molecular interactions and leads to enhanced underwater adhesion, while the efficient dimerization of anthracene via light-triggered cycloaddition facilitates the viscoelastic property of f-PSA, rendering it phototunable. The f-PSA is envisioned to open up more opportunities for applications such as underwater manipulation, transfer printing, and medical adhesives.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Engineering, Biomedical
Soichiro Fujiwara, Yuta Yoshizaki, Akinori Kuzuya, Yuichi Ohya
Summary: Injectable polymers (IPs) with in situ hydrogel formation are important for vascular embolization and postoperative adhesion prevention. Tissue adhesion properties are crucial, and the introduction of aldehyde groups can enhance these properties. The in vitro embolization properties of IPs can be improved by mixing with aldehyde-modified Pluronic, and the IP system shows good performance for postoperative adhesion prevention.
ACTA BIOMATERIALIA
(2021)
Article
Materials Science, Characterization & Testing
Hyun-Joong Kim, Zbigniew Czech, Marcin Bartkowiak, Gyu-Seong Shim, Janina Kabatc, Adam Licbarski
Summary: Studied properties of novel acrylic PSAs for carrier-free films or adhesive tapes, and achieved the UV crosslinking of solvent-free acrylic pressure-sensitive adhesive layers.
Article
Polymer Science
Rusta Bidari, Annur Ahadi Abdillah, Rogelio Alfredo Bonilla Ponce, Albert Linton Charles
Summary: Studies on renewable polymers have shown that starch can be used as a replacement for petroleum-based components to produce biodegradable films with plastic-like qualities. This study introduces the use of taro peel starch (TPS) for the first time in producing such films using the casting technique. The effects of different concentrations of TPS and glycerol on the properties of the TPS films were investigated, and their optimized values were determined using the response surface method. The TPS films exhibited desirable physico-mechanical and water barrier properties, making them a promising option for food packaging.
Article
Polymer Science
Dongdong Wang, Jiapeng Li, Fushi Li, Jianing Zhang, Yunbao Gao, Jing Jin, Wei Jiang, Haojun Liang
Summary: The challenge lies in developing solvent-free and biodegradable pressure-sensitive adhesives (PSAs). By introducing polar groups onto poly(propylene carbonate)s (PPC) and combining it with degradation, a series of biodegradable and solvent-free chlorosulfonated poly(propylene carbonate)s (CSPPCs) with different molecular weights have been obtained. The balance between molecular weight and polar group content is crucial for adhesive properties.
Article
Biochemistry & Molecular Biology
Paula Ossowicz-Rupniewska, Paulina Bednarczyk, Malgorzata Nowak, Anna Nowak, Wiktoria Duchnik, Lukasz Kucharski, Joanna Rokicka, Adam Klimowicz, Zbigniew Czech
Summary: This study demonstrated the feasibility of developing photoreactive acrylic-based transdermal patches containing ibuprofen. The patches, with biocomponents capable of delivering a therapeutically relevant dose of ibuprofen, exhibited improved adhesive properties and permeability compared to commercial adhesives. The study highlights the potential of using renewable alternatives and environmentally friendly synthesis routes for transdermal drug delivery systems.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2021)
Article
Chemistry, Applied
Garima Agrawal, Ankita Dhiman, Dimpy Bhardwaj, Kajal Goswami
Summary: In this study, redox-sensitive DH-ChSt MGs were developed for controlled release of insecticide and capturing heavy metal ions. The DH-ChSt MGs exhibited high loading and encapsulation efficiency for imi-dacloprid insecticide, and prolonged release under reducing conditions. DH-ChSt MGs also showed enhanced foliar adhesion and efficient binding of Fe3+. MTT assay confirmed the non-toxicity of DH-ChSt MGs, and their capability to bind heavy metal ions makes them a promising platform for agriculture application.
