Article
Multidisciplinary Sciences
Fangyun Lu, Huiliu Wang, Mengqi Zeng, Lei Fu
Summary: This article provides an overview of the structures, properties, and synthesis strategies of ultrathin III-V semiconductors, with a focus on space confinement, atomic substitution, adhesion energy regulation, and epitaxial growth. The current challenges and future development directions of ultrathin III-V semiconductors are also summarized.
Article
Chemistry, Analytical
Peng Lei, Ying Zhou, Ruiqi Zhu, Chuan Dong, Si Wu, Shaomin Shuang
Summary: The ultrathin Ni6MnO8@C nanosheets were developed as a non-enzymatic electrochemical sensor nanomaterial for epinephrine detection, with excellent electrocatalytic activity and adsorption capabilities. The prepared electrode showed promising linear calibration range and low detection limit in electrolyte, suggesting potential application in clinical disease diagnosis.
SENSORS AND ACTUATORS B-CHEMICAL
(2021)
Article
Chemistry, Physical
Zhuan Wang, Bo Yang, Xueying Zhao, Yushuai Chen, Dandi Wei, Lijuan Zhang, Xintai Su
Summary: This study successfully prepared ultrathin γ-Fe2O3 nanosheets with excellent photocatalytic OER activity and good cycling stability. The outstanding performance of this material is attributed to its ultrathin porous structure, appropriately narrow bandgap, and abundant oxygen vacancies.
APPLIED SURFACE SCIENCE
(2022)
Article
Chemistry, Multidisciplinary
Saba Latif, Bilal Akram, Chaudry Sajed Saraj, Bilal Ahmad Khan, Mudussar Ali, Javeed Akhtar
Summary: Two-dimensional mixed oxide ZnO-Fe2O3 dendritic nanosheets were successfully fabricated using a new low temperature single step and single pot wet chemical approach. Control experiments showed that precursor salts of both the metals were crucial for the formation of stable nanosheets. The obtained nanosheets exhibited the best photoreduction performance and greatly enhanced electrocatalytic performance, providing a promising avenue for the synthesis of cost effective transition metal mixed oxide based 2D nanosheets with wide ranging applications.
Article
Chemistry, Physical
Xianzeng Li, Tingyu Lu, Huan Pang, Mingyi Zhang, Dongdong Xu, Lin Xu, Min Han, Jun Yang
Summary: Highly curved and ultrathin PdNiRu nanosheets were developed and exhibited excellent electrocatalytic performance towards ORR and EGOR. The nanosheets showed enhanced specific/mass activities and better stability/durability compared to control electrocatalysts. This study contributes to the development of multi-functional electrocatalysts for practical fuel cells.
Article
Chemistry, Multidisciplinary
Yuqiao Wang, Chuanyong Jian, Wenting Hong, Wei Liu
Summary: A new scalable strategy for synthesizing nonlayered ultrathin two-dimensional molybdenum nitride on a SiO2/Si substrate has been reported. The edge of MoN demonstrates higher performance in both acidic and alkaline solutions compared to the basal plane.
CHEMICAL COMMUNICATIONS
(2021)
Article
Chemistry, Multidisciplinary
Yanrong Xue, Mengyuan Liu, Yangyuanxiang Qin, Yufeng Zhang, Xuejiang Zhang, Jinjie Fang, Xu Zhang, Wei Zhu, Zhongbin Zhuang
Summary: This study reports an efficient 2-dimensional oxygen evolution reaction (OER) catalyst consisting of ultrathin nickel-iron sulfide nanosheets. The catalyst shows high OER catalytic activity in alkaline electrolyte, requiring only a small overpotential to achieve high OER current density, and exhibits almost no decay after long-term testing. The high performance is attributed to the 2-dimensional structure, synergistic effect from the nickel and iron components, and tuning effect from in-situ generated sulfate doping.
