Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 78, Issue -, Pages 78-81Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2017.03.007
Keywords
Rhenium; Benzothiazole; Uracil; Spectral characterization; Crystal structure; DNA interaction
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Funding
- University of KwaZulu-Natal
- National Research Foundation of South Africa
- Deutscher Akademischer Austauschdienst (DAAD)
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Novel facial tricarbonylrhenium(I) complexes, fac-[Re(urca)(2)(CO)(3)Cl] (1) and fac-[Re(bzta)(CO)(3)Cl] (2) were isolated from the coordination reactions of 5-((5-hydroxypentylimino)methyl)uracil (urca) and 2-((5-hydroxypentylimino)methyl)benzothiazole (bzta) with [Re(CO)(5)Cl], respectively. Spectral characterization of metal complexes 1 and 2 were supported by their X-ray crystal structures. DNA interactions were assessed via UV-Vis calf-thymus (CT)-DNA binding titrations and gel electrophoresis. Redox properties of the metal complexes were probed using voltammetry. (C) 2017 Elsevier B.V. All rights reserved.
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