CARBOHYDRATE POLYMERS
(2023)
Article
Chemistry, Physical
Lulu Xu, Jian Liu, Xiu Yun Daphne Ma, Zibiao Li, Chaobin He, Xuehong Lu
Summary: A new biomimetic macromolecule C-L-D was designed and synthesized as a versatile biodegradable adhesion promoter to facilitate the deposition of biodegradable fragrance carriers on diverse surfaces. The C-L-D modified nanoparticles showed significantly higher deposition efficiencies on target surfaces, indicating its potential application in various personal care and other fields.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2022)
Article
Engineering, Mechanical
Wei Sun, Qingrui Song, Kun Liu, Xiaojun Liu, Jiaxin Ye
Summary: The addition of nano-sized fillers can greatly reduce the wear rate of polytetrafluoroethylene by forming a protective transfer film. The wear reduction is influenced by the properties of the polymer wear surface and the roughness of the transfer film.
Article
Biochemistry & Molecular Biology
Hafiz Muhammad Saleem Akhtar, Shakeel Ahmed, Ewa Olewnik-Kruszkowska, Magdalena Gierszewska, Maria Swiontek Brzezinska, Katarzyna Dembinska, Agnieszka Kalwasinska
Summary: This study examined the properties of a new active packaging film developed by adding mulberry leaves polysaccharides (MLP) into carboxymethyl cellulose (CMC). The addition of MLP increased the thickness and roughness of the films, while decreasing the moisture content, water vapor permeability, and swelling degree. Increasing the concentration of MLP improved the mechanical properties of the films and enhanced UV light dispersion. The films exhibited good inter-molecular interaction between CMC matrix and MLP, as demonstrated by Fourier transform-infrared spectroscopy and X-ray diffraction. The prepared films showed excellent thermal stability, antioxidant and antibacterial properties, and biodegradability in the soil environment. Additionally, the films showed the ability to retard oil oxidation.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2023)
Article
Polymer Science
Seonghyun Kim, Seung Hui Lee, Subi Choi, Suk-kyun Ahn, Gi-Deog Jang, Jong S. Park, Dong Gi Seong
Summary: The PSA-silica nanocomposite thin-films with optimized process showed a 180% increase in tensile strength without significant loss in peel strength, thanks to reinforcement with polydopamine-embedded silica nanoparticles. Lap shear and probe tack tests successfully verified the reinforcing mechanism overcoming the trade-off relationship.
Article
Nanoscience & Nanotechnology
Jialing Li, Sha Luo, Fenfang Li, Shengyi Dong
Summary: This article introduces a new type of pressure-sensitive adhesive that can be directly operated at low temperatures and exhibits excellent mechanical properties and adhesion capacity. The results of the study show that the adhesive has strong adhesion strength at -60 degrees Celsius and can stably adhere to various surfaces.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Physical
Karolina Mozelewska, Zbigniew Czech, Marcin Bartkowiak, Malgorzata Nowak, Paulina Bednarczyk, Piotr Niezgoda, Janina Kabatc, Agnieszka Skotnicka
Summary: This study synthesized acrylate copolymers and tested the effects of monomer type, UV radiation dose, and basis weight on the self-adhesive properties of the tapes obtained.
Article
Biochemistry & Molecular Biology
Paula Ossowicz-Rupniewska, Paulina Bednarczyk, Malgorzata Nowak, Anna Nowak, Wiktoria Duchnik, Lukasz Kucharski, Joanna Klebeko, Ewelina Swiatek, Karolina Bilska, Joanna Rokicka, Ewa Janus, Adam Klimowicz, Zbigniew Czech
Summary: This study evaluated the effect of chemical modifications of the structure of active compounds on the skin permeation and accumulation of ibuprofen from a drug-in-adhesives matrix type transdermal patch. The results showed that the modified patches had increased drug permeability compared to unmodified ibuprofen.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2022)
Article
Chemistry, Physical
Adrian Krzysztof Antosik, Karolina Mozelewska
Summary: This study focused on the research of self-adhesive tapes based on silicone pressure-sensitive adhesives, and conducted various tests on the prepared tapes. The results showed that the new self-adhesive materials maintained their adhesive properties while increasing the thermal resistance, indicating their potential applications in electrical engineering and heavy industry.
Article
Chemistry, Physical
Adrian Krzysztof Antosik, Karolina Mozelewska, Magdalena Zdanowicz, Konrad Gziut, Piotr Miadlicki
Summary: In this study, organophilized montmorillonites (OMMT) with different quaternary ammonium compounds (QAC) were used as fillers in modified silicone pressure-sensitive adhesives (Si-PSA). The chemical structure of QAC affected the d-spacing of OMMT, as analyzed by TGA and XRD techniques. The new self-adhesive materials based on the prepared Si-PSA compositions with OMMT showed improved thermal resistance up to 225 degrees C.
