Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2017, Issue 46, Pages 6816-6830Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201700986
Keywords
Ynamides; Diels-Alder reactions; Pyrimidines; Pyridines; Pericyclic reactions; Nitrogen heterocycles; Cycloaddition
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Nitrogen-substituted alkynes such as ynamines and ynamides are competent partners in [4+2] cycloaddition reactions. This microreview aims to discuss in a historical context the main achievements in the work on this class of reactions that leads to valuable nitrogen-containing heterocycles in a single-step fashion. In the last section, our own work in the field of inverse-electron-demand Diels-Alder reactions between ynamides and pyrimidines is discussed.
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