Article
Green & Sustainable Science & Technology
Philipp Brandt, Alexander Nuhnen, Secil Ozturk, Gulin Kurt, Jun Liang, Christoph Janiak
Summary: The search for adsorbents for flue gas desulfurization processes is a current interest. The experimental study found that microporous materials with pore sizes in the range of 4-8 angstrom or with nitrogen heterocycles are optimal for SO2 uptake in the low-pressure range. Zeolite Y and SAPO-34 were found to be stable toward humid SO2, and Zeolite Y and CTF-1(600) showed the most promising SO2/CO2 selectivity results.
ADVANCED SUSTAINABLE SYSTEMS
(2021)
Review
Chemistry, Multidisciplinary
Yaqi Wu, Bert M. Weckhuysen
Summary: This Minireview focuses on the developments of the adsorptive separation of methane/nitrogen, ethene/ethane, propene/propane mixtures as well as on the separation of C-8 aromatics with various materials. The advantages and disadvantages of each material category are discussed, and guidelines for the design of improved materials are proposed. Furthermore, challenges and future developments of each material type and separation processes are discussed.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Multidisciplinary Sciences
Yan Su, Ken-ichi Otake, Jia-Jia Zheng, Satoshi Horike, Susumu Kitagawa, Cheng Gu
Summary: Efficient separation of water isotopologues at room temperature has been achieved by constructing porous coordination polymers with flip-flop molecular motions to regulate the diffusion rates of water isotopologues. This method shows promise for high-performance vapor separation.
Review
Engineering, Chemical
Taofeeqah A. Agbaje, Lourdes F. Vega, Maryam Khaleel, Kean Wang, Georgios N. Karanikolos
Summary: C4 hydrocarbons are important fractions in the oil and gas processing industry, and traditional methods for their separation face challenges. Therefore, new technologies such as membranes and adsorption are being actively explored as efficient, economical, and energy-saving alternatives for the separation of C4 hydrocarbons.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)
Article
Energy & Fuels
Tingyan Lu, Jiali Bai, Jiamei Huang, Qiyun Yu, Muslum Demir, Murat Kilic, Bilge Nazli Altay, Linlin Wang, Xin Hu
Summary: This study introduces a self-activating synthesis method for fabricating self-S-doped porous carbon adsorbents. The activating temperature was found to control the textural and elemental compositions of the prepared carbons, with the optimal S-doped porous carbon exhibiting good CO2 uptake capacities and stability.
Review
Chemistry, Multidisciplinary
Wen-Gang Cui, Tong-Liang Hu
Summary: The design and development of efficient catalytic materials with synergistic catalytic sites, such as crystalline porous materials (CPMs), have been a focus of recent research due to their essential role in enhancing catalytic activity and selectivity. By incorporating guest species in CPMs, synergistic effects can be achieved between different components, leading to improved performance in catalytic processes.
Article
Energy & Fuels
Tingyan Lu, Jiali Bai, Jiamei Huang, Qiyun Yu, Muslum Demir, Murat Kilic, Bilge Nazli Altay, Linlin Wang, Xin Hu
Summary: A self-activating synthesis approach has been developed to fabricate self-S-doped porous carbon with excellent CO2 uptake capacities. The activating temperatures can control the textural and elemental compositions of the carbons. The resulting NDS-derived self-S-doped porous carbons exhibit desirable CO2 adsorption properties and can be synthesized from various organic precursors.
Review
Chemistry, Multidisciplinary
Kayode A. Adegoke, Kabir O. Oyedotun, Joshua. O. Ighalo, James F. Amaku, Chijioke Olisah, Adedapo O. Adeola, Kingsley O. Iwuozor, Kovo G. Akpomie, Jeanet Conradie
Summary: This study presents recent advancements in cellulose and cellulose-MOFs (CelluMOFs) for CO2 adsorption and separation, discussing different cellulose materials, membranes, and preparation methods. The study also highlights the potential of cellulose-MOF materials as a new generation of materials for CO2 adsorption and separation.
JOURNAL OF CO2 UTILIZATION
(2022)
Review
Polymer Science
Jun-Feng Feng, Min Tan, Sheng Zhang, Bang-Jing Li
Summary: Porous materials have been increasingly used in various fields, with cyclodextrins being suitable building units due to their nanoporous structure, ease of modification, and biocompatibility. This review focuses on the recent progress in the fabrication and applications of CD-based porous materials, including CD-MOFs, CD-COFs, and hybrid porous materials.
MACROMOLECULAR RAPID COMMUNICATIONS
(2021)
Review
Materials Science, Multidisciplinary
Kaiwen Xue, Yan Mo, Baojun Long, Wen Wei, Changsheng Shan, Shaojun Guo, Li Niu
Summary: Single-atom catalysts (SACs) have drawn extensive attention due to their high catalytic activity and selectivity, high utilization of metal atoms, and cost reduction. Ordered porous materials (OPMs) serve as promising carriers for stabilizing single atoms by tuning their geometric and electronic structures through interactions, enhancing the catalytic activity. The development of SACs based on OPMs such as zeolites, metal-organic frameworks, and ordered mesoporous materials has been rapidly advancing, providing opportunities and challenges for developing novel catalysts with superior catalytic performances in the future.
