4.7 Article

Petrophysical characterization of tight oil formations using 1D and 2D NMR

Journal

FUEL
Volume 206, Issue -, Pages 89-98

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.fuel.2017.05.098

Keywords

Nuclear magnetic resonance; Tight oil; Porosity; Hydrogen-bearing phases

Funding

  1. National Natural Science Foundation of China [41574122]
  2. National Science and Technology Major Project [2016ZX05006002-004]
  3. China Petroleum and Chemical Corporation (SINOPEC)

Ask authors/readers for more resources

Porosity and fluid types in pores are crucial parameters in evaluating the quality of a tight oil reservoir in both laboratory analyses and log interpretation. As an advanced technique, nuclear magnetic resonance (NMR) has been applied in oilfields to acquire specific petrophysical properties of rocks. In order to interpret NMR data collected from actual oil wells more accurately, it is necessary to perform experiments in the laboratory and then make a well-designed contribution. Due to the complex components of low-permeable rocks, the petrophysical characterization of tight oil formations with both 1D and 2D NMR techniques remains a challenge. In this study, we designed novel NMR experimental procedures to characterize petrophysical properties of tight oil formations. We first investigated optimal parameters for measuring porosities of core samples. In order to explain the porosity differences between NMR porosity and water porosity, we examined contents of hydrogen-bearing matters and studied their total effects on measured porosity. Then, we performed a series of experiments to make core samples in five states, including water saturated state, after-centrifugation state, light oil saturated state, fresh state, and oven drying state. Each state represented a special fluid type, and hydrogen-bearing matters in cores were tried to be identified. Based on experimental results and similarity analyses, identification graphs of hydrogen-bearing phases were made by using 1D T-2 spectrums and a 2D T-1-T-2 map. Our results can not only expand the applications of NMR core analyses, but also help to interpret NMR logging data better. (C) 2017 Elsevier Ltd. All rights reserved.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Chemistry, Physical

Upgrade of low rank coal by using emulsified asphalt and its application for preparation of coal water slurry with high concentration

Lun Du, Guanghua Zhang, Shining Hu, Jie Luo, Wanbin Zhang, Ce Zhang, Junguo Li, Junfeng Zhu

Summary: Emulsified asphalt is an effective and low-cost modifier that can reduce the hydrophilicity of low rank coals and improve the preparation performance of coal water slurry. The modified coal has better adsorption ability for dispersants and exhibits characteristics similar to high rank coal.

JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY (2023)

Article Green & Sustainable Science & Technology

Efficient production of biodiesel with electric furnace dust impregnated in Na2CO3 solution

Yi-Tong Wang, Di Gao, Ya-Nan Zeng, Jun-Guo Li, Ai-Min Ji, Tian-Ji Liu, Shuang Cai, Wen-Jie Cong, Fu-Ping Wang, Qing Yu, Xiao-Man Wang, Zhen Fang

Summary: A solid catalyst Na2CO3@EFD was prepared from electric furnace dust (EFD) and used for biodiesel production. The catalyst exhibited high activity and recyclability, enabling the production of biodiesel with high yield. The study demonstrates the feasibility of utilizing industrial solid waste for the green production of biodiesel.

JOURNAL OF CLEANER PRODUCTION (2022)

Correction Chemistry, Multidisciplinary

Synthesis of 2,3,5-trimethylbenzoquinone from 2,3,6-trimethylphenol and tert-butyl hydroperoxide in microreactors (vol 12, 219, 2022)

Junguo Li, Weifeng Lin, Yingjie Shao, Tianren Tang, Wei Qiang, Zhaohui Pan, Yuanhai Su, Minjing Shang

JOURNAL OF FLOW CHEMISTRY (2022)

Article Environmental Sciences

Highly efficient removal of hexavalent chromium by magnetic Fe-C composite from reed straw and electric furnace dust waste

