Article
Multidisciplinary Sciences
Houssni Lamkaddam, Josef Dommen, Ananth Ranjithkumar, Hamish Gordon, Gunther Wehrle, Jordan Krechmer, Francesca Majluf, Daniil Salionov, Julia Schmale, Sasa Bjelic, Kenneth S. Carslaw, Imad El Haddad, Urs Baltensperger
Summary: The study reveals that processing isoprene oxidation products in cloud droplets can produce a significant amount of secondary organic aerosol, which may have a substantial impact on the global aerosol burden.
Article
Engineering, Environmental
Ziying Lei, Yuzhi Chen, Yue Zhang, Madeline E. Cooke, Isabel R. Ledsky, N. Cazimir Armstrong, Nicole E. Olson, Zhenfa Zhang, Avram Gold, Jason D. Surratt, Andrew P. Ault
Summary: The study demonstrates that initial aerosol acidity plays a significant role in shaping the physicochemical properties of SOA formed from IEPDX, with higher acidity resulting in more organosulfate formation and a tendency for the organic phase to transition to a semi-solid or solid state. These findings can be used to improve model parameterizations of SOA formation and properties from IEPDX to better align predictions with atmospheric observations.
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2022)
Article
Chemistry, Analytical
Wen Zhang, Haofei Zhang
Summary: Iodide-adduct chemical ionization mass spectrometry (I-CIMS) is widely used in atmospheric chemistry to detect oxygenated volatile organic compounds (OVOCs) in real time. The study reports secondary ion chemistry from interactions between strong oxygen donors and acidic OVOCs in I-CIMS, which can lead to misinterpretations of gas-phase products' compositions and distributions. However, the varying degrees of signal change in response to secondary ion chemistry may provide clues to OVOCs' functionalities.
ANALYTICAL CHEMISTRY
(2021)
Review
Environmental Sciences
Magda Claeys, Willy Maenhaut
Summary: This review covers research on secondary organic aerosol (SOA) formation from isoprene over the past two decades, highlighting the complex pathways and source apportionment. The importance of molecular characterization and mass spectrometric techniques in understanding the formation mechanisms is emphasized. Efforts to distinguish different sources of SOA, including isoprene SOA, using organic marker-based methods and positive matrix factorization are examined.
Article
Environmental Sciences
Linlin Liang, Guenter Engling, Wanyun Xu, Qianli Ma, Weili Lin, Xuyan Liu, Chang Liu, Gen Zhang
Summary: Laboratory experiments suggest acid-catalyzed aqueous-phase production can promote the formation of isoprene SOA, i.e., 2-methyltetrols. In this study, ambient observations and chemical measurements were used to investigate the importance of environmental factors in the formation of isoprene epoxydiols (IEPDX) SOA under atmospheric humidity conditions. The results show that photochemical processes dominate the formation of 2-methyltetrols in humid environments, and aerosol acidity has a limited influence on their formation. Additionally, high liquid water content reduces aerosol droplet acidity, thereby diminishing the enhancement of SOA formation.
Article
Engineering, Environmental
Yixin Li, Jiayun Zhao, Yuan Wang, John H. Seinfeld, Renyi Zhang
Summary: Photooxidation of toluene can lead to the formation of secondary organic aerosol (SOA) and light-absorbing brown carbon (BrC) through a complex series of chemical reactions, involving the production of dicarbonyls and carboxylic functional groups as primary precursors. The study shows that volatile dicarbonyls form nonvolatile oligomers and light-absorbing nitrogen heterocycles/heterochains at high humidity, while organic acids contribute to aerosol carboxylates through ionic dissociation or acid-base reactions over a wide range of humidity levels. These findings highlight the important role of toluene in SOA/BrC formation due to the unique functionalities of dicarbonyls and organic acids in aerosol-phase reactions.
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2021)
Article
Meteorology & Atmospheric Sciences
Christina S. McCluskey, Andrew Gettelman, Charles G. Bardeen, Paul J. DeMott, Kathryn A. Moore, Sonia M. Kreidenweis, Thomas C. J. Hill, Kevin R. Barry, Cynthia H. Twohy, Darin W. Toohey, Bryan Rainwater, Jorgen B. Jensen, John M. Reeves, Simon P. Alexander, Greg M. McFarquhar
Summary: Southern Ocean low-level mixed phase clouds pose a challenge for accurately representing in Earth system models. Simulated clouds in the Community Earth System Model version 2 now have too little ice, while observations show that marine particles are the main contributors to cloud ice nucleation. This study emphasizes the importance of assessing simulated mineral dust properties in order to better represent ice nucleating particle populations in the Southern Ocean.
JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES
(2023)
Article
Environmental Sciences
Dagen D. Hughes, Megan B. Christiansen, Alissa Milani, Michael P. Vermeuel, Gordon A. Novak, Hariprasad D. Alwe, Angela F. Dickens, R. Bradley Pierce, Dylan B. Millet, Timothy H. Bertram, Charles O. Stanier, Elizabeth A. Stone
Summary: The Lake Michigan Ozone Study conducted in 2017 aimed to understand the sources contributing to ozone and fine particles along the Lake Michigan coast. The study found that different weather patterns during high ozone periods affected the regional characteristics of PM2.5. The research also highlighted the importance of anthropogenic sulfate emissions and aerosol acidity on secondary organic aerosol (SOA) formation.
ATMOSPHERIC ENVIRONMENT
(2021)
Article
Environmental Sciences
Long Jia, YongFu Xu, MinZheng Duan
Summary: Aerosol particles have significant effects on local environment and global climate. The mechanism of explosive growth of secondary organic aerosol (SOA) during severe haze events is unclear. Through chamber experiments and kinetic model simulations, this study revealed the microphysical mechanism for explosive organic aerosol formation. The condensation of gas-phase organics and the interaction between aerosol and fog were found to contribute to the explosive growth of SOA. The co-condensation of organic vapors with water should not be overlooked as it can significantly underestimate SOA and liquid water content in 3D models.
SCIENCE OF THE TOTAL ENVIRONMENT
(2023)
Article
Environmental Sciences
Long Jia, YongFu Xu
Summary: The study developed a novel CSVA model to simulate the gas-phase and particle-phase reactions of SOA as well as the evolution of particle size distribution.
SCIENCE OF THE TOTAL ENVIRONMENT
(2021)
Article
Environmental Sciences
Duseong S. Jo, Alma Hodzic, Louisa K. Emmons, Simone Tilmes, Rebecca H. Schwantes, Michael J. Mills, Pedro Campuzano-Jost, Weiwei Hu, Rahul A. Zaveri, Richard C. Easter, Balwinder Singh, Zheng Lu, Christiane Schulz, Johannes Schneider, John E. Shilling, Armin Wisthaler, Jose L. Jimenez
Summary: Secondary organic aerosol (SOA) is a significant contributor to fine particulate matter in the atmosphere, with volatility-based SOA parameterizations showing reasonable performance but potential errors when applied to future climatic conditions. Explicit mechanism predictions suggest variability in isoprene epoxydiols (IEPOX SOA) concentrations across different scenarios, highlighting the importance of capturing key physicochemical drivers for accurate SOA concentration predictions in climate studies.
ATMOSPHERIC CHEMISTRY AND PHYSICS
(2021)
Article
Environmental Sciences
Weiqi Xu, Wei Zhou, Zhijie Li, Qingqing Wang, Aodong Du, Bo You, Lu Qi, Andre S. H. Prevot, Junji Cao, Zifa Wang, Jiang Zhu, Yele Sun
Summary: The reductions in traffic-related emissions and fossil fuel-related organic aerosols during the 2021 Chinese New Year in Beijing were smaller than previous years, while the concentrations of secondary aerosol species increased due to a severe haze episode. The composition of organic aerosols also changed, with an increase in oxidized primary aerosols and a decrease in aqueous-phase secondary aerosols.
ENVIRONMENTAL POLLUTION
(2022)
Article
Engineering, Environmental
Tanguy Demeautis, Alexandra Bouyssi, Annelise Chapalain, Johann Guillemot, Patricia Doublet, Alain Geloen, Christian George, Jean Menotti, Olivier Glehen, Gilles Devouassoux, Abderrazzak Bentaher
Summary: Recently, it was found that chronic exposure to secondary organic aerosols (SOAs) results in lung inflammation and tissue destruction in mice. This study provides the first in vivo evidence showing the pathogenic mechanisms of SOAs, including inflammatory cell recruitment, changes in levels of inflammatory mediators, and increased matrix metalloproteinase proteolytic activity. These findings highlight the importance of further research on SOAs and potential therapeutic strategies against SOA-mediated lung injury.