Article
Chemistry, Multidisciplinary
Soochan Lee, Dongsik Nam, David ChangMo Yang, Wonyoung Choe
Summary: This study efficiently identifies synthesizable candidate topologies for zeolitic imidazolate frameworks (ZIFs) from a zeolite database containing over 2,000,000 hypothetical structures, using structural descriptors extracted from known ZIFs. Intuition-based structural descriptors, such as ring patterns, node numbers, and T-O-T bridging angles, are used as data filters to eliminate infeasible topologies for ZIF formation. The carefully chosen structural descriptors facilitate the prediction of plausible ZIF topologies. Hydrogen adsorption screening is performed to investigate potential applications as porous ZIFs, leading to the suggestion of notable target ZIFs. The collection of new plausible ZIFs, derived from the combined descriptors, will serve as a structural blueprint for synthetic chemists.
Review
Chemistry, Multidisciplinary
Rongchao Shi, Xiao Han, Jialiang Xu, Xian-He Bu
Summary: Crystalline porous materials have been extensively explored for various applications in nonlinear optics, due to their structural diversity and flexibility in organizing dipolar chromophores. Recent advances in the field have focused on second-order NLO in chiral and achiral structures, as well as third-order NLO in pure organic and hybrid organic/inorganic materials. The future challenges and research directions of these materials have also been proposed.
Article
Engineering, Chemical
Donglai Mao, John M. Griffin, Richard Dawson, Alasdair Fairhurst, Gaurav Gupta, Nuno Bimbo
Summary: This review compares the performance of commonly-studied porous materials used for adsorption at low temperatures, considering test conditions and identifying high performing materials for future research directions.
SEPARATION AND PURIFICATION TECHNOLOGY
(2021)
Article
Chemistry, Multidisciplinary
Xiaoying Lin, Weipeng Zeng, Yilan Chen, Ting Su, Qinhua Zhong, Linzhu Gong, Yamin Liu
Summary: A porous carbon material UiO-66-C was synthesized by carbonization of metal-organic frameworks UiO-66 under inert gas atmosphere. The physicochemical properties and adsorption performance of UiO-66-C were well characterized. The results showed that UiO-66-C exhibited high specific surface area and excellent adsorption capacity for tetracycline.
Article
Nanoscience & Nanotechnology
Kaifei Chen, Ranjeet Singh, Jining Guo, Yalou Guo, Ali Zavabeti, Qinfen Gu, Randall Q. Snurr, Paul A. Webley, Gang Kevin Li
Summary: This study demonstrates for the first time that gas adsorption in microporous materials can be regulated by a moderate external electric field, providing a new method for controlling gas adsorption.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Polymer Science
Mustafa Abu Ghalia, Yaser Dahman
JOURNAL OF POLYMER RESEARCH
(2015)
Article
Biochemistry & Molecular Biology
Mustafa Abu Ghalia, Yaser Dahman
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2017)
Review
Polymer Science
Mustafa Abu Ghalia, Yaser Dahman
JOURNAL OF POLYMER RESEARCH
(2017)
Article
Engineering, Environmental
Mustafa Abu Ghalia, Yaser Dahman
JOURNAL OF POLYMERS AND THE ENVIRONMENT
(2018)
Article
Materials Science, Characterization & Testing
Mustafa Abu Ghalia, Yaser Dahman
Article
Polymer Science
Mustafa Abu Ghalia, Azman Hassan, Abdirahman Yussuf
JOURNAL OF APPLIED POLYMER SCIENCE
(2011)
Review
Biotechnology & Applied Microbiology
Atika Alhanish, Mustafa Abu Ghalia
Summary: The demand for biobased materials in the bioplastic industry is growing substantially due to increasing awareness of health and environmental concerns. Biobased plasticizers are considered essential additives to boost biobased packaging applications, and the replacement of synthetic plasticizers by biobased counterparts is a growing trend.
BIOTECHNOLOGY PROGRESS
(2021)
Article
Engineering, Biomedical
Mustafa Abu Ghalia, Atika Alhanish
Summary: This study investigates the design and development of a new class of biomaterials, specifically polymer scaffolds, for biomedical applications. The incorporation of cellulose nanofibers (CNF) into the polymer contributes to improved mechanical properties, controlled pore structure, and enhanced biodegradability. The findings highlight the optimal parameters for CNF content, pore size, and porosity in order to achieve desired properties for tissue repair and regeneration.
MEDICAL ENGINEERING & PHYSICS
(2023)