Fu-Ping Wang, Ya-Nan Zeng, Yi-Tong Wang, Jun-Guo Li, Xi Zhang, Ai-Min Ji, Le-Le Kang, Rui Ji, Qing Yu, Di Gao, Xiao-Man Wang, Zhen Fang

Summary: In this study, magnetic Fe-C composites (EFD&C) were prepared using reed straw and electric furnace dust waste to remove Cr(VI) from water. The EFD&C had a large specific surface area and porous structure, and showed efficient removal capacity for Cr(VI). The adsorption mechanism involved chemical adsorption by redox reaction and physical adsorption into the porous structure. This study provided a feasible solution for preparing adsorbents from iron-containing metallurgical solid waste and biomass waste, contributing to environmental pollution reduction and cost savings in adsorbent preparation.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2023)

Article Energy & Fuels

Combustion of the banana Pseudo-stem hydrochar by the High-Pressure CO2-Hydrothermolysis: Thermal conversion, kinetic, and emission analyses

Fenghao Jiang, Daofan Cao, Yan Zhang, Shunxuan Hu, Xiaohe Huang, Yutian Ding, Changning Wu, Junguo Li, Yulong Ding, Ke Liu

Summary: Due to improper disposal, banana pseudo-stem has caused serious environmental problems and fungal diseases. High-pressure CO2-hydrothermolysis is an effective strategy for improving the combustion characteristics and emission analysis of banana pseudo-stem. The results of this study show that high-pressure CO2-hydrothermolysis can produce coal-like fuel with higher heating value and reduce carbon, sulfur, and nitrogen emissions.
Article Energy & Fuels

Enhancement of ultrafine coal slime flotation using high-shear pretreatment and polyvinylpyrrolidone

Yujie Mei, Qiuyu Lin, Daofan Cao, Junguo Li, Ke Liu

Summary: This paper investigates the influence of high-shear pretreatment and polyvinylpyrrolidone (PVP) on the flotation performance of ultrafine coal slime (UCS). The results show that with the assistance of HSP and PVP, the flotation concentrate has less gangue entrainment, high combustible recovery, and low ash content.

INTERNATIONAL JOURNAL OF COAL PREPARATION AND UTILIZATION (2023)

Article Materials Science, Multidisciplinary

A Novel Two-Step γ → α′L → β Phase Transformation Method for Dicalcium Silicate in AOD Slag for Improving Hydration Activity

Xi Zhang, Hao Na, Pengyao Liu, Yajun Wang, Junguo Li, Qian Meng, Guopeng Li

Summary: Regulating the phase transformation from gamma to beta in dicalcium silicate (C2S) can enhance the hydration activity and recycling rate of AOD slag. This study presents a novel two-step gamma -> alpha '(L) -> beta phase transformation method in C2S, which transforms needle-like nanostructured gamma-C2S grains to lamellar-structured beta-C2S grains.

METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE (2023)

Article Thermodynamics

Investigation on influencing mechanisms of phosphogypsum (PG) on the ash fusion behaviors of coal

Fenghai Li, Wei Zhao, Junguo Li, Hongli Fan, Meiling Xu, Guopeng Han, Mingxi Guo, Zhiqing Wang, Jiejie Huang, Yitian Fang

Summary: This study investigates the influence of phosphogypsum (PG) on the coal ash fusion characteristics and analyzes the modifications of ash fusion temperature (AFT) for Xiaolongtan coal (XLT) and Jiaozuo coal (JZ) under a reducing atmosphere. The AFT of mixed XLT increases with increasing PG mass ratio, while the AFT decreases for JZ mixtures. The suitable PG mass ratios for XLT and JZ are 4.9%-8.9% and 6.5%-9.0%, respectively. The changes in AFT result from the variations in the base/acid ratio and the presence of different minerals in the ash. The AFT variation can also be explained by the variations in the temperature range and ash composition positions in the SiO2-Al2O3-CaO ternary phase diagram with increasing PG mass ratio.