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2023)
Article
Chemistry, Physical
S. Indira Murugachandran, Jackson Tang, Isabel Pena, Donatella Loru, M. Eugenia Sanz
Summary: Limonene effectively interacts with water to form various complexes, with water preferentially binding to the endocyclic double bond of limonene. These findings enrich our understanding of the interactions of limonene in the atmosphere.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2021)
Article
Green & Sustainable Science & Technology
Li-Ming Cao, Jing Wei, Ling-Yan He, Hui Zeng, Meng-Lin Li, Qiao Zhu, Guang-He Yu, Xiao-Feng Huang
Summary: This study found that in the northern hemisphere winter, the evolution of SOA in aerosols on BC particles may differ from that in the bulk aerosol, with transition metals playing a catalytic role in SOA formation. Additional research is needed to further explore the potential role of BC and transition metals as catalysts for OA aging and the co-benefit of BC and transition metals pollution control in reducing SOA in the atmosphere.
JOURNAL OF CLEANER PRODUCTION
(2022)
Article
Chemistry, Physical
Maria Lbadaoui-Darvas, Giovanni Garberoglio, Katerina S. Karadima, M. Natalia D. S. Cordeiro, Athanasios Nenes, Satoshi Takahama
Summary: This comprehensive review explores methods and applications of molecular simulations of interfacial systems, providing detailed insights into techniques and challenges in solid and fluid surfaces. The review also summarizes methods for estimating macroscopic properties of interfaces and extracting information about fluctuating liquid surfaces, demonstrating their application in atmospheric science, material science, and biophysics. The main goals are to guide practical questions in software, force fields, and select appropriate analysis methods, while highlighting the potential for molecular simulations to advance our understanding in applied science.
MOLECULAR SIMULATION
(2023)
Article
Chemistry, Medicinal
Mohammadamin Tavakoli, Yin Ting T. Chiu, Pierre Baldi, Ann Marie Carlton, David Van Vranken
Summary: We introduce RMechDB, an open-access platform for aggregating, curating, and distributing reliable data about elementary radical reaction steps. RMechDB contains over 5,300 such steps, manually curated from various sources and encoded in the SMIRKS format. It serves as a central platform for accessing and contributing to the knowledge of radical reactions.
JOURNAL OF CHEMICAL INFORMATION AND MODELING
(2023)
Article
Chemistry, Physical
Bo Chen, Jessica A. Mirrielees, Yuzhi Chen, Timothy B. Onasch, Zhenfa Zhang, Avram Gold, Jason D. Surratt, Yue Zhang, Sarah D. Brooks
Summary: We measured the Tg of IEPOX-derived SOA components using broadband dielectric spectroscopy and found that the Tg of mixtures depends on their composition. The Kwei equation provides a good fit for the Tg-composition relationship of complex mixtures. We demonstrate that the non-linear deviation of Tg as a function of composition may be caused by changes in the extent of hydrogen bonding in the mixture using Raman spectroscopy and density functional theory.
JOURNAL OF PHYSICAL CHEMISTRY A
(2023)
Editorial Material
Geochemistry & Geophysics
Fabio Florindo, Valerio Acocella, Ann Marie Carlton, Paolo D'Odorico, Qingyun Duan, Andrew Gettelman, Jasper Halekas, Ruth Harris, Gesine Mollenhauer, Alan Robock, Claudine Stirling, Yusuke Yokoyama
Summary: Reviews of Geophysics is an AGU journal that publishes comprehensive review articles across various disciplines within the Earth and Space Sciences. It is a highly ranked journal in the fields of Geochemistry and Geophysics, with a high Journal Impact Factor (JIF). The journal's review papers provide crucial context for current work, establishing a framework for comprehensive understanding of research progress and interconnections between different communities.
REVIEWS OF GEOPHYSICS
(2023)
Correction
Chemistry, Multidisciplinary
David O. De Haan, Lelia N. Hawkins, Praveen D. Wickremasinghe, Alyssa D. Andretta, Juliette R. Dignum, Audrey C. De Haan, Hannah G. Welsh, Elyse A. Pennington, Tianqu Cui, Jason D. Surratt, Mathieu Cazaunau, Edouard Pangui, Jean-Francois Doussin
ACS EARTH AND SPACE CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
David O. De Haan, Lelia N. Hawkins, Praveen D. Wickremasinghe, Alyssa D. Andretta, Juliette R. Dignum, Audrey C. De Haan, Hannah G. Welsh, Elyse A. Pennington, Tianqu Cui, Jason D. Surratt, Mathieu Cazaunau, Edouard Pangui, Jean-Francois Doussin
Summary: Aqueous-phase dark reactions during the co oxidation of glyoxal and S(IV) were found to be a potential source of brown carbon (BrC), which occurs more slowly in sunlit, sulfite containing solutions. Detectable amounts of BrC in aerosol require an OH radical source and occur most rapidly after a cloud event. Radical-initiated reactions and redox mechanisms play a role in this process. However, the BrC produced is about ten times less light-absorbing than wood smoke BrC at 365 nm.
