Journal
JOURNAL OF MATERIALS CHEMISTRY B
Volume 4, Issue 38, Pages 6316-6325Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6tb01881e
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Funding
- Top Hundred Talents Program'' of Chinese Academy of Sciences (CAS)
- National Natural Science Foundation of China [41476068]
- National Natural Science Foundation of China-Shandong Joint Funded Project [U1406403]
- Qingdao Talent [13-CX-20]
- Taishan Scholar Program
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In this paper, CeVO4 materials were developed as highly efficient biomimetic catalysts for the first time to detect H2O2. These CeVO4 materials were prepared by a facile hydrothermal method with the assistance of EDTA, exhibiting different morphologies, surface properties, and distinct peroxidase mimetic activities. Among them, CeVO4-2 nanorods (NRs) were proved to display the best intrinsic peroxidase-like property compared to other CeVO4 samples due to their more negative potential and larger BET specific surface area, which could efficiently catalyze the oxidation of 3,3',5,5'-tetramethylbenzidine (TMB) in the presence of H2O2 to generate a blue oxide. Based on the excellent peroxidase mimetic catalytic activity of CeVO4-2 NRs, a simple, convenient and visual H2O2 detection system was successfully established. The detection limit of H2O2 could reach as low as 0.07 mu M. Moreover, the CeVO4-2 NR-based assay system presented an excellent selectivity, practicability, long-term stability, and reusability. The peroxidase-like catalytic mechanism of CeVO4-2 NRs was proposed on the basis of active species trapping experiments. This work provides a novel, convenient, rapid, and ultrasensitive system for the colorimetric detection of H2O2, which has a bright prospect in H2O2 detection and biomedical analysis.
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