Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2017, Issue 32, Pages 4773-4777Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201700618
Keywords
Iodine-mediated reactions; Synthetic methods; Iodine; Nitrogen heterocycles; Domino reactions; Fused-ring systems
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Funding
- National Natural Science Foundation of China (NSFC) [21562052, 81573294, 81373285]
- Major Project for the Innovation of Industry and Research of Guangzhou City [201508020128]
- Guizhou Provincial Department of Science and Technology [LH[2014]7554]
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An efficient and practical approach to 3a-azidofuroindolines and -pyrroloindolines involving an iodine-catalyzed azidation/cyclization cascade of tryptophols and tryptamines with NaN3 was developed. Further transformation of the C3-azidated product provided a key intermediate for the total synthesis of psychotriasine.
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