ACS EARTH AND SPACE CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
Jie Zhang, Manish Shrivastava, Alla Zelenyuk, Rahul A. Zaveri, Jason D. Surratt, Matthieu Riva, David Bell, Marianne Glasius
Summary: This study investigates the key parameters governing the formation of isoprene epoxydiol-derived secondary organic aerosol (IEPOX-SOA). The results show that reducing the reaction rate constants of 2-methyltetrol (tetrol) can bring the model predictions in agreement with experimental measurements of IEPOX-SOA under acidified aerosol conditions. Additionally, both the organosulfate (OS) and tetrol reaction rate constants need to be reduced for nonacidified aerosols to match the chamber observations. The study also reveals that the aerosol acidity significantly affects the oligomerization rate of tetrols.
ACS EARTH AND SPACE CHEMISTRY
(2023)
Article
Multidisciplinary Sciences
Kristen M. Foleya, George A. Pouliota, Alison Eytha, Michael F. Aldridge, Christine Allen, K. Wyat Appel, Jesse O. Basha, Megan Beardsleya, James Beidlerb, David Choia, Caroline Farkas, Robert C. Gilliam, Janice Godfrey, Barron H. Henderson, Christian Hogrefe, Shannon N. Koplitza, Rich Masona, Rohit Mathura, Chris Misenisa, Norm Possiela, Havala O. T. Pye, Lara Reynolds, Matthew Roark, Sarah Roberts, Donna B. Schwedea, Karl M. Seltzera, Darrell Sonntaga, Kevin Talgob, Claudia Toro, Jeff Vukovicha, Jia Xingc, Elizabeth Adamsd
Summary: The US EPA has developed annual North American emissions data for air pollutants across 18 source categories from 2002 to 2017. These data are intended to support regional air quality modeling for a variety of applications. This dataset is part of the EPA's Air Quality Time Series Project.
Article
Engineering, Environmental
Clara M. A. Eichler, Naomi Y. Chang, Elaine A. Cohen Hubal, Daniel E. Amparo, Jiaqi Zhou, Jason D. Surratt, Glenn C. Morrison, Barbara J. Turpin
Summary: During the Indoor PFAS Assessment (IPA) Campaign, concentrations of nine neutral PFAS were measured in air and cotton cloth in 11 homes in North Carolina. The study found that fluorotelomer alcohols were the dominant species in indoor air, while perfluorooctane sulfonamidoethanols accumulated most significantly in cloth. Cloth-air partition coefficients were derived for different PFAS and were positively correlated with the octanol-air partition coefficient. Temperature was found to have the greatest effect on PFAS accumulation.
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2023)
Article
Geosciences, Multidisciplinary
Christine Wiedinmyer, Yosuke Kimura, Elena C. McDonald-Buller, Louisa K. Emmons, Rebecca R. Buchholz, Wenfu Tang, Keenan Seto, Maxwell B. Joseph, Kelley C. Barsanti, Annmarie G. Carlton, Robert Yokelson
Summary: We introduce FINNv2.5, a fire emissions inventory that provides publicly available emissions of trace gases and aerosols for various applications, including global and regional atmospheric chemistry modeling. FINNv2.5 includes updates to better represent burned area, vegetation burned, and chemicals emitted, and utilizes active fire detections from VIIRS for smaller fires. It also improves the calculation of burned area and updates fuel characterization and emissions factors. The daily emissions for trace gases and aerosols are determined for different time periods using MODIS and MODIS+VIIRS fire detections.