ENERGY (2023)

Article Materials Science, Multidisciplinary

Microstructure and mechanical properties of dense ZTA ceramics with high Cr2O3 solution

Junguo Li, Xinyu Zhong, Guoqiang Luo, Qiwang Cai, Qiang Shen, Rong Tu, Xiaoping Guo, Renchi Ding

Summary: In this study, dense ZTA ceramics with high Cr2O3 content were prepared using spark plasma sintering, which inhibited the volatilization of Cr2O3. The addition of Cr2O3 improved the hardness and fracture toughness of the ceramics by regulating the grain size in the matrix. The optimum performance was achieved with a 5 wt% dosage of Cr2O3, resulting in the maximum values of Vickers hardness and fracture toughness.

JOURNAL OF MATERIALS SCIENCE (2023)

Article Polymer Science

Ceramicization mechanism and thermal insulation/ablative properties of hollow microspheres/boron phenolic composites

Junguo Li, Lei Pan, Shiquan Zhang, Jian Zhang, Minxian Shi, Qiang Shen

Summary: This study provides a novel phenolic resin composite with high thermal insulation capacity by introducing hollow silica microspheres as an insulation layer. The composites with microspheres exhibit high uniformity and improved bending strength. The introduction of microspheres also improves the thermal stability and reduces the back surface temperature during oxyacetylene ablation.

POLYMER DEGRADATION AND STABILITY (2023)

Article Green & Sustainable Science & Technology

A novel strategy for efficient biodiesel production: Optimization, prediction, and mechanism

Xiao-Man Wang, Ya-Nan Zeng, Yu-Ran Wang, Fu-Ping Wang, Yi-Tong Wang, Jun-Guo Li, Rui Ji, Le-Le Kang, Qing Yu, Tian-Ji Liu, Zhen Fang

Summary: To solve the resistance of biodiesel industrial production, researchers prepared the Na2CO3@BFD catalyst from blast furnace dust and used it to catalyze biodiesel production at low temperature, achieving a biodiesel yield of 99.04 wt%. The optimized conditions included a methanol/oil molar ratio of 13.72/1, catalyst dosage of 9.77 wt%, and temperature of 74.86 degrees C for 1.62 h. The study also found that temperature had the greatest influence on the reaction, followed by time, methanol/oil molar ratio, and catalyst dosage.

RENEWABLE ENERGY (2023)

Article Engineering, Chemical

Simulation of Rock Electrical Properties in Deep Reservoirs Based on Digital Rock Technology

Suogui Shang, Qiangyong Gao, Yunjiang Cui, Peichun Wang, Zhang Zhang, Yadong Yuan, Weichao Yan, Peng Chi

Summary: We proposed a low-cost and high-efficiency workflow for simulating the electrical properties of rocks under high-pressure and high-temperature conditions. This method accurately predicts the electrical characteristics of rocks and plays a key role in water saturation prediction.

PROCESSES (2023)

Article Agriculture, Dairy & Animal Science

Effects of Lactobacillus Lactis Supplementation on Growth Performance, Hematological Parameters, Meat Quality and Intestinal Flora in Growing-Finishing Pigs

Haitao Duan, Lizi Lu, Lei Zhang, Jun Li, Xu Gu, Junguo Li

Summary: The study aimed to assess the effects of Lactobacillus lactis supplementation on growth performance, hematological parameters, meat quality, and intestinal flora in pigs. The results showed that LL supplementation increased final body weight, average daily weight gain, average daily feed intake, and improved meat quality.

ANIMALS (2023)

Article Environmental Sciences

Highly effective sequestration of Cd(II) from aqueous solution using marine diatom biomass: Adsorption performances and mechanism

Xin Wang, Jingfeng Wang, Shanfa Zhang, Junguo Li

Summary: This study revealed that different nonliving marine diatom biomass could efficiently remove Cd(II), with nonliving Nitzschia possessing the highest adsorption capacity. The adsorption process was found to be spontaneous, endothermic, and involving chemisorption. Inorganic salts and turbidity had negative effects on Cd(II) adsorption, while humic acid had a positive effect. Additionally, leaching of organics during adsorption could also affect chemical bonds distribution on the biomass.

