Ruthenium and Osmium Germyl Complexes Derived from the Reactions of MXCl(PPh3 )3 (M = Ru, Os; X = Cl, H) with Terphenylchlorogermylene (C6 H3 -2,6-Trip2 )GeCl (Trip = 2,4,6-i Pr3 C6 H2 )

β-Diketiminato-Germylene Complexes of Carbonyl Ruthenium: Synthesis, Structure, and Reactivity

(2017) Peng Nie et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Coordination Chemistry of [E(Idipp)]2+ Ligands (E = Ge, Sn): Metal Germylidyne [Cp*(CO)2W≡Ge(Idipp)]+ and Metallotetrylene [Cp*(CO)3W–E(Idipp)]+ Cations

(2017) Yury N. Lebedev et al.   ORGANOMETALLICS

Synthesis and Reactivity of Intramolecularly NHC-Stabilized Germylenes and Stannylenes

(2017) Daniel Paul et al.   ORGANOMETALLICS

Theoretical Assessment of Low-Valent Germanium Compounds as Transition Metal Ligands: Can They Be Better than Phosphines or NHCs?

(2017) Zsolt Benedek et al.   ORGANOMETALLICS

E–H (E = B, Si, Ge) bond activation of pinacolborane, silanes, and germanes by nucleophilic palladium carbene complexes

(2016) Cezar C. Comanescu et al.   CHEMICAL COMMUNICATIONS

Multinuclear Alkali Metal Complexes of a Triphenylene-Based Hexamine and the Transmetalation to Tris(N-heterocyclic tetrylenes) (Ge, Sn, Pb)

(2016) Fei Zhong et al.   INORGANIC CHEMISTRY

Oxidative-addition of germanium–hydrogen bonds to triosmium centers: Reactions of Os 3 (CO) 10 (μ-dppm) and Os 3 (CO) 8 (μ 3 -Ph 2 PCH 2 P(Ph)C 6 H 4 )(μ-H) with Ph 3 GeH

(2016) Mohd. Rezaul Haque et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

The transition-metal chemistry of amidinatosilylenes, -germylenes and -stannylenes

(2015) Lucía Álvarez-Rodríguez et al.   COORDINATION CHEMISTRY REVIEWS

All-metallagermoxane with an adamantanoid cage structure: [(Cp*Ru(CO)2Ge)4(μ-O)6] (Cp* = η5-C5Me5)

(2015) K. Bakthavachalam et al.   DALTON TRANSACTIONS

Intramolecularly Stabilized Heavier Tetrylenes: From Monodentate to Bidentate ­Ligands

(2015) Javier A. Cabeza et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Amidinatogermylene Derivatives of Ruthenium Carbonyl: New Insights into the Reactivity of [Ru3(CO)12] with Two-Electron-Donor Reagents of High Basicity

(2015) Lucía Álvarez-Rodríguez et al.   INORGANIC CHEMISTRY

Reactivity Studies on a Binuclear Ruthenium(0) Complex Equipped with a Bridging κ2N,Ge-Amidinatogermylene Ligand

(2015) Javier A. Cabeza et al.   INORGANIC CHEMISTRY

New Vinylgermanium Derivatives of Silsesquioxanes and Their Ruthenium Complexes—Synthesis, Structure, and Reactivity

(2015) Dawid Frąckowiak et al.   ORGANOMETALLICS

A Ruthenium Dihydrogen Germylene Complex and the Catalytic Synthesis of Digermoxane

(2015) Katharine A. Smart et al.   ORGANOMETALLICS

Iron Complexes with Stabilized Germylenes: Syntheses and Characterizations

(2015) Mohammad El Ezzi et al.   ORGANOMETALLICS

[Ge(H)(2-C6H4PPh2)3] as Ligand Precursor at Ruthenium: Formation and Reactivity of [Ru(Cl){Ge(2-C6H4PPh2)3}]

(2014) Roy Herrmann et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Application of the Donor–Acceptor Concept to Intercept Low Oxidation State Group 14 Element Hydrides using a Wittig Reagent as a Lewis Base

(2014) Anindya K. Swarnakar et al.   INORGANIC CHEMISTRY

Cationic Metallogermylene and Dicationic Dimetallodigermenes: Synthesis by Chloride Abstraction from N-Heterocyclic Carbene-Stabilized Chlorometallogermylenes

(2014) Koya Inomata et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Dehydrogenative Germylation of C–H Bonds: New Entry to Unsymmetrically Functionalized 9-Germafluorenes

(2014) Masahito Murai et al.   ORGANIC LETTERS

Steric effects in the reactions of amidinate germylenes with ruthenium carbonyl: isolation of a coordinatively unsaturated diruthenium(0) derivative

(2014) Javier A. Cabeza et al.   RSC Advances

Rhenium-Germanium Triple Bonds: Syntheses and Reactions of the Germylidyne Complexesmer-[X2(PMe3)3ReGeR] (X=Cl, I, H; R=m-terphenyl)

