Article
Chemistry, Physical
Badr M. Thamer, Meera Moydeen Abdul Hameed, Abdullah M. Al-Enizi
Summary: The study focuses on the development of efficient electrocatalysts using low-cost nanostructured transition metals. Highly dispersed bimetallic nickel-molybdenum nanoparticles were prepared on electrospun carbon nanofibers. The Ni0.6Mo0.4/CNFs showed higher electrocatalytic activity due to the synergistic effect between Ni and Mo nanoparticles and the morphology and structure of the substrate.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Physical
El Mahdi Halim, Hubert Perrot, Ozlem Sel, Catherine Debiemme-Chouvy, Khalid Lafdi, Mama El Rhazi
Summary: In this study, a new catalyst based on CuNDs supported on CNF/PpPD nanocomposite for methanol oxidation reaction was successfully developed, showing high catalytic activity and stability under alkaline conditions. This inexpensive catalyst exhibited the highest activity and stability compared to CNF/CuNDs and PpPD/CuNDs, making it a promising anode catalyst for alkaline DMFC applications.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Electrochemistry
Ibrahim M. Maafa
Summary: This study successfully synthesized NiS nanoparticle-decorated carbon nanofibers as an electrocatalyst for methanol oxidation. Characterization techniques confirmed the good electrocatalytic activity and stability of the prepared NiS NPs/CNFs.
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
(2021)
Article
Chemistry, Multidisciplinary
Mehdi Salmi, Amina Amarray, Youssef Samih, Mohammed Azzi, Sanae EL Ghachtouli
Summary: In this study, nickel sulfide thin film incorporated with carbon nanofibers (Ni4S3-CNF/ITO) was successfully electrodeposited on indium tin oxide. The electrocatalytic activity of Ni4S3-CNF/ITO towards methanol oxidation reaction (MOR) was investigated and showed high activity and stability in an alkaline medium. The addition of carbon nanofibers increased the surface area and improved the tolerance to catalyst-poising species, making it a promising low-cost and efficient fuel cell electrocatalyst.
Article
Chemistry, Physical
Guirong Zhang, Huihui Zhang, Lushi Tan, Zhejuan Zhang, Jiaxing Lu
Summary: The study prepared carbon paste electrodes with different mass percent of silicon-carbon materials. Results showed that the Pt/CPE-Si@C(10%) electrode exhibited higher catalytic activity and stronger tolerance against CO poisoning in the electrocatalytic oxidation of methanol, compared to the Pt/CPE electrode.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Chemistry, Multidisciplinary
Mohamed Sh. Abdel-wahab, Hadeer K. El Emam, Waleed M. A. El Rouby
Summary: In this study, Cu-doped NiO thin films of different thicknesses were successfully prepared on fluorine-doped tin oxide (FTO) using the co-sputtering deposition technique. The prepared films showed ideal crystallinity and purity, as confirmed by X-ray diffraction (XRD) and energy-dispersive X-ray spectroscopy (EDS). Field emission scanning electron microscopy (FESEM) images revealed an increase in film thickness with increasing deposition time. The Cu-doped NiO thin films exhibited high electrocatalytic performance for methanol oxidation, with the highest activity observed in 1 M methanol. The film thickness had a clear impact on the catalytic activity, and Cu-doped NiO films showed good adhesion and electrical contact with the FTO substrate, eliminating the need for binders or conducting agents.
Article
Physics, Applied
Mohsen Shojaeifar, Mohammad Bagher Askari, Seyed Rouhollah Samareh Hashemi, Antonio Di Bartolomeo
Summary: This study investigates the potential of metal oxide-based nanocatalysts and multi-walled carbon nanotubes (MWCNTs) for the electrooxidation of methanol and ethanol. The synthesized MnO2-NiO and MnO2-NiO-MWCNT catalysts show improved stability and kinetic performance, making them attractive options for alcohol fuel cells.
JOURNAL OF PHYSICS D-APPLIED PHYSICS
(2022)
Article
Chemistry, Multidisciplinary
Bin Sun, Zhe Wang, Zi-Han Yuan, Yu Ding, Fu-Min Li, Guang-Tao Zhao, Dong-Sheng Li, Xi-Fei Li, Yu Chen
Summary: Electrostatically assembled ultrathin rhodium nanosheet-gold nanowire nanocomposites (Rh-Au CNSs) were used as an advanced electrocatalyst for the methanol oxidation reaction, demonstrating a significantly higher mass activity compared to single metal Rh nanosheets and commercial Rh nanoparticles.