CHINESE CHEMICAL LETTERS
(2022)
Article
Chemistry, Inorganic & Nuclear
Lihua Yao, Zhuo Qiu, Xingliang Yin, Ying Yang, Xiaodi Hong, Zhi Yang
Summary: Designing efficient non-precious electrocatalysts for water splitting is a challenging objective. In this study, single-phase Ni5P4 ultrathin porous nanosheets grown on Ni foam were assembled using a simple hydrothermal and phosphating process. The 3D SHF-Ni5P4 exhibited outstanding performance in the oxygen evolution reaction (OER) and the hydrogen evolution reaction (HER), achieving low overpotentials and Tafel slopes. The overall water separation setup using 3D SHF-Ni5P4 surpassed the performance of commercial Pt C/NF||RuO2/NF.
DALTON TRANSACTIONS
(2023)
Article
Environmental Sciences
Zekun Zhao, Suqin Li, Yabin Zhang, Penghui Guo, Xin Zhao, Yongkui Li
Summary: In this study, cost-effective and highly adsorbent α-Fe2O3 nanoparticles were prepared from steel rolling sludge (SRS) and used for treating As(III/V)-containing wastewater. The prepared nanoparticles exhibited a spherical structure with a small crystal size and high specific surface area. The adsorption results showed that the adsorbent effectively removed arsenic over a wide pH range, with optimal performance observed at pH 4.0-9.0 for As(III) and pH 2.0-4.0 for As(V). The adsorption process followed pseudo-second-order kinetic and Langmuir isothermal model. The resource utilization of SRS and the treatment of As(III)/(V)-containing wastewater in this study align well with the current developments in environmental and waste-to-value research.
JOURNAL OF ENVIRONMENTAL MANAGEMENT
(2023)
Article
Chemistry, Inorganic & Nuclear
Jinwu Hu, Caihong Fang, Xiaomin Jiang, Deliang Zhang, Zhiqing Cui
Summary: We successfully synthesized two-dimensional PtPdCu nanostructures with different morphologies, which exhibited excellent electrocatalytic performances for alcohol oxidation reactions. These nanoalloys showed significantly higher activity compared to commercial Pt/C catalysts, and demonstrated excellent performance and stability for the oxidation of other alcohol molecules.
INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Physical
Lisan Cui, Chunlei Tan, Yu Li, Qichang Pan, Lixuan Zhang, Man Zhang, Zilu Chen, Fenghua Zheng, Hongqiang Wang, Qingyu Li
Summary: A novel sodium ion battery anode material composed of ultrathin MoS2/C nanosheets and hollow Fe2O3 nanorods has been designed and reported, showing excellent electrochemical performance with high stability and good rate capability. The synergic effects of Fe2O3 nanorods and MoS2/C nanosheets contribute to the avoidance of volume change during the sodiation/desodiation process, leading to high sodium storage capacity and stable cyclability.
ACS APPLIED ENERGY MATERIALS
(2021)
Article
Environmental Sciences
R. Ramprasath, L. Arul Pragasan, V. Manikandan, S. Sudha, S. Cholan, Abdullah A. Alarfaj, Abdurahman Hajinur Hirad, B. Gokul, Sridhar Sampath
Summary: Vanadium-doped alpha-Fe2O3 nanoparticles were prepared through polyol-assisted hydrothermal method and the impact on their structure, optical, magnetic, and photocatalytic properties were studied. The results show that 5% V-doped alpha-Fe2O3 nanoparticles exhibit superior photocatalytic activity.
Article
Energy & Fuels
Monalisa Ghosh, Pavel Bulkin, Francois Silva, Erik Johnson, Ileana Florea, Daniel Funes-Hernando, Alexandre Tanguy, Charles Renard, Nicolas Vaissiere, Jean Decobert, Ivan Garcia, Ignacio Rey-Stolle, Pere Roca Cabarrocas
Summary: This study demonstrates a low-cost approach to tandem solar cells by depositing ultrathin epitaxial films of germanium on silicon wafers as virtual substrates for the growth of III-V materials. The optimized plasma-enhanced chemical vapor deposition process allows for direct growth of germanium films on silicon wafers, which can withstand high-temperature annealing. III-V layers deposited on the virtual substrates exhibit comparable properties to those deposited on silicon wafers.