(2013) Alexander C. Filippou et al.   CHEMISTRY-A EUROPEAN JOURNAL

Preparation and reactivity of germyl complexes of ruthenium and osmium stabilised by cyclopentadienyl, indenyl and tris(pyrazolyl)borate fragments

(2013) Gabriele Albertin et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

The Osmium–Silicon Triple Bond: Synthesis, Characterization, and Reactivity of an Osmium Silylyne Complex

(2013) Paul G. Hayes et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and reactivity of cationic ruthenium germylene complexes [Cp*(PiPr3)RuH2(GeRR′)]+

(2012) Meg E. Fasulo et al.   CHEMICAL COMMUNICATIONS

Expanding the coordination chemistry of donor-stabilized group-14 metalenes

(2012) Javier A. Cabeza et al.   DALTON TRANSACTIONS

Preparation of Germyl Complexes of Osmium(II)

(2012) Gabriele Albertin et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Coordination Chemistry of 4-Methyl-2,6,7-trioxa-1-phosphabicyclo[2,2,1]heptane: Preparation and Characterization of Ru(II) Complexes

(2012) Evan E. Joslin et al.   INORGANIC CHEMISTRY

Synthesis and Characterization of Rhodium Complexes with Phosphine-Stabilized Germylenes

(2012) Juan M. García et al.   INORGANIC CHEMISTRY

Reactivity of Divalent Germanium Alkoxide Complexes Is in Sharp Contrast to the Heavier Tin and Lead Analogues

(2012) Lorenzo Ferro et al.   INORGANIC CHEMISTRY

Synthesis and Characterization of β-Diketiminate Germanium(II) Compounds

(2012) Ying Yang et al.   INORGANIC CHEMISTRY

A Germanium Isocyanide Complex Featuring (n → π*) Back-Bonding and Its Conversion to a Hydride/Cyanide Product via C–H Bond Activation under Mild Conditions

(2012) Zachary D. Brown et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Osmium–Germanium and Osmium–Germanium–Gold Carbonyl Cluster Complexes: Syntheses, Structures, Bonding, and Reactivity

(2012) Richard D. Adams et al.   ORGANOMETALLICS

Syntheses and Reactions of Derivatives of (Pyrrolylaldiminato)germanium(II) and -Aluminum(III)

(2012) Ying Yang et al.   ORGANOMETALLICS

Metal Activation of a Germylenoid, a New Approach to Metal–Germanium Triple Bonds: Synthesis and Reactions of the Germylidyne Complexes [Cp(CO)2M≡Ge–C(SiMe3)3] (M = Mo, W)

(2012) Alexander C. Filippou et al.   ORGANOMETALLICS

Selective Substitution of One of the Substituents on Germanium in Coordinatively Unsaturated Ruthenium Germyl Complexes

(2012) Peter D. W. Boyd et al.   ORGANOMETALLICS

Group 14 Hydrides with Low Valent Elements for Activation of Small Molecules

(2011) Swadhin K. Mandal et al.   ACCOUNTS OF CHEMICAL RESEARCH

Trans-selective hydrogermylation of alkynes promoted by methyliron and bis(germyl)hydridoiron complexes as a catalyst precursor

(2011) Masumi Itazaki et al.   CHEMICAL COMMUNICATIONS

Reactivity of Diaminogermylenes with Ruthenium Carbonyl: Ru3Ge3and RuGe2Derivatives

(2011) Javier A. Cabeza et al.   INORGANIC CHEMISTRY

Osmium–carbon multiple bonds: Reduction and C–C coupling reactions

(2011) Tamara Bolaño et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Synthesis and reactivity of germyl complexes of manganese and rhenium

(2011) Gabriele Albertin et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Reactivity of N-Heterocyclic Germylene Toward Ammonia and Water

(2011) Wenyuan Wang et al.   ORGANOMETALLICS

Palladium(II) Hydrido Complexes Having a Primary Silyl or Germyl Ligand: Synthesis, Crystal Structures, and Dynamic Behavior

(2011) Norio Nakata et al.   ORGANOMETALLICS

α-Cleavage of Phenyl Groups from GePh3 Ligands in Iridium Carbonyl Cluster Complexes. A Mechanism and Its Role in the Synthesis of Bridging Germylene Ligands

(2011) Richard D. Adams et al.   ORGANOMETALLICS

Novel Stable Silyl, Germyl, and Stannyl Germanium(II) Compounds Containing an Amidinato Ligand

(2011) Dimitri Matioszek et al.   ORGANOMETALLICS

Chemical Properties of Tetragermaplatinacyclopentane. Insertion of an Alkyne into a Pt–Ge Bond and Silylation Caused by H2SiPh2

(2011) Makoto Tanabe et al.   ORGANOMETALLICS

Interstellar molecules: guides for new chemistry

(2010) Swadhin K. Mandal et al.   CHEMICAL COMMUNICATIONS

Dihydrogenactivation by sulfido-bridged dinuclear Ru/Ge complexes: insight into the [NiFe] hydrogenase unready state