Article
Polymer Science
Adrian Krzysztof Antosik, Marlena Musik, Piotr Miadlicki, Mateusz Weisbrodt, Katarzyna Wilpiszewska
Summary: This study presents the preparation of a new eternally alive adhesive using silicone pressure-sensitive adhesives with clinoptilolite. Neat and acid-modified clinoptilolite were used, and the effect of acid treatment on the adhesive properties of pressure-sensitive adhesive tapes was tested. The results demonstrated that the obtained tapes showed increased thermal resistance while maintaining good functional properties, suggesting promising implementation potential for self-adhesive materials where increased thermal resistance is required.
Article
Biochemistry & Molecular Biology
Magdalena Zdanowicz, Marta Rokosa, Magdalena Pieczykolan, Adrian Krzysztof Antosik, Justyna Chudecka, Malgorzata Mikiciuk
Summary: The aim of this study was to plasticize corn starch using two selected urea-rich plasticizers: choline chloride (CC):U or betaine (B):U eutectic mixtures, with the addition of spent coffee grounds as a filler. The materials were characterized using various tests and a study on biodegradation and remaining nitrogen content in soil was conducted. The results showed that the materials had improved mechanical properties when the coffee filler was added and had a good processability. The materials disappeared in soil within approximately 70 days and did not exhibit any toxic effects on plants.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2023)
Article
Chemistry, Physical
Adrian Krzysztof Antosik, Edyta Kucharska, Karolina Mozelewska
Summary: This study focuses on the characteristics of a modified silicone adhesive with filler to ensure its high resistance to harsh environmental conditions. The functionalized palygorskite (palygorskite-MPTMS) was prepared by grafting 3-mercaptopropyltrimethoxysilane onto palygorskite under dried conditions. The results showed that the initial calcination of palygorskite promotes the grafting of functional groups on its surface, leading to improved thermal resistance in self-adhesive materials.
Article
Chemistry, Physical
Adrian Krzysztof Antosik, Karolina Mozelewska, Marlena Musik, Piotr Miadlicki, Katarzyna Wilpiszewska
Summary: The synthesis of a new silicone self-adhesive with modified illite has been studied. The illite filler was modified with N,N,4-trimethylaniline. The impact of illite content and modification on the functional properties of the adhesive was analyzed, including adhesion, cohesion, stickiness, and shrinkage. The obtained silicone pressure-sensitive adhesives showed increased thermal resistance and reduced shrinkage, making them suitable for high-temperature applications such as heavy industry.
Review
Polymer Science
Alicja Balcerak, Janina Kabatc-Borcz, Zbigniew Czech, Marcin Bartkowiak
Summary: Light-activated polymerization is an important strategy for fabricating advanced polymer materials. Dye-based photoinitiating systems have revolutionized the market of innovative photoinitiators. This paper provides important information about photoinitiated radical polymerization and its applications in various fields.
Article
Polymer Science
Adebukola Abiola Agboola, Anna Nowak, Wiktoria Duchnik, Lukasz Kucharski, Anna Story, Grzegorz Story, Lukasz Struk, Adrian Krzysztof Antosik, Paula Ossowicz-Rupniewska
Summary: The effect of vehicle and chemical modifications on the skin permeation and accumulation of ibuprofen were evaluated in this study. Semi-solid formulations of emulsion-based gel were developed, which enhanced the permeation of ibuprofen and its derivatives compared to commercial products. The study also demonstrated the potential of transdermal emulsion-based gel as a faster drug delivery system when combined with drug modification.
Article
Chemistry, Physical
Katarzyna Wilpiszewska, Dorota Skowronska
Summary: The efficiency of potato starch plasticization using two deep eutectic solvents (DESs) based on choline chloride (CC) and glycerol (G) or urea (U) has been evaluated. Both DESs exhibited solubility towards starch, but CCU showed significantly higher solvent power than CCG. The XRD result indicated that both DESs were able to penetrate the starch crystal regions and form stable hydrogen bonds with the hydroxylic groups of the polysaccharide. The viscosity and thermal stability of the starch material depended on the DES content, with a decrease in viscosity and thermal stability observed with increasing DES content. The gelatinization temperature was strongly affected by the type of DES, occurring at a lower temperature in CCU compared to CCG. The plasticization efficiency was tested using modulated DSC, and it was found that CCG had higher plasticizing efficiency compared to CCU.