SOLAR ENERGY MATERIALS AND SOLAR CELLS
(2022)
Article
Chemistry, Physical
Yunhua Song, Yang Yang, Shudi Mo, Donggang Guo, Lu Liu
Summary: This study synthesized a novel (Fe2O3)(0.36)@Ni-MOF heterostructure nanosheets as an efficient OER catalyst, showing excellent catalytic performance with low overpotential, fast reaction rate, and stable activity in long-term tests. The work provides a new strategy for preparing heterostructure catalysts with good OER catalytic performance.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Nanoscience & Nanotechnology
Jianli Tang, Chunqiao Jin, Liuxiang Huo, Shenyu Du, Xionghu Xu, Yuting Yan, Kai Jiang, Liyan Shang, Jinzhong Zhang, Yawei Li, Zhigao Hu, Junhao Chu
Summary: Fe-ReS2 electrocatalyst was prepared to trap intermediates and accelerate sulfur reduction reaction kinetics. It significantly reduces the activation energy and optimizes the adsorption strength of polysulfides, resulting in a highly reversible discharge capacity and low capacity fade rate.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Review
Instruments & Instrumentation
Qingsheng Bai, Yongguang Yin, Yanwanjing Liu, Haowen Jiang, Mengxin Wu, Weidong Wang, Zhiqiang Tan, Jingfu Liu, Myeong Hee Moon, Baoshan Xing
Summary: Due to the increased applications of engineered elemental metal nanoparticles (EMNPs) in recent years, their release into the environment has gained attention. The on-line coupling of flow field-flow fractionation with inductively coupled plasma mass spectrometry (F4-ICPMS) has been well established for the characterization of EMNPs in complex matrices of environmental samples. This review focuses on the specific advantages of the F4 method and recent advances in the application of F4-ICPMS techniques in examining the occurrence and transformation of EMNPs in the environment.
APPLIED SPECTROSCOPY REVIEWS
(2023)
Article
Environmental Sciences
Li Li, Su-Juan Yu, Rong-Gang Zheng, Peng Li, Qing-Cun Li, Jing-Fu Liu
Summary: The synthesized nanocomposite Ag-D201 showed high efficiency in removing iodide from water, and its adsorption capacity was influenced by pH and water matrix. The synergistic mechanism for iodide adsorption by Ag-D201 was proposed, including the Donnan membrane effect caused by D201 resin, chemisorption of iodide by AgNPs, and catalytic effect of AgNPs.
JOURNAL OF ENVIRONMENTAL SCIENCES
(2023)
Article
Environmental Sciences
Ruohua Qu, Mi Chen, Jingfu Liu, Qiting Xie, Na Liu, Fei Ge
Summary: Studies have shown that silver nanoparticles (AgNPs) have a negative impact on ATP generation of aquatic organisms, leading to decreased ATP content and metabolic disturbances. AgNPs compete with adenosine diphosphate and inorganic phosphate for binding sites on chloroplast ATPase, reducing substrate binding efficiency. Additionally, AgNPs significantly inhibit multiple ATP-related metabolic pathways. These findings are of great significance for understanding the mechanism of energy supply and metabolic regulation in aquatic organisms under nanoparticle stress.
JOURNAL OF ENVIRONMENTAL SCIENCES
(2023)
Article
Environmental Sciences
Sujuan Yu, Hao Liu, Rui Yang, Wenjing Zhou, Jingfu Liu
Summary: This study systematically investigated the aggregation and stability of selenium nanoparticles (SeNPs) under various water conditions using alginate-coated SeNPs (Alg-SeNPs) and polyvinyl alcohol-coated SeNPs (PVA-SeNPs) as models. The results showed that Alg-SeNPs underwent apparent aggregation in the presence of calcium and lanthanum ions, while PVA-SeNPs remained highly stable. Natural organic matter enhanced the stability of Alg-SeNPs in monovalent electrolytes but accelerated their attachment in polyvalent electrolytes. The long-term stability experiments demonstrated that both Alg-SeNPs and PVA-SeNPs increased in aggregation size over time, indicating their potential suspension or settling in water.