CHEMICAL COMMUNICATIONS
(2022)
Article
Chemistry, Analytical
Biljana Milovanovic, Sanja Marinovic, Zorica Vukovic, Aleksandra Milutinovic-Nikolic, Rada Petrovic, Predrag Bankovic, Tihana Mudrinic
Summary: This study investigates the impact of cobalt loading in pillared clay-supported materials on the electrocatalytic performance for glucose oxidation. The research shows that an appropriate amount of cobalt loading can improve electrode performance, while excessive loading may decrease it.
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
(2022)
Article
Energy & Fuels
Guo Zhi, Xiaohang Zhang, Wei Qiao, Ligang Feng
Summary: A novel and efficient PtIr alloy catalyst supported on CoSe-NC was developed for methanol electro-oxidation. The well-anchored PtIr alloy nanoparticles exhibited a strong electronic interaction with the support, leading to improved catalytic kinetics, stability, and activity. The PtIr/CoSe-NC catalyst showed a peak current density of 56.7 mA cm-2, which was 2.1 times higher than that of a commercial Pt/C catalyst.
Article
Chemistry, Multidisciplinary
Yuwei Wang, Jian He, Yipeng Zang, Changbao Zhao, Miaomiao Di, Bin Wang
Summary: In this study, α-Mo2C micron flowers were synthesized via a vapor-liquid-solid (VLS) process and were found to exhibit excellent catalytic performance when combined with Pt, surpassing Pt/VSS-Mo2C as a collaborative electrocatalyst for hydrogen evolution reaction (HER).
Article
Chemistry, Analytical
Ebtisam Saeed, Ibrahim Abdelwahab, Abdalla Abdelwahab
Summary: Nitrogen-doped carbon quantum dots (N-CDs) were prepared via a simple microwave-assisted method, and further functionalized with different materials to obtain nanocomposites. Among them, NiCoP/N-CDs shows the highest performance in both anode electro-catalysis for direct methanol fuel cells and preparation of nanofluids. Its high catalytic activity is attributed to its high crystallinity, large pore size, and nanoflakes-like surface morphology. The nanocomposite-based nanofluids exhibit high thermal stability and electrical conductivity, showing promise for various heat transfer operations.
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
(2023)
Article
Chemistry, Physical
Ana C. Ferreira, Joana F. Martinho, Joaquim B. Branco
Summary: Cobalt-lanthanide bimetallic oxide nanofibers prepared by electrospinning technique show excellent catalytic performance and deactivation resistance in the hydrogenation of CO2.
Article
Materials Science, Ceramics
Nur Hawa Nabilah Azman, Yusran Sulaiman
Summary: This research presents a new supercapattery technology with a positive electrode composed of porous functionalized carbon nanofibers (pfCNFs), poly(3,4-ethylenedioxythiophene) (PEDOT), and cobalt oxide (Co3O4). The composite exhibits a flower-like structure and demonstrates high specific capacity and cycling stability, showing great potential as an electrode for supercapattery.
CERAMICS INTERNATIONAL
(2022)
Article
Chemistry, Physical
Chen Deng, Jingjin Tan, Cui Ying Toe, Xuan Li, Guodong Li, Xingxing Jiang, Shaomin Wei, Hengpan Yang, Qi Hu, Chuanxin He
Summary: A three-dimensional hierarchically porous N-doped carbon nanofibers anchored with well-dispersed FeCo site composite electrocatalyst has been developed, showing superior ORR catalytic performance and higher peak power density with excellent stability as an air-cathode in primary zinc-air batteries.
JOURNAL OF MATERIALS CHEMISTRY A
(2022)
Article
Biochemistry & Molecular Biology
Nasser A. M. Barakat, Osama M. Irfan, Hager M. Moustafa
Summary: H3PO4/KOH combined solution is an effective activation agent for producing activated carbon from rice husk. The mixed agent decomposes chemical compounds on the rice husk char surface and increases the surface area. Both single and mixed activation agents need to have optimized solution volumes for maximum specific capacitance. The proposed activated carbon shows excellent electrochemical performance and stability.
