Journal
FARADAY DISCUSSIONS
Volume 198, Issue -, Pages 419-431Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6fd00192k
Keywords
-
Categories
Funding
- Global Research Network Program through the National Research Foundation, Korea [2014S1A2A2027802]
- Basic Science Research Program through the National Research Foundation, Korea [2016R1A2B4007366]
- Nano Material Technology Development Program through the National Research Foundation, Korea [2016M3A7B4908169]
- Korea CCS RD Center (KCRC) [2014M1A8A1049354]
- Qatar National Research Fund under its National Priorities Research Program [NPRP 9-052-2-020]
- National Research Foundation of Korea [2016R1A2B4007366, 2014S1A2A2027802] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Ask authors/readers for more resources
The photocatalytic production of molecular hydrogen (H-2) on ternary composites of Pt, CdS, and sodium trititanate nanotubes (NaxH2-xTi3O7, TNTs) is examined in an aqueous 2-propanol (IPA) solution (typically 5 vol%) at a circum-neutral pH under visible light (lambda > 420 nm). The H-2 production rates are dependent on the Pt-loading level, and the optimum production rate in the Pt/CdS/TNTs is approximately six times higher than that in Pt/CdS/TiO2. A D2O solution containing 5 vol% IPA leads only to the production of D-2 molecules, whereas increasing the IPA amount to 30 vol% leads to the production of DH molecules. This indicates that the Pt/CdS/TNTs composites enable H-2 production via true water splitting under our typical experimental conditions. X-ray photoelectron spectroscopy (XPS) analyses of the as-synthesized Pt/CdS/TNTs and those used for 6 and 12 h show that metallic Pt on the CdS/TNTs is less susceptible to oxidation than Pt on CdS/TiO2. In addition, photocorrosion of CdS (i.e., sulfate formation) is significantly inhibited during the photocatalytic H-2 production reactions in the Pt/CdS/TNTs because of the efficient charge transfer via the TNTs framework. The Pt/CdS/TNTs samples are thermally more stable than Pt/CdS/TiO2 and CdS/TNTs, effectively inhibiting the formation of CdO during the thermal synthesis. Detailed surface characterizations of the as-synthesized ternary composites are performed using Xray diffraction, transmission electron microscopy, energy dispersive spectroscopy, and XPS.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available