JOURNAL OF ENVIRONMENTAL SCIENCES
(2023)
Review
Energy & Fuels
Fengyu Zhang, Yunna Guo, Liqiang Zhang, Peng Jia, Xiang Liu, Ping Qiu, Hongbing Zhang, Jianyu Huang
Summary: As the most promising next-generation energy storage system, all-solid-state batteries (ASSBs) have the advantages of high theoretical energy density and intrinsic safety. However, the limitation of the solid-solid contact between the electrode and the solid electrolytes (SEs) severely hinders the interfacial charge transport. Studies have shown that the introduction of external pressure can effectively reduce the solid-solid contact resistance and prolong the cycle life of the battery.
Article
Engineering, Environmental
Qingsheng Bai, Qingcun Li, Jingfu Liu
Summary: We developed an effective method for determining the particle number, size, and species of dominant AgCNPs in soils. AgCNPs were extracted efficiently from soils using ultrasonication wand-assisted tetrasodium pyrophosphate extraction. Multistep selective dissolution of Ag NPs, AgCl NPs, and whole Ag NPs/AgCl NPs/Ag2S NPs was achieved by different reagents. The concentrations and sizes of AgCNPs in the extracts were determined, and Ag2S NPs were found to be the main form of AgCNPs in the soils.
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2023)
Article
Chemistry, Physical
Xiaoyu Zhao, Wei Ran, Zixuan Wang, Jiefang Sun, Rui Liu, Jingfu Liu
Summary: This article investigated the structural transformation of Pd shells on Au nanocubes in different electrolytes at various electrochemical windows. It was found that Pd sites are stable under basic and neutral conditions but experience severe structure evolution under acidic conditions. Pd atoms react with H+ under acidic conditions to form Pd ions, which are easily coreduced with Au ions into surface alloys.
JOURNAL OF PHYSICAL CHEMISTRY C
(2023)
Article
Chemistry, Physical
Lun Zhang, Xuedong Zhang, Zhaoyu Rong, Tao Wang, Zhenyu Wang, Zaifa Wang, Longchen Zhang, Qiao Huang, Lingyun Zhu, Liqiang Zhang, Yongfu Tang, Jianyu Huang
Summary: Sulfide electrolyte-based all-solid-state batteries (ASSBs) are explored for their low temperature (LT) performance, with a focus on LiNi0.8Co0.1Mn0.1O2 (NCM811)|Li9.54Si1.74P1.44S11.7Cl0.3 (LiSPSCl)|Li4Ti5O12 (LTO) ASSBs. Charging the ASSB to 6 V at -40 degrees C resulted in a higher capacity of 100.7 mAh center dot g(-1) at 20 mA center dot g(-1) compared to charging to 4.3 V (-40 degrees C, 4.6 mAh center dot g-1). Thinner electrolytes are found to be favorable for LT operation due to reduced ion transfer distance. This study provides new strategies for boosting the capacity and energy density of sulfide-based ASSBs at LT for dedicated applications.
Article
Chemistry, Multidisciplinary
Guobao Xu, Zhihao Yan, Hengyu Yang, Xuedong Zhang, Yong Su, Zhikai Huang, Liqiang Zhang, Yongfu Tang, Zhenyu Wang, Lingyun Zhu, Jianguo Lin, Liwen Yang, Jianyu Huang
Summary: This study reports a multiscale structural engineering of sulfur/carbon composites, where ultrasmall sulfur nanocrystals are homogeneously anchored on the two sides of graphene layers with strong S-C bonds. The fabricated S@EG-LSPSCL cathode, mixed with LSPSCL solid electrolytes, exhibits enhanced electrochemical reactivity, charge transport, and chemomechanical stability. The assembled InLi/LSPSCL/S@EG-LSPSCL all-solid-state lithium-sulfur batteries demonstrate ultralong cycling stability and high capacities, making it a promising candidate for energy storage applications.