Article
Polymer Science
Nasser A. M. Barakat, Aya Gamil, Ibrahim Ashour, Khalil Abdelrazek Khalil
Summary: Novel (Ca, Mg)CO3&SiO2 NPs-decorated multilayer graphene sheets were successfully prepared from corn stalk pith using a simple alkaline hydrothermal treatment process followed by calcination in an inert atmosphere. The nanocomposite exhibited efficient activity as a photocatalyst for water-splitting reactions under visible light. The study investigated the influence of preparation parameters on the hydrogen evolution rate and found the optimal condition to achieve the maximum hydrogen production rate of 43.35 mmol H-2/gcat.min and an energy-to-hydrogen conversion efficiency of 9%.
Article
Chemistry, Multidisciplinary
Seong-Min Ji, Alagan Muthurasu, Hak Yong Kim
Summary: This work describes a concise method for generating marigold flower-like metal-organic frameworks (MOFs) aided manganese vanadium oxide via a hydrothermal procedure for increased OER activity. As synthesized MOF MnV oxide has a higher surface area due to the 3D flower-like structure, which is reinvented with enhanced electrocatalytic active sites. These distinctive structural features result in remarkable catalytic activity for MOF MnV oxide microflowers towards OER.
CHEMISTRY-A EUROPEAN JOURNAL
(2023)
Article
Materials Science, Multidisciplinary
Hany Elsawy, Badr M. Thamer, Azza Sedky, Mohamed H. El-Newehy
Summary: In this study, a high-efficiency anodic electrocatalyst based on nickel nanoparticles supported on three-dimensional porous carbon frameworks (Ni/3DPCFs) was designed for the oxidation of urea and methanol. The catalyst was prepared by a innovative method involving microwave-assisted synthesis of carbon quantum dots (CQDs) and nickel ions (Ni2+) adsorbed on its surface, followed by pyrolysis. The prepared electrocatalyst showed high efficiency for the oxidation of urea and methanol in alkaline media.
MATERIALS CHEMISTRY AND PHYSICS
(2023)
Article
Biochemistry & Molecular Biology
Mohsen M. El-Sherbiny, Reny P. Devassy, Mohamed E. El-Hefnawy, Soha T. Al-Goul, Mohammed I. Orif, Mohamed H. El-Newehy
Summary: Foodborne pathogens pose a significant threat to public health, making it crucial to ensure the sustainability of food production. This study successfully isolated various foodborne pathogens and synthesized silver nanoparticles/montmorillonite nanocomposite with antibacterial potential. The nanocomposite showed strong antibacterial activity against the strains of bacteria tested and has the potential to be used for food preservation to prevent the growth of harmful bacteria and reduce the risk of foodborne illnesses.
Article
Chemistry, Physical
Mohamed H. El-Newehy, Ahmed M. El-Mahalawy, Badr M. Thamer, Meera Moydeen Abdul Hameed
Summary: This study explores the use of dyed environmentally friendly biopolymeric thin films as optical absorbers for multifunctional optoelectronic and solar cell applications. The films were prepared using a spin-coating approach and their molecular interactivity and optical properties were evaluated. The films exhibited potential for laser shielding and as absorbing organic layers in organic/inorganic heterojunction architectures for efficient light sensing and solar energy conversion applications. The engineered dyed films were considered suitable for a wide range of optical and optoelectronic applications based on characterization results.
Article
Polymer Science
Marwa M. Abdel-Aty, Hassan E. Gomaa, Hany Mohamed Abdu, Radwan A. Almasri, Osama M. Irfan, Nasser A. M. Barakat
Summary: In this study, molybdenum carbide co-catalyst and carbon nanofiber matrix were used to enhance the activity of nickel in methanol electrooxidation. The catalyst was synthesized by calcinating electrospun nanofiber mats composed of molybdenum chloride, nickel acetate, and poly (vinyl alcohol) under vacuum at elevated temperatures. The electrochemical measurements showed that the fabricated composite exhibited specific activity for methanol electrooxidation, with the highest performance achieved using nanofibers obtained from an electrospun solution containing 5% molybdenum precursor.
