4.5 Article

The role of chloride ions in rapid synthesis of ultra-long silver nanowires for flexible electrodes

Journal

MATERIALS RESEARCH EXPRESS
Volume 3, Issue 7, Pages -

Publisher

IOP PUBLISHING LTD
DOI: 10.1088/2053-1591/3/7/075007

Keywords

silver nanowires; polyol method; shape-controlled synthesis; transparent electrodes

Funding

  1. National Natural Science Foundation of China [51522503]
  2. Program for New Century Excellent Talents in University [NCET-13-0175]

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Ultra-long silver nanowires (AgNWs) could be an ideal material to replace the commercial used indium tin oxide in highly conductive and transparent electrodes field. In this report, AgNWs with mean length of 102 mu m and even 268 mu m have been synthesized through a rapid and one-step polyol method within only 40 min. The effective synthesis was contributed to the relatively high concentration of Cl- which facilitated the generation of silver five-twined seeds by heterogeneous nucleation during the nucleation process. By varying the ratio of Cl-, AgNWs with various diameters ranging from 60 to 141 nm could be obtained. Moreover, AgNWs based electrodes were prepared on paper and polyethylene terephthalate (PET) substrates and the sheet resistance of the PET based transparent electrode were measured to be 14 Omega sq(-1) at optical transmittance of 87%. The mechanical properties of the ultra-long AgNWs based electrodes were also characterized.

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