Article
Engineering, Environmental
Peng Li, Yujian Lai, Rong-gang Zheng, Qing-cun Li, Xueying Sheng, Sujuan Yu, Zhineng Hao, Ya-qi Cai, Jingfu Liu
Summary: A novel method combining TMAH digestion and DCM dissolution has been developed to extract small microplastics and nanoplastics embedded in soils, sediments, and sludges. The feasibility of this method has been verified and it shows promise for evaluating small solid-embedded microplastic and nanoplastic pollution.
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2023)
Article
Engineering, Environmental
Xue-ying Sheng, Yu-jian Lai, Su-juan Yu, Qing-cun Li, Qing-xiang Zhou, Jing-fu Liu
Summary: Plastic has been shown to release nanoparticles (NPs) into the atmosphere when exposed to sunlight, which poses a continuous health risk to the respiratory system. This study presents a simple and reliable method for quantifying atmospheric polystyrene (PS) NPs using pyrolysis-gas chromatography-mass spectrometry (Py-GC/MS). The method demonstrated excellent reproducibility and high sensitivity, with a detection limit as low as 15 pg/m(3) for PS NPs. The method can be used for routine monitoring of atmospheric PS NPs and assessing their risk to human health.
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2023)
Article
Chemistry, Multidisciplinary
Lin Geng, Dingchuan Xue, Jingming Yao, Qiushi Dai, Haiming Sun, Dingding Zhu, Zhaoyu Rong, Ruyue Fang, Xuedong Zhang, Yong Su, Jitong Yan, Stephen J. Harris, Satoshi Ichikawa, Liqiang Zhang, Yongfu Tang, Sulin Zhang, Jianyu Huang
Summary: All solid-state batteries (ASSBs) with ceramic electrolytes and alkali metal anodes have the potential to be future energy storage technology for vehicle electrification and smart grids. However, uncontrollable dendrite growth in solid electrolytes (SEs) is a serious concern, and the underlying mechanism remains unclear. Through imaging and tracking, it is shown that Na dendrites grow in beta ''-Al2O3 SEs through alternating Na deposition and crack propagation. A multiscale model is developed to predict the fractal morphology of the growing dendrites. Decoupling between Na deposition and cracking can mitigate dendrite growth in ASSBs.
ENERGY & ENVIRONMENTAL SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Xuedong Zhang, Zaifa Wang, Xiaomei Li, Yong Su, Zhangran Ye, Liqiang Zhang, Qiao Huang, Yongfu Tang, Jianyu Huang
Summary: Cracks are commonly found in Ni-rich layered cathodes during cycling in liquid electrolyte-lithium-ion batteries (LELIBs), but their influence on capacity decay remains unclear. Moreover, the effect of cracks on the performance of all solid-state batteries (ASSBs) has not been studied yet. In this study, mechanically created cracks in single crystal LiNi0.8Mn0.1Co0.1O2 (NMC811) are examined, and their impact on capacity decay in solid-state batteries is revealed.
MATERIALS HORIZONS
(2023)
Article
Chemistry, Physical
Yixuan Wen, Shuaijun Ding, Chongchong Ma, Peng Jia, Wei Tu, Yunna Guo, Shuang Guo, Wei Zhou, Xiaoqian Zhang, Jianyu Huang, Liqiang Zhang, Tongde Shen, Yuqing Qiao
Summary: A nanoscale processing method was used to assemble a Li-O-2 nanobattery, where a single Ag nanowire was used as catalyst for O-2 electrode. The insertion process of lithium ions during electrochemical reactions was visualized. It was found that Ag nanoparticles on the surface of the Ag nanowire acted as catalyst during the charge/discharge reaction. Based on these findings, Ag nanoparticles decorated on porous carbon were synthesized and improved the cycling stability and the maximum specific capacity in a coin cell Li-O-2 battery.