FRONTIERS IN ENVIRONMENTAL SCIENCE (2023)

Article Materials Science, Ceramics

Enhanced mechanical, thermal and ablation properties of carbon fiber/BPR composites modified by mica synergistic MoSi2 at 1500 °C

Shiquan Zhang, Jian Zhang, Suohui Yang, Minxian Shi, Junguo Li, Qiang Shen

Summary: A high flexural strength of 66.91 MPa was achieved in carbon fiber/boron phenolic resin (CF/BPR) composites modified by MoSi2 and mica, after ablation at 1500 degrees C. The addition of MoSi2 improved the reactivity of MoSi2 powders and provided a suitable interfacial state between CF and the matrix, resulting in improved ablation resistance. The oxygen-acetylene test showed reduced mass ablation and linear ablation rates of 0.034 g/s and 0.006 mm/s, respectively. These high-strength CF/BPR composites have strong potential in aerospace applications.

CERAMICS INTERNATIONAL (2023)

Article Energy & Fuels

Preparation of surface modified nano-hydrotalcite and its applicaiton as a flow improver for crude oil

Yingna Du, Chen Huang, Wei Jiang, Qiangwei Yan, Yongfei Li, Gang Chen

Summary: In this study, anionic surfactants modified hydrotalcite was used as a flow improver for crude oil under low-temperature conditions. The modified hydrotalcite showed a significant viscosity reduction effect on crude oil. The mechanism of the modified hydrotalcite on viscosity and pour point of crude oil was explored through characterization and analysis of the modified hydrotalcite and oil samples.
Article Energy & Fuels

Effect of incorporated hybrid MIL-53(Al) and MWCNT into PES membrane for CO2/CH4 and CO2/N2 separation

Mohammad Saeid Rostami, Mohammad Mehdi Khodaei

Summary: In this study, a hybrid structure, MIL-53(Al)@MWCNT, was synthesized by combining MIL-53(Al) particles and -COOH functionalized multi-walled carbon nanotube (MWCNT). The hybrid structure was then embedded in a polyethersulfone (PES) polymer matrix to prepare a mixed matrix membrane (MMM) for CO2/CH4 and CO2/N2 separation. The addition of MWCNTs prevented MIL-53(Al) aggregation, improved membrane mechanical properties, and enhanced gas separation efficiency.
Article Energy & Fuels

Phase behaviour and physical properties of dimethyl ether (DME)/flue gas/ water/heavy oil systems under reservoir conditions

Yunlong Li, Desheng Huang, Xiaomeng Dong, Daoyong Yang

Summary: This study develops theoretical and experimental techniques to determine the phase behavior and physical properties of DME/flue gas/water/heavy oil systems. Eight constant composition expansion (CCE) tests are conducted to obtain new experimental data. A thermodynamic model is used to accurately predict saturation pressure and swelling factors, as well as the phase boundaries of N2/heavy oil systems and DME/CO2/heavy oil systems, with high accuracy.
Article Energy & Fuels

Comparison of CO2 absorption in DETA solution and [bmim]-[PF6] using thermodynamic and process modelling

Morteza Afkhamipour, Ebad Seifi, Arash Esmaeili, Mohammad Shamsi, Tohid N. Borhani

Summary: Non-conventional amines are being researched worldwide to overcome the limitations of traditional amines like MEA and MDEA. Adequate process and thermodynamic models are crucial for understanding the applicability and performance of these amines in CO2 absorption, but studies on process modeling for these amines are limited. This study used rate-based modeling and Deshmukh-Mather method to model CO2 absorption by DETA solution in a packed column, validated the model with experimental data, and conducted a sensitivity analysis of mass transfer correlations. The study also compared the CO2 absorption efficiency of DETA solution with an ionic solvent [bmim]-[PF6] and highlighted the importance of finding optimum operational parameters for maximum absorption efficiency.
Article Energy & Fuels

