4.8 Article

Ru/ceria-catalyzed direct formylation of amines and CO to produce formamides

Journal

GREEN CHEMISTRY
Volume 19, Issue 1, Pages 88-92

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6gc02603f

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Funding

  1. National Natural Science Foundation of China [21422308, 21303189]
  2. Strategic Priority Research Program of Chinese Academy of Sciences [XDB17020300]

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We herein report a new strategy of directly converting amines and CO to formamides with 100% atom utilization efficiency. It is suitable for up to 25 amine substrates with no additives. Ru/ceria is found to be an excellent catalyst for this reaction due the efficient co-activation of CO and amine on Ru species.

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