Article
Chemistry, Physical
Zhenpeng Huang, Jihang Yu, Wenbo Li, Xuan Tang, Yanglong Guo, Yun Guo, Li Wang, Sheng Dai, Rui Liu, Wangcheng Zhan
Summary: This study focuses on the surface structure of PtFe nanoparticles on PtFe/CeO2-x catalysts and its impact on the activity and water resistance for propane oxidation. The PtFe/CeO2-O catalyst exhibited superior performance due to the cooperation among metallic Pt sites, active oxygen species, and FeOx nanoclusters. The findings of this study provide valuable insights for the development of efficient bimetallic catalysts to eliminate volatile organic compound pollutants.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Mei Gui Vanessa Wee, Amutha Chinnappan, Runxin Shang, Poh Seng Lee, Seeram Ramakrishna
Summary: Cooling processes, from residences to industries, require a lot of energy and are essential. This study introduces MIL-101(Cr), a new desiccant, to heat exchangers for more efficient cooling. By improving the synthesis method and using a special binder, the MIL-101(Cr)-coated heat exchanger shows improved water uptake capacity and lower regeneration temperature.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Ao Zhen, Guanyu Zhang, Ao Wang, Feng Luo, Jiehua Li, Hong Tan, Zhen Li
Summary: In this study, a solvent-free microemulsion method was used to synthesize waterborne polyurethane (WPU) material with high retention of mechanical properties and satisfactory water absorption rates. The material showed excellent biocompatibility and has broad application potential in the field of biomedicine.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Wensong Ge, Rui Wang, Xiaoyang Zhu, Houchao Zhang, Luanfa Sun, Fei Wang, Hongke Li, Zhenghao Li, Xinyi Du, Huangyu Chen, Fan Zhang, Huifa Shi, Huiqiang Hu, Yongming Xi, Jiankang He, Liang Hu, Hongbo Lan
Summary: This paper reviews the research on the surface tension of eutectic gallium-indium alloys (EGaIn) in the field of stretchable electronics. It covers the principles of oxide layer formation, factors influencing surface tension, and methods for surface modification of liquid metals. The paper also discusses the applications of EGaIn surface modification in different fields and highlights the challenges still faced and the future outlook.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Xiang Song, Lianghao Jia, Zhengen Wei, Tao Xiang, Shaobing Zhou
Summary: This paper provides an overview of the application, preparation, and role of biomimetic structures in solar evaporators with improved evaporation rate and lifetime.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Wei Yuan, Qian Deng, Dong Pan, Xiang An, Canyang Zhao, Wenjun Su, Zhengmin He, Qiang Sun, Ran Ang
Summary: Optimizing the performance of n-type PbTe thermoelectric materials is crucial for practical applications. Dynamic doping has emerged as an effective method to improve the performance of n-type PbTe by optimizing the carrier concentration. This study demonstrates the significance of Mn alloying in enhancing the performance of Ag-doped n-type PbTe by creating a hierarchical structure to suppress thermal transport and improving the Seebeck coefficient.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Xiaoyan Wang, Meiqi Geng, Shengjun Sun, Qian Xiang, Shiyuan Dong, Kai Dong, Yongchao Yao, Yan Wang, Yingchun Yang, Yongsong Luo, Dongdong Zheng, Qian Liu, Jianming Hu, Qian Wu, Xuping Sun, Bo Tang
Summary: This review provides a comprehensive analysis of the progress and challenges in the field of bifunctional electrocatalysts and efficient electrolyzers for seawater splitting. It summarizes recent advancements and proposes future perspectives for highly efficient bifunctional electrocatalysts and electrolyzers.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Jason K. Phong, Christopher B. Cooper, Lukas Michalek, Yangju Lin, Yuya Nishio, Yuran Shi, Huaxin Gong, Julian A. Vigil, Jan Ilavsky, Ivan Kuzmenko, Zhenan Bao
Summary: Dynamic block copolymers (DBCPs) combine the phase separation of traditional block copolymers with the supramolecular self-assembly of periodic dynamic polymers, resulting in the spontaneous self-assembly of high aspect ratio nanofibers with well-ordered PEG and PDMS domains. DBCPs with a periodic block sequence exhibit superior properties compared to those with a random sequence, including delayed onset of terminal flow and higher ionic conductivity values.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Hong Kyu Lee, Yasaswini Oruganti, Jonghyeon Lee, Seunghee Han, Jihan Kim, Dohyun Moon, Min Kim, Dae-Woon Lim, Hoi Ri Moon