GEOSCIENTIFIC MODEL DEVELOPMENT
(2023)
Article
Chemistry, Analytical
Marc Webb, Liyong Cui, Glenn Morrison, Karsten Baumann, Jason D. Surratt, Zhenfa Zhang, Joanna Atkin, Barbara J. Turpin
Summary: Humidity affects the removal and concentrations of indoor pollutants, especially in humid homes. Research on a model organic peroxide showed that the relative humidity has a greater effect on the removal rate and reaction probability on soiled surfaces compared to clean surfaces. These findings are important for predicting indoor concentrations of organic peroxides.
ENVIRONMENTAL SCIENCE-PROCESSES & IMPACTS
(2023)
Article
Environmental Sciences
Havala O. T. Pye, Bryan K. Place, Benjamin N. Murphy, Karl M. Seltzer, Emma L. D'Ambro, Christine Allen, Ivan R. Piletic, Sara Farrell, Rebecca H. Schwantes, Matthew M. Coggon, Emily Saunders, Lu Xu, Golam Sarwar, William T. Hutzell, Kristen M. Foley, George Pouliot, Jesse Bash, William R. Stockwell
Summary: Chemical mechanisms are used to describe how organic and inorganic species in the atmosphere transform and how they contribute to the formation of secondary species such as ozone, fine particles, and hazardous air pollutants. This study introduces the Community Regional Atmospheric Chemistry Multiphase Mechanism (CRACMM) version 1.0, which includes several new species and reactions to better represent atmospheric chemistry processes. The CRACMMv1.0 model provides a comprehensive understanding of the formation of ozone, secondary organic aerosol, and hazardous air pollutants.
ATMOSPHERIC CHEMISTRY AND PHYSICS
(2023)
Article
Geosciences, Multidisciplinary
Forwood Wiser, Bryan K. Place, Siddhartha Sen, Havala O. T. Pye, Benjamin Yang, Daniel M. Westervelt, Daven K. Henze, Arlene M. Fiore, V. Faye McNeill
Summary: Previous studies on the mechanism of isoprene oxidation have included numerous species and reactions, making it computationally expensive for large-scale atmospheric models. This study developed a reduced isoprene oxidation mechanism using an automated model reduction approach. The reduced mechanism accurately predicted the changes in oxidation products in a smaller-scale model. When applied to a larger atmospheric model, the reduced mechanism significantly improved the agreement with observed data.
GEOSCIENTIFIC MODEL DEVELOPMENT
(2023)
Article
Chemistry, Medicinal
Mohammadamin Tavakoli, Yin Ting T. Chiu, Pierre Baldi, Ann Marie Carlton, David Van Vranken
Summary: We present RMechDB, an accessible platform that gathers, organizes, and distributes trustworthy data on elementary radical reactions for computational modeling and prediction. RMechDB includes more than 5,300 elementary radical reaction steps, each featuring a single transition state occurring around room temperature. These reaction steps are manually curated and represent plausible arrow-pushing steps for organic radical reactions. The database incorporates steps from various sources, with over 2,000 steps extracted from textbooks and/or synthesized from research publications, while another 3,000 are sourced from atmospheric reactions involving isoprene and other organic compounds on the MCM website. Reactions are encoded in the SMIRKS format, ensuring accurate atom mapping and arrow-pushing mechanism annotations. RMechDB comprises a database schema with an interactive online search interface and a request portal for downloading the raw form of elementary step reactions along with their metadata. It also provides an interface for submitting new reactions to RMechDB and expanding the dataset through community contributions. Primarily designed as a centralized platform for radical elementary steps, RMechDB offers open access to this data and platform to facilitate the extension of data-driven models for chemical reaction predictions and other chemoinformatics predictive tasks.
JOURNAL OF CHEMICAL INFORMATION AND MODELING
(2023)
Article
Meteorology & Atmospheric Sciences
Virendra P. Ghate, Thomas Surleta, Leehi Magaritz-Ronen, Shira Raveh-Rubin, Francesca Gallo, Annmarie G. Carlton, Eduardo B. Azevedo
Summary: This study analyzed seven years of data from the Atmospheric Radiation Measurement's Eastern North Atlantic (ENA) site to understand the factors controlling Cloud Condensation Nuclei (CCN) concentrations in the region. The results showed that aerosol observations were influenced by local emissions, and CCN concentrations were higher in the summer months compared to winter months. Advection and precipitation scavenging were found to be the main factors modulating CCN concentrations on monthly timescales, with rain rates playing a role in precipitation scavenging. Low CCN events were associated with thicker clouds, stronger rain rates, and lower aerosol concentrations in the free troposphere.
JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES
(2023)