JOURNAL OF MOLECULAR LIQUIDS
(2023)
Article
Polymer Science
Adrian Krzysztof Antosik, Karolina Mozelewska, Konrad Gziut
Summary: The paper presents the results of research on the UV radiation influence on the self-adhesive properties of silicone adhesives. The adhesives were obtained by cross-linking commercial resins (PSA 590, Q2-7566) at the temperature of 110 degrees C, using different amounts (0-3 wt%) of bis(2,4-dichlorobenzoyl) peroxide. Self-adhesive properties of adhesives such as adhesion, tack, and durability before and after aging were determined. The adhesives showed stable self-adhesive properties, however, the PSA 590 adhesive had a higher maximum operating temperature than the Q2-7566 adhesive.
Article
Multidisciplinary Sciences
Adrian Krzysztof Antosik, Karolina Mozelewska, Marlena Musik, Piotr Miadlicki
Summary: This study examined the impact of diatomite and its modifications on the self-adhesive ability of silicone pressure-sensitive adhesives. The modified tapes showed higher thermal resistance and lower shrinkage compared to the unmodified tapes.
SCIENTIFIC REPORTS
(2023)
Article
Engineering, Chemical
Fengze Dai, Yinjie Dai, Shu Huang, Xijun Hua
Summary: In this study, laser surface texturing (LST) was performed on the surface of 6061 aluminum alloy using a pulsed laser, and then SHF-2D zinc epoxy coating (SP) was applied. The results show that LST can effectively increase the adhesion strength, and the pattern of the spatter produced by laser irradiation determines the adhesion strength.
INTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES
(2024)
Article
Engineering, Chemical
Leonardo Lamberti Miotti, Andressa Cargnelutti Follak, Luciano de Souza Goncalves, Eliseu Aldrighi Munchow, Alexandre Henrique Susin
Summary: The purpose of this in vitro study was to evaluate the immediate and long-term bond strength of self-adhesive and conventional resin luting agents with a new restorative material to dentin. The results showed that the conventional dual resin cement had better bond strength to dentin when using the etch-and-rinse strategy.
INTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES
(2024)
Article
Engineering, Chemical
Ivan Argatov, Xiaoqing Jin, Gennady Mishuris
Summary: This study presents a fitting-based analysis of experimental force/displacement curves to propose an explanation method for adhesive contact based on Griffith's energy balance model, which is applicable for finite deformations between a polymer brush grafted onto a rigid substrate and an AFM probe.
INTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES
(2024)
Article
Engineering, Chemical
Mitsuhiro Gonda, Toru Utsunomiya, Takashi Ichii, Hiroyuki Sugimura
Summary: The technique of surface photoactivation using VUV light has been used for adhesive-free bonding of POM plates. The POM surfaces were modified through VUV light irradiation, resulting in the formation of oxygen-containing functionalities. The bonds formed through thermocompression and the mechanical properties of the bonding interface were different from the bulk POM.
INTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES
(2024)
Review
Engineering, Chemical
Renally Bezerra Wanderley Lima, Juan Vitor Costa Leite, Joao Vitor do Nascimento Santos, Laryssa Mylenna Madruga Barbosa, Hermano Nobrega Macedo Neto, Joao Gabriel Regis da Silva, Isis de Araujo Ferreira Muniz, Debora e Silva Campos, Grace Mendonca De Souza
Summary: This systematic review compared the bond strength between zirconia and resin cements when different surface treatments were used. The findings indicated that tribochemical silica-coating/silane-based treatments are more effective than alumina blasting/zirconia primers in enhancing the bond strength to zirconia.
INTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES
(2024)
Review
Engineering, Chemical
Luisa Valente Gotardo Lara Alves, Nathalia Mancioppi Cerqueira, Amanda Pelegrin Candemil, Andre Luis Faria-e-Silva, Manoel Damiao Sousa-Neto, Aline Evangelista Souza-Gabriel
Summary: This systematic review and meta-analysis evaluated the effect of chitosan on resin-dentin bond strength. The results showed that chitosan can improve the immediate bond strength of self-etching adhesives and the long-term bond strength of etch-and-rinse adhesives.
INTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES
(2024)
Retraction
Engineering, Chemical
M. Soliman, S. Saadaldin, A. Aldegheishem, A. Abdull, S. Al-Shma, E. Eldwakhly
INTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES
(2024)
Article
Engineering, Chemical
Sabrina Mahnel, Franz Bannert, Johannes Zimmermann, Sergio Grunder, Martin Demmig, Silvia Lomolino, Guido Grundmeier
Summary: These studies present a new method for analyzing the maximum open time of cold curing adhesives, and investigate the curing reaction and bonding behavior of two cold curing polyurethane adhesives. The results show that the main problem for industrial applications is dimensional accuracy, and the manual spatula test is a suitable method for production environment with good reproducibility.
INTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES
(2024)
Article
Engineering, Chemical
J. Vanerek, R. Balkova, M. Smak, A. Betak, Z. Vejpustek
Summary: The paper focuses on the behavior of glued joints of wooden sections at elevated temperatures. The study found that the curing of PRF and PUR adhesives was insufficient at high temperatures. At 140℃, there was no significant reduction in strength for all tested adhesives, but a longer duration (1 day) led to a decrease in tensile shear strength. At 170℃, PRF and EPI showed a significant drop in strength, while PUR lost its strength completely after longer duration exposures.
INTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES
(2024)
Article
Engineering, Chemical
Ryota Aoki, Toshiki Takamizawa, Yuta Kasahara, Munenori Yokoyama, Shunichi Suda, Rei Muto, Atsushi Kamimoto, Masashi Miyazaki
INTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES
(2024)
Review
Engineering, Chemical
Isabel V. Souza, Nathalia S. Finck, Camila S. Rodrigues, Rafael R. Moraes
Summary: This systematic review summarizes the evidence from in vitro studies on the effect of different glass ceramic processing methods on the bond strength to resin-based luting agents. The findings suggest that ceramics processed by CAD-CAM method generally have higher bond strength to resin-based materials compared to heat-pressing or layering processing methods.
INTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES
(2024)
Article
Engineering, Chemical
Chenglong Zhang, Huiqi Shao, Yue Zhang, Nanliang Chen, Jinhua Jiang
Summary: This study investigates the potential application of adhesive bonding techniques for connecting envelope composites in airships. Experimental results show that the mechanical performance of adhesively bonded joints is significantly influenced by structural parameters, while simulation results reveal the mechanism of the negative effect of stiffness mismatch on the failure strength of adhesively bonded joints.
INTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES
(2024)
Article
Engineering, Chemical
Xinyi Chen, Hisham Essawy, Haizhu Wu, Antonio Pizzi, Emmanuel Fredon, Christine Gerardin, Guanben Du, Xiaojian Zhou
Summary: In this study, the performance of tannin-based non-isocyanate polyurethane adhesive was improved by using branched polyethylenimine/tannin mixtures instead of toxic hexamethylenediamine. By adding appropriate amounts of tannin/PEI mixtures, the viscosity and thermal stability of the adhesive were enhanced, and it achieved similar bonding performance to the traditional adhesive.
INTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES
(2024)
Article
Engineering, Chemical
M. K. Saravanan, A. V. S. Siva Prasad, Raguraman Munusamy
Summary: Polyurea coated structures have garnered significant attention due to their various applications. However, there is a lack of research on delamination in polyurea coated structures. This study aims to develop a rate-dependent traction-separation model and a numerical modeling framework to simulate the rate-dependent delamination process. The proposed approach successfully reproduced the fracture mechanisms and aided in understanding the interaction between different regions during delamination.
INTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES
(2024)
Article
Engineering, Chemical
Jihyeon Hur, Minseok Kim, Jun Tae Kim, Eunyeong Yang, Seung Sang Hwang, Jongok Won
Summary: A multinetwork structured urushi organogel was created by using Fe3+ ions for both chemical and physical crosslinking. This gel exhibits reversible adhesive properties and consistent tensile strength, providing potential applications for natural urushi.
INTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES
(2024)