(2010) Tsuyoshi Matsumoto et al.   CHEMICAL COMMUNICATIONS

N-Heterocyclic Carbene Analogues with Low-Valent Group 13 and Group 14 Elements: Syntheses, Structures, and Reactivities of a New Generation of Multitalented Ligands†

(2010) Matthew Asay et al.   CHEMICAL REVIEWS

Coordination complexes of silicon and germanium halides with neutral ligands

(2010) William Levason et al.   COORDINATION CHEMISTRY REVIEWS

Rhodium−Germanium Carbonyl Complexes

(2010) Richard D. Adams et al.   INORGANIC CHEMISTRY

Sila- and Germametallacycles of Late Transition Metals†

(2010) Makoto Tanabe et al.   ORGANOMETALLICS

Reactivity Studies of N-Heterocyclic Carbene Complexes of Germanium(II)†

(2010) Paul A. Rupar et al.   ORGANOMETALLICS

Transformations of Triphenylgermyl Ligands in Iridium−Ruthenium Carbonyl Cluster Complexes

(2010) Richard D. Adams et al.   ORGANOMETALLICS

Stable Heavier Carbene Analogues

(2009) Yoshiyuki Mizuhata et al.   CHEMICAL REVIEWS

Ruthenium-Based Heterocyclic Carbene-Coordinated Olefin Metathesis Catalysts†

(2009) Georgios C. Vougioukalakis et al.   CHEMICAL REVIEWS

Platinum−Germanium Compounds from the Reactions of (COD)PtMe2(COD = 1,5-cyclooctadiene) with HGePh3

(2009) Richard D. Adams et al.   INORGANIC CHEMISTRY

Photochemical Reaction of Mo(CO)6with Et2GeH2: NMR and DFT Studies of Reaction Products; Crystal Structure of a Novel Complex [{Mo(μ-η2-H−GeEt2)(CO)4}2]

(2009) Magdalena Zyder et al.   ORGANOMETALLICS

Formation and Ring Expansion of Germaplatinacycles via Dehydrogenative Ge−Ge and Ge−Pt Bond-Forming Reactions

(2009) Makoto Tanabe et al.   ORGANOMETALLICS

Syntheses and Ligand Exchange Reaction of Iron(IV) Complexes with Two Different Group 14 Element Ligands, Cp(CO)FeH(EEt3)(E′Et3) (E, E′ = Si, Ge, Sn)

(2009) Masumi Itazaki et al.   ORGANOMETALLICS

Sila- and Germaplatinacycles Produced from a Stepwise E−E Bond Forming Reaction

(2009) Janet Braddock-Wilking et al.   ORGANOMETALLICS

Spectroscopic and Structural Characterization of Copper−Germylene Complexes Bearing an Isopropyl-Substituted β-Diketiminate Ligand

(2009) Hidekazu Arii et al.   ORGANOMETALLICS

Synthesis, Structure, and Reactivity of Neutral Hydrogen-Substituted Ruthenium Silylene and Germylene Complexes

(2009) Paul G. Hayes et al.   ORGANOMETALLICS

E−H Bond Activation Reactions (E = H, C, Si, Ge) at Ruthenium: Terminal Phosphides, Silylenes, and Germylenes

(2009) Ayumi Takaoka et al.   ORGANOMETALLICS

Heterolytic Dihydrogen Activation by a Sulfido- and Oxo-Bridged Dinuclear Germanium–Ruthenium Complex

(2008) Tsuyoshi Matsumoto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of substituted vinylgermanes and germylsilylethenes via ruthenium complex catalyzed germylation of olefins

(2008) Bogdan Marciniec et al.   APPLIED ORGANOMETALLIC CHEMISTRY

Transition Metal Complexes of N-Heterocyclic Germylenes

(2008) Farman Ullah et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

A Functional Hydrogenase Model:  Reversible Interconversion of H2and H2O by a Hydroxo/Sulfido-Bridged Dinuclear Ruthenium−Germanium Complex

(2008) Tsuyoshi Matsumoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation of Hydrogen and Related Small Molecules by the Unsaturated Cluster Complex PtOs3(CO)7(PBut3)(μ-PBut2)(μ4-CHCMeCH)

(2008) Richard D. Adams et al.   ORGANOMETALLICS

Mono- and Dinuclear Germapalladacycles Obtained via the Ge−Ge Bond Forming Reactions Promoted by Palladium Complexes

(2008) Makoto Tanabe et al.   ORGANOMETALLICS

The Chemistry of Aluminum(I), Silicon(II), and Germanium(II)

(2008) Selvarajan Nagendran et al.   ORGANOMETALLICS

Synthesis and Crystal Structures of the First Stable Mononuclear Dihydrogermyl(hydrido) Platinum(II) Complexes

(2008) Norio Nakata et al.   ORGANOMETALLICS