Interfacial tension of smart water and various crude oils

Arastoo Abdi, Mohamad Awarke, M. Reza Malayeri, Masoud Riazi

Summary: The utilization of smart water in EOR operations has gained attention, but more research is needed to understand the complex mechanisms involved. This study investigated the interfacial tension between smart water and crude oil, considering factors such as salt, pH, asphaltene type, and aged smart water. The results revealed that the hydration of ions in smart water plays a key role in its efficacy, with acidic and basic asphaltene acting as intrinsic surfactants. The pH also influenced the interfacial tension, and the aged smart water's interaction with crude oil depended on asphaltene type, salt, and salinity.
Article Energy & Fuels

Co-based metal-organic frameworks confined N-hydroxyphthalimide for enhancing aerobic desulfurization of diesel fuels

Dongao Zhu, Kun Zhu, Lixian Xu, Haiyan Huang, Jing He, Wenshuai Zhu, Huaming Li, Wei Jiang

Summary: In this study, cobalt-based metal-organic frameworks (Co-based MOFs) were used as supports and co-catalysts to confine the NHPI catalyst, solving the leaching issue. The NHPI@Co-MOF with carboxyl groups exhibited stronger acidity and facilitated the generation of active oxygen radicals O2•, resulting in enhanced catalytic activity. This research provides valuable insights into the selection of suitable organic linkers and broadens the research horizon of MOF hybrids in efficient oxidative desulfurization (ODS) applications.
Article Energy & Fuels

Influence of carbon-coated zero-valent iron-based nanoparticle concentration on continuous photosynthetic biogas upgrading

Edwin G. Hoyos, Gloria Amo-Duodu, U. Gulsum Kiral, Laura Vargas-Estrada, Raquel Lebrero, Rail Munoz

Summary: This study investigated the impact of carbon-coated zero-valent nanoparticle concentration on photosynthetic biogas upgrading. The addition of nanoparticles significantly increased microalgae productivity and enhanced nitrogen and phosphorus assimilation. The presence of nanoparticles also improved the quality of biomethane produced.
Article Energy & Fuels

Effect of aqueous phase recycling on iron evolution and environmental assessment during hydrothermal carbonization of dyeing sludge

Yao Xiao, Asma Leghari, Linfeng Liu, Fangchao Yu, Ming Gao, Lu Ding, Yu Yang, Xueli Chen, Xiaoyu Yan, Fuchen Wang

Summary: Iron is added as a flocculant in wastewater treatment and the hydrothermal carbonization (HTC) of sludge produces wastewater containing Fe. This study investigates the effect of aqueous phase (AP) recycling on hydrochar properties, iron evolution and environmental assessment during HTC of sludge. The results show that AP recycling process improves the dewatering performance of hydrochar and facilitates the recovery of Fe from the liquid phase.
Article Energy & Fuels

Investigation on the lower flammability limit and critical inhibition concentration of hydrogen under the influence of inhibitors

He Liang, Tao Wang, Zhenmin Luo, Jianliang Yu, Weizhai Yi, Fangming Cheng, Jingyu Zhao, Xingqing Yan, Jun Deng, Jihao Shi

Summary: This study investigated the influence of inhibitors (carbon dioxide, nitrogen, and heptafluoropropane) on the lower flammability limit of hydrogen and determined the critical inhibitory concentration needed for complete suppression. The impact of inhibitors on explosive characteristics was evaluated, and the inhibitory mechanism was analyzed with chemical kinetics. The results showed that with the increase of inhibitor quantity, the lower flammability limit of hydrogen also increased. The research findings can contribute to the safe utilization of hydrogen energy.
Article Energy & Fuels

Phosphotungstic acid supported on Zr-SBA-15 as an efficient catalyst for one-pot conversion of furfural to ?-valerolactone

Zonghui Liu, Zhongze Zhang, Yali Zhou, Ziling Wang, Mingyang Du, Zhe Wen, Bing Yan, Qingxiang Ma, Na Liu, Bing Xue