Article
Chemistry, Physical
Alagan Muthurasu, Prabhakaran Sampath, Tae Hoon Ko, Prakash Chandra Lohani, Ishwar Pathak, Debendra Acharya, Kisan Chhetri, Do Hwan Kim, Hak Yong Kim
Summary: A defect-rich porous framework composed of metal-organic compound networks is developed to create high-performance electrocatalysts with improved electrochemical activity, conductivity, and mass transport properties. The resulting hollow carbon nanostructures with in situ-grown N-doped graphitic carbon matrix and embedded selenium-doped CoS2 hollow spheres exhibit efficient and long-lasting chemical energy conversion functions. Additionally, a zinc-air battery with excellent discharge-charge performance and mechanical stability is successfully constructed using this technique.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2023)
Article
Chemistry, Physical
Ishwor Pathak, Debendra Acharya, Kisan Chhetri, Prakash Chandra Lohani, Subhangi Subedi, Alagan Muthurasu, Taewoo Kim, Tae Hoon Ko, Bipeen Dahal, Hak Yong Kim
Summary: In this study, a novel Ti3C2Tx MXene-decorated porous carbon nanofiber (PCNF) freestanding/flexible electrode is prepared by electrospinning, in situ growth of ZIF67, and carbonization processes. The optimized MX-5@PCNF exhibits high specific capacitance, cycling stability, and rate capability. Furthermore, MX-5@PCNF-based flexible symmetric and asymmetric supercapacitors demonstrate high energy densities, long life cycle, and ideal coulombic efficiency, showing their practical applicability. This study provides an alternative strategy to prepare MXene-decorated PCNF freestanding electrodes and can be extended to other 2D MXenes for designing efficient electrodes for flexible supercapacitors.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)
Article
Chemistry, Physical
Meera Moydeen Abdul Hameed, Badr M. Thamer
Summary: Security encoding using photochromism is an effective method for creating authentication substrates. A unique photochromic ink has been developed that emits light continuously under UV rays and darkness. The ink is produced by dispersing lanthanidedoped aluminate nanoparticles in a polymer binder. The resulting composite ink can be used to create transparent films on paper, and the stamped patterns become visible under UV rays, changing from colorless to green.
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
(2024)
Article
Biochemistry & Molecular Biology
Badr M. Thamer, Faiz A. Al-aizari, Hany S. Abdo
Summary: In this study, the adsorption efficiency of activated carbon derived from pomegranate peel waste was improved through surface modification, which showed high effectiveness in removing crystal violet dye. The characterization studies confirmed the highly porous structure of the activated carbon.
Article
Nanoscience & Nanotechnology
Pengfei Cai, Chunchun Li, Yangfan Ding, Hanting Lu, Xiao Yu, Jie Cui, Fan Yu, Hongsheng Wang, Jinglei Wu, Mohamed EL-Newehy, Meera Moydeen Abdulhameed, Liang Song, Xiumei Mo, Binbin Sun
Summary: This research introduces a novel method that combines electrospun nanofibers with 3D printing techniques to fabricate composite scaffolds for bone defect treatment. Compared to nanoparticle-reinforced scaffolds, these scaffolds infused with nanofibers exhibit superior mechanical attributes and bioactivity.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Analytical
Mohamed H. El-Newehy, Ali Aldalbahi, Badr M. Thamer, Meera Moydeen Abdulhameed
Summary: The use of electrospun nanofibers of rare-earth aluminate (NREA) and recycled poly(ethylene terephthalate) (PET) with photochromic properties can enhance the anti-counterfeiting performance of economic goods. The nanofibers have a diameter of 150-250 nm, high transparency, and exhibit fast and reversible fluorescent photochromism.
Article
Energy & Fuels
Chanwoo Park, Bhavana Joshi, Edmund Samuel, Byeong-yeop Kim, Ali Aldalbahi, Mohamed El-Newehy, Hae-Seok Lee, Sam S. Yoon
Summary: This study presents a flexible PENG with supersonically cold-sprayed films of cobalt titanate and polyvinylidene fluoride. The PENG exhibits excellent mechanical durability and generates high voltage and current output during tapping and bending tests.
INTERNATIONAL JOURNAL OF ENERGY RESEARCH
(2023)