Summary: This study reports the moisture-triggered proton-conductivity switching behavior in Zn5FDC MOFs induced by the presence and absence of coordinating solvents, which illustrates the significant role of coordinating solvents in conductivity variation.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Bommaramoni Yadagiri, Sanjay Sandhu, Ashok Kumar Kaliamurthy, Francis Kwaku Asiam, Jongdeok Park, Appiagyei Ewusi Mensah, Jae-Joon Lee
Summary: The molecular engineering of the interface modulator between the perovskite and hole transporting material is crucial for achieving satisfactory performance and stability of perovskite solar cells. In this study, cruciform-shaped dual functional organic materials were employed as surface passivation and hole transporting interfacial layers in perovskite solar cells. The use of these materials significantly improved the power conversion efficiency of the solar cells.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Joaquin Martinez-Ortigosa, Reisel Millan, Jorge Simancas, Manuel Hernandez-Rodriguez, J. Alejandro Vidal-Moya, Jose L. Jorda, Charlotte Martineau-Corcos, Vincent Sarou-Kanian, Mercedes Boronat, Teresa Blasco, Fernando Rey
Summary: This study investigates the synthesis of all-silica RTH zeolites using triisopropyl(methyl)phosphonium as the organic SDA. The results show the formation of two distinct crystalline phases under different synthesis conditions, with fluoride bonding to different silicon sites. It demonstrates the possibility of controlling the placement of fluoride in RTH zeolites through synthesis conditions.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Luyao Zheng, Cong Liu, Wenbiao Zhang, Boxu Gao, Tianlan Yan, Yahong Zhang, Xiaoming Cao, Qingsheng Gao, Yi Tang
Summary: This study successfully improves the efficiency and stability of water splitting by constructing a heterostructured electrocatalyst. The catalyst shows extraordinary performance and could offer an effective approach for the sustainable production of hydrogen.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Carlos A. Campos-Roldan, Raphael Chattot, Frederic Pailloux, Andrea Zitolo, Jacques Roziere, Deborah J. Jones, Sara Cavaliere
Summary: This study systematically evaluated the hydrogen evolution/oxidation reactions on a series of Pt-rare earth nanoalloys in alkaline media, and identified the effect of the lanthanide contraction. The experimental results revealed that the chemical nature of the rare earth modulates the adsorption and mobility of oxygenated-species, enhancing the kinetics of the reactions.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Sara Frank, Mads Folkjaer, Mads L. N. Nielsen, Melissa J. Marks, Henrik S. Jeppesen, Marcel Ceccato, Simon J. L. Billinge, Jacopo Catalano, Nina Lock
Summary: This study investigates the thermal decomposition of ZIF-67 and its correlation with structural evolution and electrocatalytic performance. The researchers used in situ X-ray absorption spectroscopy and total scattering techniques to analyze the process. They found that disorder emerges at lower temperatures and that extending the pyrolysis process can result in materials with superior electrochemical properties.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Zi-Yang Zhang, Hao Tian, Han Jiao, Xin Wang, Lei Bian, Yuan Liu, Nithima Khaorapapong, Yusuke Yamauchi, Zhong-Li Wang
Summary: By constructing Cu-0-Cu+-NH2 composite interfaces with the assistance of SiO2, the electrochemical CO2 reduction reaction (CO2RR) achieves high Faraday efficiency and current density for C2+ production, improving the productivity of carbon cycle.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Ting Wang, Ruijuan Zhang, Pengda Zhai, Mingjie Li, Xinying Liu, Chaoxu Li
Summary: This study successfully exfoliated COFs using a simple electrochemical method, which resulted in improved photocatalytic performance for COFs and enriched the fabrication approach of COF exfoliation.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)