Summary: In this study, high-performance solid catalysts based on phosphotungstic acid (HPW) supported on Zr-SBA-15 were synthesized and evaluated for the one-pot conversion of furfural (FUR) to γ-valerolactone (GVL). The catalysts were characterized using various techniques, and the ratio of HPW and Zr was found to significantly affect the selectivity of GVL. The HPW/Zr-SBA-15 (2-4-15) catalyst exhibited the highest GVL yield (83%) under optimized reaction conditions, and it was determined that a balance between Bronsted acid sites (BAS) and Lewis acid sites (LAS) was crucial for achieving higher catalytic performance. The reaction parameters and catalyst stability were also investigated.
Article Energy & Fuels

Experimental study of droplet vaporization for conventional and renewable transportation fuels: Effects of physical properties and chemical composition

Michael Stoehr, Stephan Ruoff, Bastian Rauch, Wolfgang Meier, Patrick Le Clercq

Summary: As part of the global energy transition, an experimental study was conducted to understand the effects of different fuel properties on droplet vaporization for various conventional and alternative fuels. The study utilized a flow channel to measure the evolution of droplet diameters over time and distance. The results revealed the temperature-dependent effects of physical properties, such as boiling point, liquid density, and enthalpy of vaporization, and showed the complex interactions of preferential vaporization and temperature-dependent influences of physical properties for multi-component fuels.
Article Energy & Fuels

An experimental and modeling study on the oxidation of ammonia-methanol mixtures in a jet stirred reactor

Yuan Zhuang, Ruikang Wu, Xinyan Wang, Rui Zhai, Changyong Gao

Summary: Through experimental validation and optimization of the chemical kinetic model, it was found that methanol can accelerate the oxidation reaction of ammonia, and methanol can be rapidly oxidized at high concentration. HO2 was found to generate a significant amount of OH radicals, facilitating the oxidation of methanol and ammonia. Rating: 7.5/10.
Article Energy & Fuels

Improving the biodiesel combustion and emission characteristics in the lean pre-vaporized premixed system using diethyl ether as a fuel additive

Radwan M. EL-Zohairy, Ahmed S. Attia, A. S. Huzayyin, Ahmed I. EL-Seesy

Summary: This paper presents a lab-scale experimental study on the impact of diethyl ether (DEE) as an additive to waste cooking oil biodiesel with Jet A-1 on combustion and emission features of a swirl-stabilized premixed flame. The addition of DEE to biodiesel significantly affects the flame temperature distribution and emissions. The W20D20 blend of DEE, biodiesel, and Jet A-1 shows similar flame temperature distribution to Jet A-1 and significantly reduces UHC, CO, and NOx emissions compared to Jet A-1.
Article Energy & Fuels

Condensation characteristics of ammonia vapor during supersonic separation: A novel approach to ammonia-hydrogen separation

Jiang Bian, Ziyuan Zhao, Yang Liu, Ran Cheng, Xuerui Zang, Xuewen Cao

Summary: This study presents a novel method for ammonia separation using supersonic flow and develops a mathematical model to investigate the condensation phenomenon. The results demonstrate that the L-P nucleation model accurately characterizes the nucleation process of ammonia at low temperatures. Numerical simulations also show that increasing pressure and concentration can enhance ammonia condensation efficiency.
Article Energy & Fuels

Multivariate time series prediction for CO2 concentration and flowrate of flue gas from biomass-fired power plants

Shiyuan Pan, Xiaodan Shi, Beibei Dong, Jan Skvaril, Haoran Zhang, Yongtu Liang, Hailong Li

Summary: Integrating CO2 capture with biomass-fired combined heat and power (bio-CHP) plants is a promising method for achieving negative emissions. This study develops a reliable data-driven model based on the Transformer architecture to predict the flowrate and CO2 concentration of flue gas in real time. The model validation shows high prediction accuracy, and the potential impact of meteorological parameters on model accuracy is assessed. The results demonstrate that the Transformer model outperforms other models and using near-infrared spectral data as input features improves the prediction accuracy.